The scrape-off layer plasma at the tokamak region is characterized by open field lines and often contains large variations in plasma properties along these field-lines. Proper characterization of local plasma conditions is critical to assessing plasma-material interaction processes occuring at the target. Langmuir probes are frequently employed in tokamak divertors but are challenging to interpretation. A kinetic interpretation for Langmuir probes in NSTX has yielded non-Maxwellian electron distributions in the divertor characterized by cool bulk populations and energetic tail populations with temperatures of 2-4 times the bulk. Spectroscopic analysis and modeling confirms the bulk plasma temperature and density which can only be obtained with the kinetic interpretation