A final series of runs was made in a four-inch continuous-flow mixing chamber to study the transfer of isobutanol into water and nitrobenzene into ethylene glycol. Satisfactory techniques were developed to provide for the rapid analysis of these systems. In addition, a light-scattering correlation was prepared to provide a measure of the interfacial area of the yellow-colored nitrobenzene-ethylene glycol mixtures.

The table of sin θ and sin2 θ, to five decimal places for every hundreth of a degree from 2°-87°, has been prepared for the use of Professor W. H. Zachariasen in his X-ray diffraction studies. [Tables not transcribed]

The Internal exponential Exponential Experiment (ZPR-V) will be constructed by loading up to 49 of the fuel cans, containing up to 155 kg of U235, of the present Fast Exponential Experiment in a 22-in. square iron tank, surrounded by an annular thermal region of fully enriched light water lattice 10 to 15 cm thick. This assembly will be placed in a 5-ft diameter tank which will, in turn, be located in the 10-ft diameter ZPR-II tank, the annular space between the outer tanks containing water for shielding. The new experiment will be a well-shielded, strongly coupled fast-thermal system. It will be possible to make measurements that cannot be made on the present Fast Exponential Experiment. One category of such determinations is the study of reactivity effects produced in the fast core, including control scheme studies and danger coefficient and oscillator measurements of such effects as Doppler coefficients and effect of lumping and streaming. The higher flux and excellent shielding will make beam studies of energy spectrum practical. Additional foil activations will be possible. Characteristics of mixed fast-thermal systems, which are of potential importance as power breeders, can be studied.

This quarterly report discusses ongoing research and experiments at Oak Ridge National Laboratory in the Metallurgy Division. This report discusses water cooled reactors, liquid metal cooled reactors, reactor development metallurgy, basic metallurgy, applied metallurgy, and aqueous corrosion.

The use of bromine trifluoride solution has been investigated for the preparation of purified uranium hexafluoride from ore concentrates. The best yields were obtained with the use of antimony pentafluoride solutions in bromine trifluoride, and less fluorine was consumed in the case of previously hydro fluorinated samples. This approach appears to be technologically sound and may prove economically superior to existing procedures in the case of newly constructed facilities.

The cup assembly of the Experimental Breeder Reactor (EBR) consists of blanket bricks, inner rings, and safety plug, all of natural uranium. The design of the finish machined brick is shown in Figure 1. These pie shaped bricks when stacked together, 12 bricks arranged in circular form and stacked seven rings high, comprise the cylindrical portion of the outer blanket, 17.875" I.D. x 30.875" O.D. after machining and canning. The inner ring, which is shown in Figure 2, fits inside the bottom layer of bricks. The circular opening in the center of the inner ring is closed by the safety plug shown in Figure 3.

Report issued by the Argonne National Laboratory covering the quarterly report from the Reactor Engineering Division. A summary of reactor programs, research, designs, development, and experiments are presented. This report includes tables, illustrations, and photographs.

This supplement includes reports on (1) transmission measurements with the fast chopper, (2) a search for Pu244, (3) crystallographic studies, (4) resonance flux in CP-[gamma], (5) multigroup methods for concentrated fast assemblies, (6) work on the ZPR-1 Reactor, and (7) work on the ZPR-II Reactor.

The growth of alpha-rolled uranium rods on thermal cycling has been shown to depend on both preferred orientation and grain size. Preferred orientation appears to be a necessary condition for growth to occur; the extent of the growth depends upon the sharpness and type of texture developed and on the grain size. The highest growth rates occur in specimens with highly developed textures coupled with small grain sizes. The growth rates increase with cycling level, particularly in specimens of large grain size.

The susceptibleness of certain "ceramic" substances to extreme radiation damage (such as that observed in graphite) as indicated by changes in dimensions and heat content is discussed in terms of the experimental evidence which is available.

Report on research and development of the lead-acid battery for electric vehicle propulsion, focusing on continuing development on the forced electrolyte flow-through concept with some work on the composite, plastic/lead grid.

A Ca-Al-Si/FeS2 cell has been developed and has exhibited reasonably stable capacity through 3200 h of operation. This system is expected to be capable of meeting the ultimate performance goals (i.e., 160 W.h/kg) of this development program. Further tests of this cell system in the coming year will better define its ultimate performance capabilities.

A combination of backscattered electron imaging and analytical electron microscopy (AEM) with electron diffraction have been used to determine the physical and chemical properties of uranium contamination in soils from the Fernald Environmental Management Project in Ohio. The information gained from these studies has been used in the development and testing of remediation technologies.

A program has been established for DOE Environmental Restoration and Waste Management (EM) to evaluate factors that are likely to affect waste glass reaction during repository disposal, with emphasis on an unsaturated environment typical of what may be expected for the proposed Yucca Mountain repository site.

This report discusses the adequacy of several nondestructive evaluation techniques for the detection of flaws in silicon carbide heat-exchanger tubing. Experimental results have been obtained for conventional ultrasonic testing, acoustic microscopy, conventional and dye-enhanced radiography, holographic interferometry, infrared scanning and internal-friction measurements.

This report covers the research, development, and management activities of the programs at Argonne National Laboratory (ANL) and at contractors' laboratories on high-temperature batteries during the period October 1978-September 1979. These batteries are being developed for electric-vehicle propulsion and for stationary energy-storage applications. The present cells, which operate at 400-500 C, are of a vertically oriented, prismatic design with one or more inner positive electrodes of FeS or FeS2, facing negative electrodes of lithium-aluminum or lithium-silicon alloy, and molten LiCl-KC1 electrolyte.

Ptolemy is an IBM/360 program for the computation of nuclear elastic and direct-reaction cross sections. It carries out both optical-model fits to elastic-scattering data at one or more energies, and DWBA calculations for nucleon-transfer reactions. Ptolemy has been specifically designed for heavy-ion calculations. It is fast and does not require large amounts of core. The input is exceptionally flexible and easy to use. This report outlines the types of calculation that Ptolemy can carry out, summarizes the formulas used, and gives a detailed description of its input.

A procedure is described for the dynamic analysis of a fast-reactor hexagonal subassembly. The internals of the fuel subassembly are treated by an axisymmetric hydrodynamic code REXCO-HT which, among other properties, possesses a model of an MFCI pressure source. The housing of the fuel subassembly is handled by the SADCAT code, which is based on a triangular finite element in three-dimensional space. The code is used to illustrate the discrepancies involved if the hexcan is modeled by a cylinder of the same thickness. A study is also made of the reduction of cylinder thickness such that the same final cylindrical deformation can be predicted. A discussion in arriving at such an equivalence is offered.

Various mechanisms that can induce flow instabilities in two-phase flow systems are reviewed and their relative importance discussed. In view of their practical importance, the density-wave instabilities have been analyzed in detail based on the one-dimensional two-phase flow formulation. The dynamic response of the system to the inlet flow perturbations has been derived from the model; thus the characteristic equation that predicts the onset of instabilities has been obtained. The effects of various system parameters, such as the heat flux, sub-cooling, pressure, inlet velocity, inlet orificing, and exit orificing on the stability boundary have been analyzed. In addition to numerical solutions, some simple stability criteria under particular conditions have been obtained. Both results have been compared with various experimental data, and a satisfactory agreement has been demonstrated.

The interim report presented describes a continuation of the work reported in ANL-7890, Interaction of Sodium with Molten Uranium dioxide and Stainless Steel Using a Dropping Mode of Contact. In the current study, sodium was injected into a pool of molten uranium dioxide. The experiment consistently produced vapor explosions, both with the injection nozzle above and beneath the surface of the uranium dioxide. Although the efficiency of the conversion of thermal to mechanical energy was small (due in part to very conservative data analysis and an inefficient geometry), the results did demonstrate that there is no intrinsic reason why reactor materials cannot produce a vapor explosion.

About 1200 Mark II driver-fuel elements were xenon-tagged to facilitate qualification for irradiation of Mark II fuel manufactured at ANL-West. Tagging equipment was designed and developed. In this equipment, the plenum in a fuel-element jacket was evacuated then filled with xenon to a predetermined pressure. The equipment design allows tagging and element fabrication to proceed normal rates for production of fuel elements. A Kr-85 tracer in the xenon-tag gas verified by gamma counting the adequate tagging of each element.

Annual report of the environmental monitoring program at Argonne National Laboratory, discussing activities and findings of the group.

This course seeks to achieve two objectives: to provide initial safety training for people just beginning work with plutonium, and to serve as a review and reference source for those already engaged in such work. Numerous references have been included to provide information sources for those wishing to pursue certain topics more fully. The first part of the course content deals with the general safety approach used in dealing with hazardous materials. Following is a discussion of the four properties of plutonium that lead to potential hazards: radioactivity, toxicity, nuclear properties, and spontaneous ignition. Next, the various hazards arising from these properties are treated. The relative hazards of both internal and external radiation sources are discussed, as well as the specific hazards when plutonium is the source. Similarly, the general hazards involved in a criticality, fire, or explosion are treated. Comments are made concerning the specific hazards when plutonium is involved. A brief summary comparison between the hazards of the trans-plutonium nuclides relative to plutonium-239 follows. The final portion deals with control procedures with respect to contamination, internal and external exposure, nuclear safety, and fire protection. The philosophy and approach to emergency planning are also discussed.

This report is a compilation of the formal Final Safety Analysis Addenda (FSAA's) to the EBR-II Hazard Summary Report and Addendum that have been prepared in support of certain modifications to the reactor-shutdown-system portion of the EBR-II plant protection system. Each major section is an edited version of the original FSAA for a particular modification and provides a description of the pre - and post -modification system, the rationale for the modification, and required supporting safety analysis.