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Polymerization in Solid Solutions of Acrylamide in Propionamide (open access)

Polymerization in Solid Solutions of Acrylamide in Propionamide

It has previously been shown that the polymer formed in solid state polymerization of acrylamide is amorphous in spite of the fact that the reaction takes place within a crystalline solid. The stage at which it becomes amorphous is not known at present. Work with dilute solid solutions of acrylamide in propionamide suggests that this occurs after the addition of, at most, a very few monomer units.
Date: March 26, 1963
Creator: Adler, G. & Reams, W.
System: The UNT Digital Library
Disposition of Radiation Products and Energy Transfer in Radiobiological Processes (open access)

Disposition of Radiation Products and Energy Transfer in Radiobiological Processes

Technical report outlining the nature and effects of energy loss and radiation in biological materials during radiobiological processes.
Date: March 28, 1962
Creator: Augenstine, L. G.
System: The UNT Digital Library
Numerical Solutions for Diffusion in a Sphere, Cylinder, and Plate (open access)

Numerical Solutions for Diffusion in a Sphere, Cylinder, and Plate

In calculating diffusion coefficients for gases diffusing from solids, the numerical solutions tabulated by Darken and Gurry, were found to lack the required precision, and the intervals between the arguments were too great to permit precise interpolations. Consequently the diffusion equation solutions of interest (diffusion from a sphere, cylinder, and plate, for the condition that the concentration of the diffusing species initially uniform) were re-evaluated. Computer programs for the three cases were written in FORTRAN for the IBM 7090. The solutions programmed are given in Crank. Values of the fractional completion were computed at approximately 0.01 increments, to the nearest 0.00001, and are tabulated in Table 1 to the nearest 0.0001. The table covers the fractional range from about 0.04 to 0.99. For smaller fractions satisfactory approximations are available. The table may be conveniently interpolated by plotting points about the region of interest and drawing a curve.
Date: March 8, 1963
Creator: Auskern, Allan
System: The UNT Digital Library
A Versatile Bubble-Chamber Track Measuring Stage (open access)

A Versatile Bubble-Chamber Track Measuring Stage

Technical report describing a bubble chamber film track measuring stage designed for maximum versatility that was build at Brookhaven National Laboratory. The report includes photographs and diagrams of the device.
Date: March 1962
Creator: Ayer, Frederick, II & Bolze, Ernest M.
System: The UNT Digital Library
A Bubble Chamber Track-Centering Device with Digitized Output (open access)

A Bubble Chamber Track-Centering Device with Digitized Output

Technical report describing "A means for automatically determining the coordinates of a point at the center of a bubble chamber track." from the abstract.
Date: March 1962
Creator: Ayer, Frederick.; Pickup, Eric.; Rappe, Edwin F. & Wall, Gaylord.
System: The UNT Digital Library
Alternating Gradient Magnets (open access)

Alternating Gradient Magnets

The angle by which a magnet deflects the trajectory of a particle in the x-z plane is proportional to the integral [integral not transcribed] taken over the trajectory wherever B≠0. Alternating gradient focusing is achieved by designing magnets so that I=I(x) varies linearly with x over a suitable x interval. Usually this is done by shaping the poles to give a linear variation of By with x while keeping the length of the magnet constant for different x. Certain advantaged may be gained by varying the effective length of the magnet with x and keeping By constant so that the integral varies properly with x. Figure 1 shows several such poles for which the trajectory length, and hence the integral (1), varies approximately from 2/3 to 4/3 of the mean value.
Date: March 3, 1963
Creator: Beth, R. A.
System: The UNT Digital Library
Long Coil Measurements Satisfy Two-Dimensional Field Equations (open access)

Long Coil Measurements Satisfy Two-Dimensional Field Equations

The amount by which the field of a magnet bends the path of a charged particle is proportional to the integral of Btds along the trajectory. Instead of making tedious point by point measurements of B in magnets and performing the integrations numerically, it has been found useful to measure directly, by using a search coil whose winding consists of long and narrow turns extending through the magnet gap from z1 and z2 in the direction of the trajectory. It should be noted that the integral Iy is taken along a straight x=constant, y=constant lines and not along the actual curved trajectory path; for small curvature the difference is small.
Date: March 8, 1963
Creator: Beth, R. A.
System: The UNT Digital Library
Radiation - Induced Mammary Gland Neoplasia in the Rat (open access)

Radiation - Induced Mammary Gland Neoplasia in the Rat

In discussing this subject, data on radiation induced mammary gland neoplasia in the rat indicating that direct interaction between the radiation and target tissue is necessary for maximum neoplasia induction will be presented mainly. Other types of radiation induced neoplasia, in which little or no information on the mechanisms involved is available, will be discussed briefly. In particular, investigations on radiation induced mouse lymphoma will be reviewed, in which neoplasia appears to be an abscopal effect. Implications of these data will be discussed, particularly with regard to possible mechanisms involved, and extrapolation to man.
Date: March 6, 1963
Creator: Bond, V. P.; Cronkite, E. P.; Shellabarger, C. A. & Aponte, G.
System: The UNT Digital Library
Study of Low Frequency Molecular Motions in HF, KHF2, KH2F3 and NaH2F3 (open access)

Study of Low Frequency Molecular Motions in HF, KHF2, KH2F3 and NaH2F3

The spectra of KHF2, KH2F3, NaH2F3, liquid and solid HF were measured between 1200 and 30 cm-1 by the inelastic scattering of "cold neutrons" (0.005e.v.). The spectrum of KHF2 is in agreement with previous infrared measurements and shows a peak at 147 mV corresponding to a deformation frequency v2 of the F-H-F group and a broad peak at 13 mV due to a libration of this group. The observed spectra for KH2F3, NaH2F3 solid and liquid HF were compared with that for KHF2 considering the known results that the F-F distance increases, the position of the H atom between the two fluorines becomes more asymmetrical, and the strength of the hydrogen bond decreases in going from the HF2- ion to H2F3- ion to HF. In this comparison the known structure of the H2F3- ion is considered as being intermediate between that of HF2- and the zig-zag hydrogen bonded chains in solid HF. As a result, the lines observed at 112 mV and 67 mV in the H2F3- spectra and in HF respectively are associated with the deformation frequency v2 of the H-F-H group in these compounds. In addition the spectra of H2F3- ions show a peak at a 15 mV …
Date: March 12, 1963
Creator: Boutin, Henri & Safford, G. J.
System: The UNT Digital Library
Four Short Articles on Genetics of Maize (open access)

Four Short Articles on Genetics of Maize

Studies carried on since 1956 indicate that the prosaic breeding procedure of sibbing among the most perennial segregates in the hybrid of 4n maize x 4n perennial teosinte quickly restores perennialism to 50% maize tetraploids through increasing the expression of the rhizomatous habit under selection pressure. Similarly, only two generations of selection at the 75% maize level have resulted in a progressive recovery of the perennial expressive. A high degree of maize-likeness therefore appears to be compatible with the perennial expression at the 4n level.
Date: March 12, 1963
Creator: Brookhaven National Laboratory
System: The UNT Digital Library
Static Corrosion Behavior of Construction Materials in an Environment of Liquid Bismuth Base Metals at 550° C (open access)

Static Corrosion Behavior of Construction Materials in an Environment of Liquid Bismuth Base Metals at 550° C

Technical report presenting preliminary results obtained in the static corrosion test program to screen promising construction materials for a proposed liquid fuel power breeder reactor.
Date: March 1, 1952
Creator: Cordovi, M. A.
System: The UNT Digital Library
A Preliminary Report on Health Physics Problems at the Brookhaven Alternating Gradient Synchrotron (AGS) (open access)

A Preliminary Report on Health Physics Problems at the Brookhaven Alternating Gradient Synchrotron (AGS)

This report discusses the alternating gradient synchrotron at Brookhaven National Laboratory and provides a preliminary discussion on experiences to date and experiments in progress.
Date: March 5, 1962
Creator: Cowan, F. P.
System: The UNT Digital Library
Personnel Dosimetry of Very High Energy Radiation (open access)

Personnel Dosimetry of Very High Energy Radiation

Before discussing personnel monitoring of high energy radiations, it is appropriate to comment briefly on two basic methods of dosimetry applicable to such situations. In the first of these methods, one measures the rad dose in air with a tissue-equivalent ionization chamber that is operated with enough voltage on the collecting electrode to insure saturation even when the radiation is concentrated in short pulses, as is frequently the case. The linear energy transfer (LET) spectrum of the radiation is then determined and an average value of relative biological effectiveness (RBE) is determined. An experimental evaluation of the depth dose situation completes the data necessary for a full evaluation of the biological hazards. The method is completely general but is most applicable to situations where a substantial proportion of high energy components is present in the mixed radiation. It should be noted that the detailed composition of the radiation need not be known. Thus, components of dosage to which an RBE of 1 is assigned may be due to X-rays, gamma rays, or the ionization tracks produced by protons in the Gev energy range as well as by many other types of radiation. This method is applied frequently to the situation …
Date: March 8, 1963
Creator: Cowan, Fredrick P.
System: The UNT Digital Library
Data Formats and Procedures for the ENDF Neutron Cross Section Library (open access)

Data Formats and Procedures for the ENDF Neutron Cross Section Library

Report issued by the Brookhaven National Laboratory discussing the formats and procedures used at the ENDF Neutron Cross Section Library. As stated in the introduction, "this report describes the philosophy, data formats, and procedures that have been developed for the Evaluated Nuclear Data File (ENDF)" (p. 1-1). This report includes tables, and illustrations.
Date: March 1971
Creator: Drake, M. K. & Honeck, Henry C.
System: The UNT Digital Library
On the Structure of Sperm Whale Myoglobin. [Part] 1, The Amino Acid Composition and Terminal Groups of the Chromatographically Purified Protein (open access)

On the Structure of Sperm Whale Myoglobin. [Part] 1, The Amino Acid Composition and Terminal Groups of the Chromatographically Purified Protein

The report objective is to establish the amino acid composition of sperm whale myoglobin. From Summary: "The homoprotein that comprises 96% by weight of the protein present in crystalline sperm whale myoglobin may be received into at least five components by chromatography on the carboxylic resin IRC-50."
Date: March 26, 1962
Creator: Edmundson, A. B. & Hirs, C. H. W.
System: The UNT Digital Library
Neutron Sources - Cross Sections and Angular Distributions (open access)

Neutron Sources - Cross Sections and Angular Distributions

It is appropriate that a conference devoted to the interactions of fast neutrons with nuclei begin with a survey of the available sources of such neutrons. Since its discovery in 1932, the neutron has provided a highly useful tool in attempts to understand the nucleus, and the types of nuclear phenomenon which could be studied and the nature of the results obtained are very dependent on the sources available.
Date: March 8, 1963
Creator: Goldberg, Murrey D.
System: The UNT Digital Library
Fundamentals of Vacuum Technology (open access)

Fundamentals of Vacuum Technology

Vacuum technology is germaine to and is utilized in an extroardinarily widespread scope of the scientific disciplines. From the medical technician freeze drying hog cholera vaccine to the solid state physicist studying thin film phenomena, vacuum technology is an important auxiliary. When one visits the NASA center at Langley and sees the clustered space environmental chambers, looking like a field of grotesque mushrooms, one realizes that vacuum technology is a vital adjunct in this most recent section of our total national scientific effort.
Date: March 26, 1963
Creator: Gould, C. L.
System: The UNT Digital Library
Secondary Tetanus Antitoxin Responses in Mice Elicited Prior to Irradiation (open access)

Secondary Tetanus Antitoxin Responses in Mice Elicited Prior to Irradiation

The pioneer study by Benjamin and Sluka in 1908 on inhibition of antibody formation by X-rays revealed the importance of the temporal relationship between exposure to radiation and injection of antigen. X-radiation delivered three days before injection of beef serum inhibited precipitin formation in rabbits. A similar exposure to X-rays delivered three days after injection of the antigen failed to repress production of specific antibody. These observations were partially confirmed in 1915 when Hektoen reported inhibition of hemolysin production in the rat when X-radiation was delivered either before or after injection of sheep red cells. Although an absolute difference in radiosensitivity was not evident, the depressant effect of radiation on antibody production appeared to be less effective when radiation was given after injection of the antigen.
Date: March 6, 1963
Creator: Hale, William M.
System: The UNT Digital Library
Structure of HCrO2 and DCrO2 (open access)

Structure of HCrO2 and DCrO2

A neutron diffraction study of polycrystalline HCrO2 and DCrO2 (chromous acid) is described. Intensity data from the two substances were refined together by the least-squares method, with the constraint that the Cr-O distance be the same in the two substances. Estimates of individual contributions to multiple peaks were included in the least-squares refinement through the use of a non-diagonal weight matrix. The O-D-O bond is found to be asymmetric, O-D = 0.96 ± 0.04 A, O...O - 2.55 ± 0.02 A. The symmetry of the O-H-O bond cannot be determined, but agreement with observation is as good with a symmetric bond as with any other model. The O-H-O bond length is 2.49 ± 0.02 A. These results are consistent with those from previous studies of the HCrO2-DCrO2 system by nuclear magnetic resonance and infrared techniques.
Date: March 8, 1963
Creator: Hamilton, Walter C. & Ibers, James A.
System: The UNT Digital Library
Hot-Atom Chemistry of the Solid StateL its History, Current Status and Future Prospects viewed in Relation to the Planning of Chemical Research Programs for New Scientific Establishments Centered about a Research Reactor (open access)

Hot-Atom Chemistry of the Solid StateL its History, Current Status and Future Prospects viewed in Relation to the Planning of Chemical Research Programs for New Scientific Establishments Centered about a Research Reactor

The History, Current Significance and Status of the Field Hot atom chemistry, like many other fields of scientific research, can trace its origin to a single experiment, that of Szilard and Chalmers, performed in 1934. This is true even though recoil effects had been known and used for a long time. Almost immediately Szilard and Chalmers put their discovery to practical use: they employed the recoil effect in ethyl iodide as a neutron detector and observed the γ,n reaction in beryllium. The ingenuity of Fermi soon provided the correct explanation of the chemical separation observed by Szilard and Chalmers, and Fermi's co-workers, especially D'Agostino put the effect to a further practical use: the preparation of radioisotopes in high specific activity. These Roman scientists carried out the first Szilard-Chalmers studies in solids (sodium bromate, chlorate, iodate, and perchlorate, cacodylic acid and potassium permanganate) and reported some quantitative results: for example a quite accurate recoil yield of 80% of the Mn 56 in potassium permanganate. Perhaps the most striking practical result of a Szilard-Chalmers experiment lay in the discovery, by Kourtchatow and co-workers, of the important isotope Br 82 in extracts from neutron-irradiated ethyl bromide.
Date: March 8, 1963
Creator: Harbottle, Garman
System: The UNT Digital Library
Mathematics of Intermittent Irradiation (open access)

Mathematics of Intermittent Irradiation

Initiation of reactions by intermittent irradiation is frequently encountered in physical, chemical, and biological systems. Mathematical expressions for transient and steady state concentrations of reactive species in these systems are useful for predicting performance and for research purposes. A general method of formulation of the intermittent irradiation problem is presented herein, and illustrative solutions are obtained for radioactive decay chains and for the rotating sector method.
Date: March 12, 1963
Creator: Hill, F. B.
System: The UNT Digital Library
Human Radiation Injury - a Correlation of Leukocyte Depression with Mortality in the Japanese Exposed to the Atomic Bombs (open access)

Human Radiation Injury - a Correlation of Leukocyte Depression with Mortality in the Japanese Exposed to the Atomic Bombs

The method of collection and the subsequent analysis of the hematological data accumulated by the Joint Commission of the Investigation of the Early Effects of the Atomic Bomb in Japan, have been described. In the present investigations, an additional analysis of the hematological data was made to investigate a possible relationship between leukopenia and the mortality rate within the first nine weeks following the bombings. It has been frequently observed in laboratory animals exposed to ionizing radiation that the extent of the fall in the white blood count reflects the dose of radiation received. Smith et al have demonstrated that in mice survival can be related to the depression of the granulocyte count at various times following radiation. Cronkite and Brecher and Cronkite, Bond and Dunham inferred that the hematological response could be used as a biologic dosimeter for exposed human beings. This report is concerned with the study of the response of the white blood cells to ionizing radiation resulting from the atomic bomb detonation in Japan.
Date: March 8, 1963
Creator: Jacobs, George J.; Lynch, Francis X.; Cronkite, Eugene P. & Bond, Victor P.
System: The UNT Digital Library
Parameters of the 132 eV Neutron Resonance in Co 59 (open access)

Parameters of the 132 eV Neutron Resonance in Co 59

An accurate determination of the parameters of the resonance excited by the interaction of the 132 eV neutrons with the Co 59 target nucleus has been made, using the fast choppers at Brookhaven National Laboratory in the United States and Chalk River Laboratory in Canada. Neutron transmission through thick and thin samples resulted in the following parameters: [parameters not transcribed]. In addition, measurements of the resonance capture γ-ray intensity gave the value for the radiation width Γγ= 0.40 ± 0.04 eV, based on the known thermal capture cross section of cobalt of 37.5 barns. The reduced and total resonance capture integrals are calculated from the above parameters to be 50.5 ± 5.5 and 67.0 ± 5.5 barns, respectively. The above results are compared with previously determined resonance parameters and also with direct measurements of the total resonance capture integral.
Date: March 25, 1963
Creator: Jain, A. P.; Chrien, R. E.; Moore, J. A. & Palevsky, H.
System: The UNT Digital Library
Diffraction Studies of Possible Ordering in α-brass (open access)

Diffraction Studies of Possible Ordering in α-brass

Recently, there has been some evidence to point to possible ordering in the α-brasses. Masumoto et al. have concluded from their specific heat measurements that there is a possibility of ordering in the α-brasses. In particular they observed an anomaly in the specific heat curves for the α-brasses for the temperature range from 200 to 260°C and explained these results upon the basis of a change in local or short range order in α-brasses at these temperatures. In connection with the study of radiation damage effects in α-brass ordering has been suspected. Rosenblatt has annealed 70-30 α-brass previously annealed at 350°C and cooled to room temperature at 190°C for six weeks. He observed a decrease of .90 ± .03% in the electrical resistivity of α-brass measured at -196°C after the anneal at 190°C.
Date: March 29, 1954
Creator: Keating, David, T.
System: The UNT Digital Library