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Quality Parameters and Chemical Analysis for Biodiesel Produced in the United States in 2011 (open access)

Quality Parameters and Chemical Analysis for Biodiesel Produced in the United States in 2011

Samples of biodiesel (B100) from producers and terminals in 2011were tested for critical properties: free and total glycerin, flash point, cloud point, oxidation stability, cold soak filterability, and metals. Failure rates for cold soak filterability and oxidation stability were below 5%. One sample failed flash point due to excess methanol. One sample failed oxidation stability and metal content. Overall, 95% of the samples from this survey met biodiesel quality specification ASTM D6751. In 2007, a sampling of B100 from production facilities showed that nearly 90% met D6751. In samples meeting D6751, calcium was found above the method detection limit in nearly half the samples. Feedstock analysis revealed half the biodiesel was produced from soy and half was from mixed feedstocks. The saturated fatty acid methyl ester concentration of the B100 was compared to the saturated monoglyceride concentration as a percent of total monoglyceride. The real-world correlation of these properties was very good. The results of liquid chromatograph measurement of monoglycerides were compared to ASTM D6751. Agreement between the two methods was good, particularly for total monoglycerides and unsaturated monoglycerides. Because only very low levels of saturated monoglycerides measured, the two methods had more variability, but the correlation was still acceptable.
Date: March 1, 2013
Creator: Alleman, T. L.; Fouts, L. & Chupka, G.
Object Type: Report
System: The UNT Digital Library
Effect Of Oxidation On Chromium Leaching And Redox Capacity Of Slag-Containing Waste Forms (open access)

Effect Of Oxidation On Chromium Leaching And Redox Capacity Of Slag-Containing Waste Forms

The rate of oxidation is important to the long-term performance of reducing salt waste forms because the solubility of some contaminants, e.g., technetium, is a function of oxidation state. TcO{sub 4}{sup −} in the salt solution is reduced to Tc(IV) and has been shown to react with ingredients in the waste form to precipitate low solubility sulfide and/or oxide phases [Shuh, et al., 1994, Shuh, et al., 2000, Shuh, et al., 2003]. Upon exposure to oxygen, the compounds containing Tc(IV) oxidize to the pertechnetate ion, Tc(VII)O{sub 4}{sup −}, which is very soluble. Consequently the rate of technetium oxidation front advancement into a monolith and the technetium leaching profile as a function of depth from an exposed surface are important to waste form performance and ground water concentration predictions. An approach for measuring contaminant oxidation rate (effective contaminant specific oxidation rate) based on leaching of select contaminants of concern is described in this report. In addition, the relationship between reduction capacity and contaminant oxidation is addressed. Chromate was used as a non-radioactive surrogate for pertechnetate in simulated waste form samples. Depth discrete subsamples were cut from material exposed to Savannah River Site (SRS) ''field cured'' conditions. The subsamples were prepared and …
Date: March 1, 2013
Creator: Almond, P. M.; Stefanko, D. B. & Langton, C. A.
Object Type: Report
System: The UNT Digital Library
Mountain Home Air Force Base, Idaho Geothermal Resource Assessment and Future Recommendations (open access)

Mountain Home Air Force Base, Idaho Geothermal Resource Assessment and Future Recommendations

The U.S. Air Force is facing a number of challenges as it moves into the future, one of the biggest being how to provide safe and secure energy to support base operations. A team of scientists and engineers met at Mountain Home Air Force Base in early 2011 near Boise, Idaho, to discuss the possibility of exploring for geothermal resources under the base. The team identified that there was a reasonable potential for geothermal resources based on data from an existing well. In addition, a regional gravity map helped identify several possible locations for drilling a new well. The team identified several possible sources of funding for this well—the most logical being to use U.S. Department of Energy funds to drill the upper half of the well and U.S. Air Force funds to drill the bottom half of the well. The well was designed as a slimhole well in accordance with State of Idaho Department of Water Resources rules and regulations. Drilling operations commenced at the Mountain Home site in July of 2011 and were completed in January of 2012. Temperatures increased gradually, especially below a depth of 2000 ft. Temperatures increased more rapidly below a depth of 5500 ft. …
Date: March 1, 2013
Creator: Armstrong, Joseph C.; Breckenridge, Robert P.; Nielson, Dennis L.; Shervais, John W. & Wood, Thomas R.
Object Type: Report
System: The UNT Digital Library
Analysis of the Impacts of Distribution-Connected PV Using High-Speed Data Sets: Preprint (open access)

Analysis of the Impacts of Distribution-Connected PV Using High-Speed Data Sets: Preprint

This paper, presented at the IEEE Green Technologies Conference 2013, utilizes information from high resolution data acquisition systems developed at the National Renewable Energy Laboratory and deployed on a high-penetration PV distribution system to analyze the variability of different electrical parameters. High-resolution solar irradiance data is also available in the same area which is used to characterize the available resource and how it affects the electrical characteristics of the study circuit. This paper takes a data-driven look at the variability caused by load and compares those results against times when significant PV production is present. Comparisons between the variability in system load and the variability of distributed PV generation are made.
Date: March 1, 2013
Creator: Bank, J. & Mather, B.
Object Type: Article
System: The UNT Digital Library
Peace Talks in Colombia (open access)

Peace Talks in Colombia

This report provides background on Colombia's armed conflict and describes its key players. It briefly analyzes prior negotiations with the Revolutionary Armed Forces of Colombia (FARC) and the lessons learned from those efforts that apply to the current talks. It examines what has transpired in the talks that have now lasted for more than a year and a half, considers some of the constraints that could limit the success of the peace talks, and looks at the prospects for the current negotiations.
Date: March 1, 2013
Creator: Beittel, June S.
Object Type: Report
System: The UNT Digital Library
Evaluation of Suitability of Selected Set of Coal Plant Sites for Repowering with Small Modular Reactors (open access)

Evaluation of Suitability of Selected Set of Coal Plant Sites for Repowering with Small Modular Reactors

This report summarizes the approach that ORNL developed for screening a sample set of small coal stations for possible repowering with SMRs; the methodology employed, including spatial modeling; and initial results for these sample plants. The objective in conducting this type of siting evaluation is to demonstrate the capability to characterize specific sample coal plant sites to identify any particular issues associated with repowering existing coal stations with SMRs using OR-SAGE; it is not intended to be a definitive assessment per se as to the absolute suitability of any particular site.
Date: March 1, 2013
Creator: Belles, Randy; Copinger, Donald A; Mays, Gary T; Omitaomu, Olufemi A & Poore, Willis P., III
Object Type: Report
System: The UNT Digital Library
DOE-CEA Benchmark on SFR ASTRID Innovative Core: N (open access)

DOE-CEA Benchmark on SFR ASTRID Innovative Core: N

ASTRID is a fast reactor being designed by CEA to
Date: March 1, 2013
Creator: Bess, J.; Bosq, J. C.; Bouret, C. & Jean, C. De Saint
Object Type: Article
System: The UNT Digital Library
HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORES 5, 6, 7, & 8: COLUMNAR HEXAGONAL POINT-ON-POINT PACKING WITH A 1:2 MODERATOR-TO-FUEL PEBBLE RATIO (open access)

HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORES 5, 6, 7, & 8: COLUMNAR HEXAGONAL POINT-ON-POINT PACKING WITH A 1:2 MODERATOR-TO-FUEL PEBBLE RATIO

PROTEUS is a zero-power research reactor based on a cylindrical graphite annulus with a central cylindrical cavity. The graphite annulus remains basically the same for all experimental programs, but the contents of the central cavity are changed according to the type of reactor being investigated. Through most of its service history, PROTEUS has represented light-water reactors, but from 1992 to 1996 PROTEUS was configured as a pebble-bed reactor (PBR) critical facility and designated as HTR-PROTEUS. The nomenclature was used to indicate that this series consisted of High Temperature Reactor experiments performed in the PROTEUS assembly. During this period, seventeen critical configurations were assembled and various reactor physics experiments were conducted. These experiments included measurements of criticality, differential and integral control rod and safety rod worths, kinetics, reaction rates, water ingress effects, and small sample reactivity effects (Ref. 3). HTR-PROTEUS was constructed, and the experimental program was conducted, for the purpose of providing experimental benchmark data for assessment of reactor physics computer codes. Considerable effort was devoted to benchmark calculations as a part of the HTR-PROTEUS program. References 1 and 2 provide detailed data for use in constructing models for codes to be assessed. Reference 3 is a comprehensive summary of …
Date: March 1, 2013
Creator: Bess, John D.
Object Type: Report
System: The UNT Digital Library
HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORES 9 & 10: COLUMNAR HEXAGONAL POINT-ON-POINT PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO (open access)

HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORES 9 & 10: COLUMNAR HEXAGONAL POINT-ON-POINT PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO

PROTEUS is a zero-power research reactor based on a cylindrical graphite annulus with a central cylindrical cavity. The graphite annulus remains basically the same for all experimental programs, but the contents of the central cavity are changed according to the type of reactor being investigated. Through most of its service history, PROTEUS has represented light-water reactors, but from 1992 to 1996 PROTEUS was configured as a pebble-bed reactor (PBR) critical facility and designated as HTR-PROTEUS. The nomenclature was used to indicate that this series consisted of High Temperature Reactor experiments performed in the PROTEUS assembly. During this period, seventeen critical configurations were assembled and various reactor physics experiments were conducted. These experiments included measurements of criticality, differential and integral control rod and safety rod worths, kinetics, reaction rates, water ingress effects, and small sample reactivity effects (Ref. 3). HTR-PROTEUS was constructed, and the experimental program was conducted, for the purpose of providing experimental benchmark data for assessment of reactor physics computer codes. Considerable effort was devoted to benchmark calculations as a part of the HTR-PROTEUS program. References 1 and 2 provide detailed data for use in constructing models for codes to be assessed. Reference 3 is a comprehensive summary of …
Date: March 1, 2013
Creator: Bess, John D.
Object Type: Report
System: The UNT Digital Library
HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORE 4: RANDOM PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO (open access)

HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORE 4: RANDOM PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO

In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. One benchmark experiment was evaluated in this report: Core 4. Core 4 represents the only configuration with random pebble packing in the HTR-PROTEUS series of experiments, and has a moderator-to-fuel pebble ratio of 1:1. Three random configurations were performed. The initial configuration, Core 4.1, was rejected because the method for pebble loading, separate delivery tubes for the moderator and fuel pebbles, may not have been completely random; this core loading was rejected by the experimenters. Cores 4.2 and 4.3 were loaded using a single delivery tube, eliminating the possibility for systematic ordering effects. The second and third cores differed slightly …
Date: March 1, 2013
Creator: Bess, John D. & Montierth, Leland M.
Object Type: Report
System: The UNT Digital Library
HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio (open access)

HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and …
Date: March 1, 2013
Creator: Bess, John D.; Dolphin, Barbara H.; Sterbentz, James W.; Snoj, Luka; Lengar, Igor & Köberl, Oliver
Object Type: Report
System: The UNT Digital Library
Fresh-Core Reload of the Neutron Radiography (NRAD) Reactor with Uranium(20)-Erbium-Zirconium-Hydride Fuel (open access)

Fresh-Core Reload of the Neutron Radiography (NRAD) Reactor with Uranium(20)-Erbium-Zirconium-Hydride Fuel

The neutron radiography (NRAD) reactor is a 250 kW TRIGA® (Training, Research, Isotopes, General Atomics) Mark II , tank-type research reactor currently located in the basement, below the main hot cell, of the Hot Fuel Examination Facility (HFEF) at the Idaho National Laboratory (INL). It is equipped with two beam tubes with separate radiography stations for the performance of neutron radiography irradiation on small test components. The initial critical configuration developed during the fuel loading process, which contains only 56 fuel elements, has been evaluated as an acceptable benchmark experiment. The 60-fuel-element operational core configuration of the NRAD LEU TRIGA reactor has also been evaluated as an acceptable benchmark experiment. Calculated eigenvalues differ significantly (~±1%) from the benchmark eigenvalue and have demonstrated sensitivity to the thermal scattering treatment of hydrogen in the U-Er-Zr-H fuel.
Date: March 1, 2013
Creator: Bess, John D.; Maddock, Thomas L.; Marshall, Margaret A. & Montierth, Leland M.
Object Type: Report
System: The UNT Digital Library
Development of YBCO Superconductor for Electric Systems: Cooperative Research and Development Final Report, CRADA Number CRD-04-150 (open access)

Development of YBCO Superconductor for Electric Systems: Cooperative Research and Development Final Report, CRADA Number CRD-04-150

The proposed project will be collaborative in exploration of high temperature superconductor oxide films between SuperPower, Inc. and the National Renewable Energy Laboratory. This CRADA will attempt to develop YBCO based high temperature oxide technology.
Date: March 1, 2013
Creator: Bhattacharya, R.
Object Type: Report
System: The UNT Digital Library
Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway (open access)

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.
Date: March 1, 2013
Creator: Biddy, M. & Jones, S.
Object Type: Report
System: The UNT Digital Library
Whole Algae Hydrothermal Liquefaction Technology Pathway (open access)

Whole Algae Hydrothermal Liquefaction Technology Pathway

This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.
Date: March 1, 2013
Creator: Biddy, M.; Davis, R. & Jones, S.
Object Type: Report
System: The UNT Digital Library
Ex-Situ Catalytic Fast Pyrolysis Technology Pathway (open access)

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.
Date: March 1, 2013
Creator: Biddy, M.; Dutta, A.; Jones, S. & Meyer, A.
Object Type: Report
System: The UNT Digital Library
In-Situ Catalytic Fast Pyrolysis Technology Pathway (open access)

In-Situ Catalytic Fast Pyrolysis Technology Pathway

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.
Date: March 1, 2013
Creator: Biddy, M.; Dutta, A.; Jones, S. & Meyer, A.
Object Type: Report
System: The UNT Digital Library
Field Testing of Low-Cost Bio-Based Phase Change Material (open access)

Field Testing of Low-Cost Bio-Based Phase Change Material

A test wall built with phase change material (PCM)-enhanced loose-fill cavity insulation was monitored for a period of about a year in the warm-humid climate of Charleston, South Carolina. The test wall was divided into various sections, one of which contained only loose-fill insulation and served as a control for comparing and evaluating the wall sections with the PCM-enhanced insulation. This report summarizes the findings of the field test.
Date: March 1, 2013
Creator: Biswas, Kaushik; Childs, Phillip W & Atchley, Jerald Allen
Object Type: Report
System: The UNT Digital Library
Digital Full-Scope Simulation of a Conventional Nuclear Power Plant Control Room, Phase 2: Installation of a Reconfigurable Simulator to Support Nuclear Plant Sustainability (open access)

Digital Full-Scope Simulation of a Conventional Nuclear Power Plant Control Room, Phase 2: Installation of a Reconfigurable Simulator to Support Nuclear Plant Sustainability

The U.S. Department of Energy’s Light Water Reactor Sustainability program has developed a control room simulator in support of control room modernization at nuclear power plants in the U.S. This report highlights the recent completion of this reconfigurable, full-scale, full-scope control room simulator buildout at the Idaho National Laboratory. The simulator is fully reconfigurable, meaning it supports multiple plant models developed by different simulator vendors. The simulator is full-scale, using glasstop virtual panels to display the analog control boards found at current plants. The present installation features 15 glasstop panels, uniquely achieving a complete control room representation. The simulator is also full-scope, meaning it uses the same plant models used for training simulators at actual plants. Unlike in the plant training simulators, the deployment on glasstop panels allows a high degree of customization of the panels, allowing the simulator to be used for research on the design of new digital control systems for control room modernization. This report includes separate sections discussing the glasstop panels, their layout to mimic control rooms at actual plants, technical details on creating a multi-plant and multi-vendor reconfigurable simulator, and current efforts to support control room modernization at U.S. utilities. The glasstop simulator provides an …
Date: March 1, 2013
Creator: Boring, Ronald L.; Agarwal, Vivek; Fitzgerald, Kirk; Hugo, Jacques & Hallbert, Bruce
Object Type: Report
System: The UNT Digital Library
Building America Expert Meeting: Combustion Safety (open access)

Building America Expert Meeting: Combustion Safety

This is a meeting overview of 'The Best Approach to Combustion Safety in a Direct Vent World', held June 28, 2012, in San Antonio, Texas. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.
Date: March 1, 2013
Creator: Brand, L.
Object Type: Report
System: The UNT Digital Library
Integral Benchmark Data for Nuclear Data Testing T (open access)

Integral Benchmark Data for Nuclear Data Testing T

The status of the International Criticality Safety
Date: March 1, 2013
Creator: Briggs, J. Blair; Bess, John D. & Gulliford, Jim
Object Type: Article
System: The UNT Digital Library
The Express-Star (Chickasha, Okla.), Ed. 1 Friday, March 1, 2013 (open access)

The Express-Star (Chickasha, Okla.), Ed. 1 Friday, March 1, 2013

Daily newspaper from Chickasha, Oklahoma that includes local, state, and national news along with advertising.
Date: March 1, 2013
Creator: Bright, James
Object Type: Newspaper
System: The Gateway to Oklahoma History
Transportation Energy Futures Series: Freight Transportation Modal Shares: Scenarios for a Low-Carbon Future (open access)

Transportation Energy Futures Series: Freight Transportation Modal Shares: Scenarios for a Low-Carbon Future

Truck, rail, water, air, and pipeline modes each serve a distinct share of the freight transportation market. The current allocation of freight by mode is the product of technologic, economic, and regulatory frameworks, and a variety of factors -- price, speed, reliability, accessibility, visibility, security, and safety -- influence mode. Based on a comprehensive literature review, this report considers how analytical methods can be used to project future modal shares and offers insights on federal policy decisions with the potential to prompt shifts to energy-efficient, low-emission modes. There are substantial opportunities to reduce the energy used for freight transportation, but it will be difficult to shift large volumes from one mode to another without imposing considerable additional costs on businesses and consumers. This report explores federal government actions that could help trigger the shifts in modal shares needed to reduce energy consumption and emissions. This is one in a series of reports produced as a result of the Transportation Energy Futures project, a Department of Energy-sponsored multi-agency effort to pinpoint underexplored strategies for reducing GHGs and petroleum dependence related to transportation.
Date: March 1, 2013
Creator: Brogan, J. J.; Aeppli, A. E.; Beagan, D. F.; Brown, A.; Fischer, M. J.; Grenzeback, L. R. et al.
Object Type: Report
System: The UNT Digital Library
Test plan for the irradiation of nonmetallic materials. (open access)

Test plan for the irradiation of nonmetallic materials.

A comprehensive test program to evaluate nonmetallic materials use in the Hanford Tank Farms is described in detail. This test program determines the effects of simultaneous multiple stressors at reasonable conditions on in-service configuration components by engineering performance testing.
Date: March 1, 2013
Creator: Brush, Laurence H.; Farnum, Cathy Ottinger; Gelbard, Fred; Dahl, M.; Joslyn, C. C. & Venetz, T. J.
Object Type: Report
System: The UNT Digital Library