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A comparative study of the complexation of Np(V) with N,N-dimethyl-3-oxa-glutaramic acid and related ligands: thermodynamics, optical properties and structural aspects (open access)

A comparative study of the complexation of Np(V) with N,N-dimethyl-3-oxa-glutaramic acid and related ligands: thermodynamics, optical properties and structural aspects

Complexation of Np(V) with N,N-dimethyl-3-oxa-glutaramic acid (DMOGA) was studied in comparison with its diamide analog, N,N,N{prime},N{prime}-tetramethyl-3-oxa-glutaramide (TMOGA), and dicarboxylate analog, oxydiacetic acid (ODA). Thermodynamic parameters, including the stability constant and the enthalpy of complexation, were determined by spectrophotometry and calorimetry. Single-crystal structure of NpO{sub 2}(H{sub 2}O)(DMOGA){center_dot}H{sub 2}O(c) was identified by X-ray diffractometry using synchrotron radiation. Like ODA and TMOGA, DMOGA forms a tridentate Np(V) complex, with three oxygen atoms coordinating to the linear NpO{sub 2}{sup +} moiety via the equatorial plane. The stability constants, enthalpy and entropy of complexation generally decrease in the order ODA > DMOGA > TMOGA, suggesting that the complexation is entropy driven and the substitution of a carboxylate group with an amide group reduces the strength of complexation with Np(V) due to the decrease in the entropy of complexation.
Date: March 29, 2010
Creator: Rao, Linfeng; Tian, Guoxin & Teat, Simon J.
Object Type: Article
System: The UNT Digital Library
Congressional Oversight of Intelligence: Current Structure and Alternatives (open access)

Congressional Oversight of Intelligence: Current Structure and Alternatives

This report describes the Select Committees on Intelligence and then the former Joint Committee on Atomic Energy, often cited as a model for a counterpart on intelligence. The study also sets forth proposed characteristics for a joint committee on intelligence, differences among these, and their pros and cons.
Date: March 29, 2010
Creator: Kaiser, Frederick M.
Object Type: Report
System: The UNT Digital Library
Defense Supplier Base: DOD Should Leverage Ongoing Initiatives in Developing Its Program to Mitigate Risk of Counterfeit Parts (open access)

Defense Supplier Base: DOD Should Leverage Ongoing Initiatives in Developing Its Program to Mitigate Risk of Counterfeit Parts

A letter report issued by the Government Accountability Office with an abstract that begins "Counterfeit parts--generally those whose sources knowingly misrepresent the parts' identity or pedigree--have the potential to seriously disrupt the Department of Defense (DOD) supply chain, delay missions, and affect the integrity of weapon systems. Almost anything is at risk of being counterfeited, from fasteners used on aircraft to electronics used on missile guidance systems. Further, there can be many sources of counterfeit parts as DOD draws from a large network of global suppliers. Based on a congressional request, GAO examined (1) DOD's knowledge of counterfeit parts in its supply chain, (2) DOD processes to detect and prevent counterfeit parts, and (3) commercial initiatives to mitigate the risk of counterfeit parts. GAO's findings are based on an examination of DOD regulations, guidance, and databases used to track deficient parts, as well as a Department of Commerce study on counterfeit parts; interviews with Commerce, DOD, and commercial-sector officials at selected locations; and a review of planned and existing efforts for counterfeit-part mitigation."
Date: March 29, 2010
Creator: United States. Government Accountability Office.
Object Type: Report
System: The UNT Digital Library
Doctoral Lecture Recital: 2010-03-29 – John Francis Roberts, marimba transcript

Doctoral Lecture Recital: 2010-03-29 – John Francis Roberts, marimba

Recital presented at the UNT College of Music Recital Hall in partial fulfillment of the Doctor of Musical Arts (DMA) degree.
Date: March 29, 2010
Creator: Roberts, John Francis
Object Type: Sound
System: The UNT Digital Library

Doctoral Recital: 2010-03-29 - John Whitaker, horn and natural horn

Recital presented at the UNT College of Music Main Auditorium in partial fulfillment of the Doctor of Musical Arts (DMA) degree.
Date: March 29, 2010
Creator: Whitaker, John
Object Type: Sound
System: The UNT Digital Library
Enzyme-Like Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation (open access)

Enzyme-Like Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation

A primary goal in the design and synthesis of molecular hosts has been the selective recognition and binding of a variety of guests using non-covalent interactions. Supramolecular catalysis, which is the application of such hosts towards catalysis, has much in common with many enzymatic reactions, chiefly the use of both spatially appropriate binding pockets and precisely oriented functional groups to recognize and activate specific substrate molecules. Although there are now many examples which demonstrate how selective encapsulation in a host cavity can enhance the reactivity of a bound guest, all have failed to reach the degree of increased reactivity typical of enzymes. We now report the catalysis of the Nazarov cyclization by a self-assembled coordination cage, a carbon-carbon bond-forming reaction which proceeds under mild, aqueous conditions. The acceleration in this system is over a million-fold, and represents the first example of supramolecular catalysis that achieves the level of rate enhancement comparable to that observed in several enzymes. We explain the unprecedented degree of rate increase as due to the combination of (a) preorganization of the encapsulated substrate molecule, (b) stabilization of the transition state of the cyclization by constrictive binding, and (c) increase in the basicity of the complexed alcohol …
Date: March 29, 2010
Creator: Hastings, Courtney; Pluth, Michael; Bergman, Robert & Raymond, Kenneth
Object Type: Article
System: The UNT Digital Library
An estimate of collisional beam scattering during final focus in NDCX-II (open access)

An estimate of collisional beam scattering during final focus in NDCX-II

None
Date: March 29, 2010
Creator: Cohen, R H
Object Type: Report
System: The UNT Digital Library
The Express-Star (Chickasha, Okla.), Ed. 1 Monday, March 29, 2010 (open access)

The Express-Star (Chickasha, Okla.), Ed. 1 Monday, March 29, 2010

Daily newspaper from Chickasha, Oklahoma that includes local, state, and national news along with advertising.
Date: March 29, 2010
Creator: Wray, Kelly
Object Type: Newspaper
System: The Gateway to Oklahoma History
Federal Register, Volume 75, Number 59, March 29, 2010, Pages 15321-15600 (open access)

Federal Register, Volume 75, Number 59, March 29, 2010, Pages 15321-15600

Daily publication of the U.S. Office of the Federal Register contains rules and regulations, proposed legislation and rule changes, and other notices, including "Presidential proclamations and Executive Orders, Federal agency documents having general applicability and legal effect, documents required to be published by act of Congress, and other Federal agency documents of public interest" (p. ii). Table of Contents starts on page iii.
Date: March 29, 2010
Creator: United States. Office of the Federal Register.
Object Type: Journal/Magazine/Newsletter
System: The UNT Digital Library
First Quarter Hanford Seismic Report for Fiscal Year 2010 (open access)

First Quarter Hanford Seismic Report for Fiscal Year 2010

The Hanford Seismic Network and the Eastern Washington Regional Network consist of 44 individual sensor sites and 15 radio relay sites maintained by the Hanford Seismic Assessment Team. The Hanford Seismic Network recorded 81 local earthquakes during the first quarter of FY 2010. Sixty-five of these earthquakes were detected in the vicinity of Wooded Island, located about eight miles north of Richland just west of the Columbia River. The Wooded Island events recorded this quarter is a continuation of the swarm events observed during fiscal year 2009 and reported in previous quarterly and annual reports (Rohay et al; 2009a, 2009b, 2009c, and 2009d). Most of the events were considered minor (coda-length magnitude [Mc] less than 1.0) with only 1 event in the 2.0-3.0 range; the maximum magnitude event (2.5 Mc) occurred on December 22 at depth 2.1 km. The average depth of the Wooded Island events during the quarter was 1.4 km with a maximum depth estimated at 3.1 km. This placed the Wooded Island events within the Columbia River Basalt Group (CRBG). The low magnitude of the Wooded Island events has made them undetectable to all but local area residents. The Hanford SMA network was triggered several times by …
Date: March 29, 2010
Creator: Rohay, Alan C.; Sweeney, Mark D.; Hartshorn, Donald C.; Clayton, Ray E. & Devary, Joseph L.
Object Type: Report
System: The UNT Digital Library
[Funeral Program for Mary J. Jones, March 29, 2010] (open access)

[Funeral Program for Mary J. Jones, March 29, 2010]

Funeral program for Mary J. Jones, born April 15, 1924 and died March 22, 2010. The funeral was held Monday, March 29, 2010 at F. E. Lewis Memorial Chapel, officiated by Rev. Kevin Nelson. Funeral arrangements were made through Lewis Funeral Home and she was buried in Meadowlawn Memorial Park in San Antonio, Texas.
Date: March 29, 2010
Creator: unknown
Object Type: Pamphlet
System: The Portal to Texas History
FY2011 Budget Proposals and Projections (open access)

FY2011 Budget Proposals and Projections

This report provides an overview of major budget estimates and projections for the FY2011 federal budget cycle. The report presents and compares budget projections calculated by the Obama Administration's Office of Management and Budget (OMB) and the Congressional Budget Office (CBO).
Date: March 29, 2010
Creator: Austin, D. A.
Object Type: Report
System: The UNT Digital Library
Inflation: Causes, Costs, and Current Status (open access)

Inflation: Causes, Costs, and Current Status

This report discusses inflation including its causes and effect on the economy. In particular, it brings together broad knowledge from economists to discuss the real costs of inflation on the economy.
Date: March 29, 2010
Creator: Labonte, Marc
Object Type: Report
System: The UNT Digital Library
Iraq: Politics, Elections, and Benchmarks (open access)

Iraq: Politics, Elections, and Benchmarks

This report provides an overview of Iraq's political transition from the dictatorship of Saddam Hussein to a plural polity that encompasses varying sects and ideological and political factions. This report also addresses ongoing governmental instabilities and their causes, as well as U.S. concerns about possible Iranian influence in Iraq as U.S. forces depart the country.
Date: March 29, 2010
Creator: Katzman, Kenneth
Object Type: Report
System: The UNT Digital Library
Kalman filtering to suppress spurious signals in Adaptive Optics control (open access)

Kalman filtering to suppress spurious signals in Adaptive Optics control

In many scenarios, an Adaptive Optics (AO) control system operates in the presence of temporally non-white noise. We use a Kalman filter with a state space formulation that allows suppression of this colored noise, hence improving residual error over the case where the noise is assumed to be white. We demonstrate the effectiveness of this new filter in the case of the estimated Gemini Planet Imager tip-tilt environment, where there are both common-path and non-common path vibrations. We discuss how this same framework can also be used to suppress spatial aliasing during predictive wavefront control assuming frozen flow in a low-order AO system without a spatially filtered wavefront sensor, and present experimental measurements from Altair that clearly reveal these aliased components.
Date: March 29, 2010
Creator: Poyneer, L & Veran, J P
Object Type: Article
System: The UNT Digital Library
Navy LPD-17 Amphibious Ship Procurement: Background, Issues, and Options for Congress (open access)

Navy LPD-17 Amphibious Ship Procurement: Background, Issues, and Options for Congress

This report discusses the Navy's FY2011-FY2015 shipbuilding plan that calls for procuring an 11th and final San Antonio (LPD-17) class amphibious ship in FY2012. This report discusses the procurement cost estimates of this ship, as well as related issues for Congress.
Date: March 29, 2010
Creator: O'Rourke, Ronald
Object Type: Report
System: The UNT Digital Library
Navy Nuclear-Powered Surface Ships: Background, Issues, and Options for Congress (open access)

Navy Nuclear-Powered Surface Ships: Background, Issues, and Options for Congress

This report discusses the possibility of increasing the number of Navy surface ships powered by nuclear energy, including the Navy's planned CG(X) cruiser. The report explores a 2006 Navy study that discusses budget considerations, the cost of a nuclear-powered ship compared to a ship powered by crude oil, and other suggestions relating to this proposed expansion. The overall report has a specific emphasis on the planned CG(X) cruiser, and how the implementation of this cruiser may be delayed by current budget proposals.
Date: March 29, 2010
Creator: O'Rourke, Ronald
Object Type: Report
System: The UNT Digital Library
The Oklahoma Daily (Norman, Okla.), Vol. 95, No. 123, Ed. 1 Monday, March 29, 2010 (open access)

The Oklahoma Daily (Norman, Okla.), Vol. 95, No. 123, Ed. 1 Monday, March 29, 2010

Student newspaper of the University of Oklahoma in Norman, Oklahoma that includes national, local, and campus news along with advertising.
Date: March 29, 2010
Creator: Hughes, Jamie
Object Type: Newspaper
System: The Gateway to Oklahoma History
Oral History Interview with Earl Morrison, March 29, 2010 transcript

Oral History Interview with Earl Morrison, March 29, 2010

The National Museum of the Pacific War presents an interview with Earl Morrison. Morrison joined the Navy around 1944. He completed Radio Technician School and was assigned aboard the USS Auriga (AK-98). They traveled to Laguna in the Philippines. In April of 1945 they delivered troops, goods and equipment to Okinawa during the invasion. They also traveled to Kwajalein, Guam and Espiritu Santo where they learned of the Japanese surrendering. Morrison was discharged in 1946.
Date: March 29, 2010
Creator: Morrison, Earl
Object Type: Sound
System: The Portal to Texas History
Oral History Interview with Earl Morrison, March 29, 2010 (open access)

Oral History Interview with Earl Morrison, March 29, 2010

The National Museum of the Pacific War presents an interview with Earl Morrison. Morrison joined the Navy around 1944. He completed Radio Technician School and was assigned aboard the USS Auriga (AK-98). They traveled to Laguna in the Philippines. In April of 1945 they delivered troops, goods and equipment to Okinawa during the invasion. They also traveled to Kwajalein, Guam and Espiritu Santo where they learned of the Japanese surrendering. Morrison was discharged in 1946.
Date: March 29, 2010
Creator: Morrison, Earl
Object Type: Text
System: The Portal to Texas History
Regulation of Yersina pestis Virulence by AI-2 Mediated Quorum Sensing (open access)

Regulation of Yersina pestis Virulence by AI-2 Mediated Quorum Sensing

The proposed research was motivated by an interest in understanding Y. pestis virulence mechanisms and bacteria cell-cell communication. It is expected that a greater understanding of virulence mechanisms will ultimately lead to biothreat countermeasures and novel therapeutics. Y. pestis is the etiological agent of plague, the most devastating disease in human history. Y. pestis infection has a high mortality rate and a short incubation before mortality. There is no widely available and effective vaccine for Y. pestis and multi-drug resistant strains are emerging. Y. pestis is a recognized biothreat agent based on the wide distribution of the bacteria in research laboratories around the world and on the knowledge that methods exist to produce and aerosolize large amounts of bacteria. We hypothesized that cell-cell communication via signaling molecules, or quorum sensing, by Y. pestis is important for the regulation of virulence factor gene expression during host invasion, though a causative link had never been established. Quorum sensing is a mode of intercellular communication which enables orchestration of gene expression for many bacteria as a function of population density and available evidence suggests there may be a link between quorum sensing and regulation of Y. pesits virulence. Several pathogenic bacteria have been …
Date: March 29, 2010
Creator: Segelke, B; Hok, S; Lao, V; Corzett, M & Garcia, E
Object Type: Report
System: The UNT Digital Library
Russian Contract Procurement Document (open access)

Russian Contract Procurement Document

This contract supports the enhancement of physical protection or nuclear material control and accounting systems at institutes or enterprises of the newly independent states under the material protection control and accounting (MPC&A) program. The contract is entered into pursuant to the MPC&A Program, a gratuitous technical assistance program, in accordance with the bilateral Agreements between the Russian Federation and the United States of America concerning the Safe and Secure Transportation, Storage and Destruction of Weapons and the Prevention of Weapons Proliferation of June 1992, as extended and amended by Protocol signed of June 1999, Agreement between the Government of the Russian Federation regarding Cooperation in the Area of Nuclear Materials Physical Protection, Control and Accounting of October 1999 and the Russian Federation law of May 1999 on the taxation exemption of gratuitous technical assistance with Russian Federation under registration No.DOE001000.
Date: March 29, 2010
Creator: Tobin, J G
Object Type: Report
System: The UNT Digital Library
Short Wavelength Seeding through Compression for Fee Electron Lasers (open access)

Short Wavelength Seeding through Compression for Fee Electron Lasers

In this paper, we propose a seeding scheme that compresses an initial laser modulation in the longitudinal phase space of an electron beam by using two opposite sign bunch compressors and two opposite sign energy chirpers. This scheme could potentially reduce the initial modulation wavelength by a factor of C and increase the energy modulation amplitude by a factor of C , where Cis the compression factor of the first bunch compressor. Using two lasers as energy chirpers, such a modulation compression scheme can generate kilo-Ampershort wavelength current modulation with significant bunching factor from an initial a few tens Amper current. This compression scheme can also be used togenerate a prebunched single atto-second short wavelength current modulation and prebunched two color, two atto-second modulations.
Date: March 29, 2010
Creator: Qiang, Ji
Object Type: Article
System: The UNT Digital Library
Sweetwater Reporter (Sweetwater, Tex.), Vol. 112, No. 114, Ed. 1 Monday, March 29, 2010 (open access)

Sweetwater Reporter (Sweetwater, Tex.), Vol. 112, No. 114, Ed. 1 Monday, March 29, 2010

Daily newspaper from Sweetwater, Texas that includes local, state, and national news along with advertising.
Date: March 29, 2010
Creator: unknown
Object Type: Newspaper
System: The Portal to Texas History