It has previously been shown that the polymer formed in solid state polymerization of acrylamide is amorphous in spite of the fact that the reaction takes place within a crystalline solid. The stage at which it becomes amorphous is not known at present. Work with dilute solid solutions of acrylamide in propionamide suggests that this occurs after the addition of, at most, a very few monomer units.

Preliminary experiments using acetylacetone in the presence of ethylenediaminetetraacetic acid to separate major quantities of beryllium from fission products are reported. Using 2M beryllium solutions, decontamination factors of the order of 10/sup 3/ were obtained with trace quantities of the more important fission products. This is sufficiently encouraging for the work to be repeated at higher activity levels.

Abstract. The region where exact thermodynamic description of the state of matter at high pressure and high temperature is possible is located. In the remaining region various approximate theories and empirical relations are discussed. These considerations are applied to hydrogen to locate the density and pressure at which the diatomic bond collapses. Also the approximate conditions are determined at which no bound electron states exist.

A comparison of methods of capital cost estimation used for nuclear fuel reprocessing plants shows that, because of the special nature and complexity of such plants, cost estimation methods for conventional chemical plants involving the use of cost factors are not applicable and will give low estimates. Cost factors which are available from other countries where reprocessing plants are installed should be used with caution since those factors apply only for the particular design philosophy used and pertain to industrial conditions which are different in this county. Capital cost estimation methods involving direct take-offs from detailed design drawings are necessary to obtain reliable estimates. The methods of estimating operating costs for nuclear reprocessing and conventional chemical plants are similar.

The work described was undertaken to provide data for nuclear safety studies concerning NPF reprocessing equipment. The original objective was to determine the uranium density and water (hydrogen) content of UO2-H2O mixtures ranging from compact centrifuge cakes to dilute slurries. The scope was later expanded to include mixtures of UO2 with hydrocarbon oil and mixtures of UO3-H2O.

This technical report describes development work done on zonal centrifuge systems at the Oak Ridge National Laboratory and the Oak Ridge Gaseous Diffusion Plant during the period July 1 to December 31, 1962 under the Joint National Institute for Health-Atomic Energy Commission Zonal Centrifuge Development Program. A basic purpose of this project is to develop new methods for isolating virus particles associated with cancerous cells and tissues. Three classes of rotor systems capable of separating particles ranging in size from whole animal or plant cells to protein or nucleic acid molecules on the basis of either sedimentation rate or density alone have been developed. Experiments with phage particles indicate the feasibility of large-scale virus isolation by continuous-flow centrifugation, followed by isopycnic banding in cesium chloride and velocity sedimentation in sucrose - all steps being carried out sequentially in the same rotor. Zonal rotors using the reorienting gradient principle for molecular separations have been tested to 141,000 rpm (formula). Previous work on zonal centrifugation and future plans for this program are discussed.

Technical report outlining the nature and effects of energy loss and radiation in biological materials during radiobiological processes.

In calculating diffusion coefficients for gases diffusing from solids, the numerical solutions tabulated by Darken and Gurry, were found to lack the required precision, and the intervals between the arguments were too great to permit precise interpolations. Consequently the diffusion equation solutions of interest (diffusion from a sphere, cylinder, and plate, for the condition that the concentration of the diffusing species initially uniform) were re-evaluated. Computer programs for the three cases were written in FORTRAN for the IBM 7090. The solutions programmed are given in Crank. Values of the fractional completion were computed at approximately 0.01 increments, to the nearest 0.00001, and are tabulated in Table 1 to the nearest 0.0001. The table covers the fractional range from about 0.04 to 0.99. For smaller fractions satisfactory approximations are available. The table may be conveniently interpolated by plotting points about the region of interest and drawing a curve.

Technical report describing a bubble chamber film track measuring stage designed for maximum versatility that was build at Brookhaven National Laboratory. The report includes photographs and diagrams of the device.

Technical report describing "A means for automatically determining the coordinates of a point at the center of a bubble chamber track." from the abstract.

Space has been reserved near the southeast corner of the 100-N Area for the 122-N Decontamination Facility. Previous correspondence between Burns and Roe, Inc and General Electric bae discussed various facilities which might be needed in the building. The concepts of the decontamination processes are under active development by research groups at Hanford. At present, there are several workable processes known; each one has one or more fairly serious drawbacks.

This technical report discusses the synthesis of vic-dioximes, the analysis of vic-dioximes, the structure of vic-dioximes, the structure of metal(II)-vic-dioxime complexes, and analytical applications of this research. The report includes tables and figures that accompany the report's contents and findings.

This technical report discusses processes to study the stability constants and intrinsic solubility of several Nickel(II)-vic-Dioxime complexes.

Abstract. The Tory II-A reactor is a small, air cooled, high power-density reactor which is to operate at quite high temperatures. Design of the reactor is essentially complete. First operation is scheduled for late 1960 at the Nevada Test Site of the Atomic Energy Commission. Since the reactor is unshielded, the control room which houses the recording and indicting equipment is located approximately two miles from the test bunker. Signals from reactor and facility transducers are amplified in the test bunker and transmitted by cable to the control point. The kinds of quantities measures include neutron flux level, temperatures, pressures, vibration amplitudes, strain and air mass flow rate. The recording and indicating system is centered around 258 channels of 1.5 cycle per second, pulse-width modulation tape recording equipment and 72 channels of 120 cps, analogue strip-chart records. In addition, there is a number of the usual meters, scalers and slow-response strip-chart recorders.

Specimens suitable for transmission electron microscopy have been prepared from bulk polycrystalline molybdenum after tensile deformation and recovery. The resulting dislocation substructures are described. Some tentative conclusions concerning the mechanism of plastic deformation in molybdenum are discussed.

The angle by which a magnet deflects the trajectory of a particle in the x-z plane is proportional to the integral [integral not transcribed] taken over the trajectory wherever B≠0. Alternating gradient focusing is achieved by designing magnets so that I=I(x) varies linearly with x over a suitable x interval. Usually this is done by shaping the poles to give a linear variation of By with x while keeping the length of the magnet constant for different x. Certain advantaged may be gained by varying the effective length of the magnet with x and keeping By constant so that the integral varies properly with x. Figure 1 shows several such poles for which the trajectory length, and hence the integral (1), varies approximately from 2/3 to 4/3 of the mean value.

The amount by which the field of a magnet bends the path of a charged particle is proportional to the integral of Btds along the trajectory. Instead of making tedious point by point measurements of B in magnets and performing the integrations numerically, it has been found useful to measure directly, by using a search coil whose winding consists of long and narrow turns extending through the magnet gap from z1 and z2 in the direction of the trajectory. It should be noted that the integral Iy is taken along a straight x=constant, y=constant lines and not along the actual curved trajectory path; for small curvature the difference is small.

In discussing this subject, data on radiation induced mammary gland neoplasia in the rat indicating that direct interaction between the radiation and target tissue is necessary for maximum neoplasia induction will be presented mainly. Other types of radiation induced neoplasia, in which little or no information on the mechanisms involved is available, will be discussed briefly. In particular, investigations on radiation induced mouse lymphoma will be reviewed, in which neoplasia appears to be an abscopal effect. Implications of these data will be discussed, particularly with regard to possible mechanisms involved, and extrapolation to man.

The feasibility of removing and recovering cesium-137 from various HAPO process solutions by precipitation of Cs2ZnFe(CN)6 has been demonstrated previously. Pilot plant studies of calcination and steam hydrolysis of non-radioactive Cs2ZnFe(CN)6 precipitates by members of the Process Equipment Development Operation are currently in progress. In support of these pilot plant studies, experiments were performed to determine the extent, if any, to which cesium volatilizes during calcination and hydrolysis of Cs2ZnFe(CN)6 precipitates containing cesium-137. Experimental procedures and results are presented in this report.

The spectra of KHF2, KH2F3, NaH2F3, liquid and solid HF were measured between 1200 and 30 cm-1 by the inelastic scattering of "cold neutrons" (0.005e.v.). The spectrum of KHF2 is in agreement with previous infrared measurements and shows a peak at 147 mV corresponding to a deformation frequency v2 of the F-H-F group and a broad peak at 13 mV due to a libration of this group. The observed spectra for KH2F3, NaH2F3 solid and liquid HF were compared with that for KHF2 considering the known results that the F-F distance increases, the position of the H atom between the two fluorines becomes more asymmetrical, and the strength of the hydrogen bond decreases in going from the HF2- ion to H2F3- ion to HF. In this comparison the known structure of the H2F3- ion is considered as being intermediate between that of HF2- and the zig-zag hydrogen bonded chains in solid HF. As a result, the lines observed at 112 mV and 67 mV in the H2F3- spectra and in HF respectively are associated with the deformation frequency v2 of the H-F-H group in these compounds. In addition the spectra of H2F3- ions show a peak at a 15 mV …

Abstract: A materials exposure program has been established in the Garigliano Nuclear Power Plant to measure the effect of neutron irradiation and time at temperate on the mechanical properties of the reactor pressure vessel steel. Base metal specimens were made from portions of the pressure vessel steel, and weld heat-affected zone and weld metal samples were taken from a weldment made from the pressure vessel steel and simulating a pressure vessel circumferential weld since there are no longitudinal welds in the forged ring shell. The specimens were sealed in helium-filled capsules and placed in the reactor vessel at locations where they will be exposed to a variety of conditions. Tensile property changes will be measured by pre- and post-irradiation tests on small tensile specimens. Fracture characteristic changes will be measured in similar fashion by Charpy V-notch impact tests. The program is planned to cover a 32-year period, with specimens to be removed for test at intervals of 1, 2, 4, 8, 16, and 32 years.

Studies carried on since 1956 indicate that the prosaic breeding procedure of sibbing among the most perennial segregates in the hybrid of 4n maize x 4n perennial teosinte quickly restores perennialism to 50% maize tetraploids through increasing the expression of the rhizomatous habit under selection pressure. Similarly, only two generations of selection at the 75% maize level have resulted in a progressive recovery of the perennial expressive. A high degree of maize-likeness therefore appears to be compatible with the perennial expression at the 4n level.

Studies are being made on the recovery of thorium (and uranium) from granitic rock, since this source represents a very large potential thorium reserve for the nuclear power industry. In preliminary leaching studies on 16 granite samples (containing 8-95 ppm thorium and 1.5-16 ppm uranium), maximum recoveries of thorium and uranium ranged 30-85% and 15-65% respectively, and sulfuric acid consumption was high (30-120 lbs H2SO4 per ton of granite). A relatively high acidity was needed to obtain rapid and efficient dissolution of the soluble thorium fraction. The cost of treating granite was estimated at $3.50-5.20 per ton, variations within this range being dependent primarily on differences in acid consumption for different granites. Estimated costs per pound of thorium plus uranium recovered ranged $30-500.

This report is the third in a series of quarterly reports discussing the concept and progression of an improved method in nuclear measuring than the usage of the scintillation counter. This report indicates that in a chopped double beam system, commutation of the detector current permits selection of optimum response time and size of radioactive sources.