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Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe₃(CO)₇(μ-edt)₂] and Phosphine Derivatives [Fe₃(CO)₇−ₓ(PPh₃)ₓ(μ-edt)₂] (x = 1, 2) and [Fe₃(CO)₅(κ²‑diphosphine)(μ- edt)₂] as Proton Reduction Catalysts (open access)

Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe₃(CO)₇(μ-edt)₂] and Phosphine Derivatives [Fe₃(CO)₇−ₓ(PPh₃)ₓ(μ-edt)₂] (x = 1, 2) and [Fe₃(CO)₅(κ²‑diphosphine)(μ- edt)₂] as Proton Reduction Catalysts

This article describes the preparation and structural characterization of the mixed-valence triiron complexes.
Date: July 15, 2013
Creator: Rahaman, Ahibur; Ghosh, Shishir; Unwin, David G.; Basak-Modi, Sucharita; Holt, Katherine B.; Kabir, Shariff E. et al.
Object Type: Article
System: The UNT Digital Library
Isomerization of the osmium-tellurium cluster Os₃(𝜇-TeR)₂(CO)₁₀: a kinetic and computational study (open access)

Isomerization of the osmium-tellurium cluster Os₃(𝜇-TeR)₂(CO)₁₀: a kinetic and computational study

This article discusses the kinetics for the isomerization of the 50e cluster Os₃(𝜇-TeTol-p)₂(CO)₁₀ as measured experimentally by H NMR spectroscopy.
Date: February 12, 2016
Creator: Shim, E. K. S.; Leong, W. K.; Li, Y. -Z. & Richmond, Michael G.
Object Type: Article
System: The UNT Digital Library
Electrodeposition of Cu-Ni Composite Coatings (open access)

Electrodeposition of Cu-Ni Composite Coatings

This book chapter reviews the electrodeposition of Cu-Ni incorporated with nano- to microparticles to produce metal matrix composites.
Date: March 23, 2016
Creator: Thurber, Casey; Mohamed, Adel M. A. & Golden, Teresa
Object Type: Book Chapter
System: The UNT Digital Library
Redox Non-Innoence Permits Catalytic Nitrene Carbonylation by (dadi)Ti=NAd (Ad = Adamantyl) (open access)

Redox Non-Innoence Permits Catalytic Nitrene Carbonylation by (dadi)Ti=NAd (Ad = Adamantyl)

This article describes (dadi)Ti(X/L) species that manifest redox non-innocence (RNI), including a rare instance in which carbon monoxide does not affect redox activity at the metal, and does not bind, thus permitting its use as a substrate in catalysis.
Date: March 3, 2017
Creator: Heins, Spencer P.; Wolczanski, Peter T.; Cundari, Thomas R., 1964- & MacMillan, Samantha N.
Object Type: Article
System: The UNT Digital Library
Adsorption and molecular siting of CO₂, water, and other gases in the superhydrophobic, flexible pores of FMOF-1 from experiment and simulation (open access)

Adsorption and molecular siting of CO₂, water, and other gases in the superhydrophobic, flexible pores of FMOF-1 from experiment and simulation

This article discusses the use of neutron diffraction and molecular simulations to investigate the framework expansion behaviour and the accessibility of the small pockets to N₂, O₂, and CO₂.
Date: March 9, 2017
Creator: Moghadam, Peyman Z.; Ivy, Joshua F.; Arvapally, Ravi K.; dos Santos, Antonio M.; Pearson, John C.; Zhang, Li et al.
Object Type: Article
System: The UNT Digital Library
Pharmaceuticals Solubility is Still Nowadays Widely Studied Everywhere (open access)

Pharmaceuticals Solubility is Still Nowadays Widely Studied Everywhere

This editorial discusses the importance of equilibrium solubility in pharmaceutical areas.
Date: March 2017
Creator: Martínez, Fleming
Object Type: Article
System: The UNT Digital Library

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 2. C11-C192.

This article updates the second part of a compendium of phase change enthalpies published in 2010 to include the period 1880-2015.
Date: March 8, 2017
Creator: Acree, William E. (William Eugene) & Chickos, James S.
Object Type: Article
System: The UNT Digital Library
Discharge-Flow/Chemiluminescence and Flash-Photolysis/Resonance Fluorescence Studies of the Reaction O + SiH4 at Room Temperature (open access)

Discharge-Flow/Chemiluminescence and Flash-Photolysis/Resonance Fluorescence Studies of the Reaction O + SiH4 at Room Temperature

Article on discharge-flow/chemiluminescence and flash-photolysis/resonance fluorescence studies of the reaction O + SiH4 at room temperature.
Date: March 1, 1993
Creator: Taylor, Craig A.; Ding, Luying & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Rate Constant and Thermochemistry for K + O2 + N2 = KO2 + N2 (open access)

Rate Constant and Thermochemistry for K + O2 + N2 = KO2 + N2

This article discusses rate constant and thermochemistry for K + O2 + N2 = KO2 + N2.
Date: March 31, 2015
Creator: Sorvajärvi, Tapio; Viljanen, Jan; Toivonen, Juha; Marshall, Paul & Glarborg, Peter
Object Type: Article
System: The UNT Digital Library
Acid-Base Indicators: Transition Colours and pH Ranges Determined in Select Aqueous-Organic Mixed Solvents (open access)

Acid-Base Indicators: Transition Colours and pH Ranges Determined in Select Aqueous-Organic Mixed Solvents

Article on acid-base indicators and transition colours and pH ranges determined in select aqueous-organic mixed solvents.
Date: March 28, 1995
Creator: Tucker, Sheryl A. (Sheryl Ann); Bates, Heather C. & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Fuel-nitrogen conversion in the combustion of small amines using dimethylamine and ethylamine as biomass-related model fuels (open access)

Fuel-nitrogen conversion in the combustion of small amines using dimethylamine and ethylamine as biomass-related model fuels

Article on fuel-nitrogen conversion in the combustion of small amines using dimethylamine and ethylamine as biomass-related model fuels.
Date: March 21, 2012
Creator: Lucassen, Arnas; Warkentin, Julia; Moshammer, Kai; Glarborg, Peter; Marshall, Paul & Kohse-Höinghaus, Katharina
Object Type: Article
System: The UNT Digital Library
Computational studies of the reactions of CH3I with H and OH (open access)

Computational studies of the reactions of CH3I with H and OH

Article on computational studies of the reactions of CH3I with H and OH.
Date: March 26, 1998
Creator: Marshall, Paul; Misra, Ashutosh & Berry, Rajiv
Object Type: Article
System: The UNT Digital Library
High-Temperature Kinetics of the Reaction between Chlorine Atoms and Hydrogen Sulfide (open access)

High-Temperature Kinetics of the Reaction between Chlorine Atoms and Hydrogen Sulfide

Article on high-temperature kinetics of the reaction between chlorine atoms and hydrogen sulfide.
Date: March 16, 2015
Creator: Gao, Yide; Alecu, I. M.; Goumri, Abdellatif & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
An Investigation of the Gas-Phase Reaction of Atomic Bromine with Disilane: Implications for the Si2H5-H Bond Strength (open access)

An Investigation of the Gas-Phase Reaction of Atomic Bromine with Disilane: Implications for the Si2H5-H Bond Strength

Article on an investigation of the gas-phase reaction of atomic bromine with disilane and implications for the Si2H5-H bond strength.
Date: March 19, 1993
Creator: Goumri, Abdellatif; Yuan, W. J.; Ding, Luying & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
The hydrogen bond properties of water from 273 K to 573 K; equations for the prediction of gas-water partition coefficients (open access)

The hydrogen bond properties of water from 273 K to 573 K; equations for the prediction of gas-water partition coefficients

Article on the hydrogen bond properties of water from 273 K to 573 K and equations for the prediction of gas-water partition coefficients.
Date: March 29, 2012
Creator: Abraham, M. H. (Michael H.) & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Solubility in Binary Solvent Systems 3: Predictive Expressions Based on Molecular Surface Areas (open access)

Solubility in Binary Solvent Systems 3: Predictive Expressions Based on Molecular Surface Areas

Article on solubility in binary solvent systems III and predictive expressions based on molecular surface areas.
Date: March 1, 1983
Creator: Acree, William E. (William Eugene) & Rytting, J. Howard
Object Type: Article
System: The UNT Digital Library
Polycyclic Aromatic Hydrocarbon Solute Probes. Part IX: Evaluation of Additional Pentaphene, Pentacene, and Pyranthrene Compounds as Possible Solvent Polarity Probes (open access)

Polycyclic Aromatic Hydrocarbon Solute Probes. Part IX: Evaluation of Additional Pentaphene, Pentacene, and Pyranthrene Compounds as Possible Solvent Polarity Probes

Article on polycyclic aromatic hydrocarbon solute probes and an evaluation of additional pentaphene, pentacene, and pyranthrene compounds as possible solvent polarity probes.
Date: March 1, 1991
Creator: Tucker, Sheryl A. (Sheryl Ann); Zvaigzne, Anita I.; Acree, William E. (William Eugene); Fetzer, John Charles, 1953- & Zander, Maximilian
Object Type: Article
System: The UNT Digital Library
Investigation of the Gas-Phase Reaction of Trimethylsilyl Radicals with HBr: Measurement of the (CH₃)₃ Si-H Bond Strength (open access)

Investigation of the Gas-Phase Reaction of Trimethylsilyl Radicals with HBr: Measurement of the (CH₃)₃ Si-H Bond Strength

Article on an investigation of the gas-phase reaction of trimethylsilyl radicals with HBr and measurement of the (CH₃)₃ Si-H bond strength.
Date: March 1, 1993
Creator: Goumri, Abdellatif; Yuan, W. J. & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
A Theoretical Investigation of Donor-Acceptor Bonding between Amines and Silylenes (open access)

A Theoretical Investigation of Donor-Acceptor Bonding between Amines and Silylenes

Article on a theoretical investigation of donor-acceptor bonding between amines and silylenes.
Date: September 23, 1993
Creator: Conlin, Robert T.; Laakso, Dianna & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
High-Temperature Photochemistry Kinetics Studies of the Reactions of H(1²S) and D(1²S) with N₂O (open access)

High-Temperature Photochemistry Kinetics Studies of the Reactions of H(1²S) and D(1²S) with N₂O

Article on high-temperature photochemistry kinetics studies of the reactions of hydrogen atom(1²S) and deuterium atom (1²S) with nitrous oxide.
Date: March 1, 1989
Creator: Marshall, Paul; Ko, Taecho & Fontijn, A. (Arthur)
Object Type: Article
System: The UNT Digital Library
A High-Temperature Photochemistry Kinetics Study of the Reaction of O(³P) Atoms with Ethylene from 290 to 1510 K (open access)

A High-Temperature Photochemistry Kinetics Study of the Reaction of O(³P) Atoms with Ethylene from 290 to 1510 K

Article on a high-temperature photochemistry kinetics study of the reaction of oxygen(³P) atoms with ethylene from 290 to 1510 K.
Date: March 1, 1987
Creator: Mahmud, Khaled; Marshall, Paul & Fontijn, A. (Arthur)
Object Type: Article
System: The UNT Digital Library
An ab Initio Study of Sulfinic Acid and Related Species (open access)

An ab Initio Study of Sulfinic Acid and Related Species

Article on an ab initio study of sulfinic acid and related species.
Date: March 1, 1992
Creator: Laakso, Dianna & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Silane (open access)

Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Silane

Article on kinetic studies of the reactions of atomic chlorine and bromine with silane.
Date: March 1, 1992
Creator: Ding, Luying & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Predicting Abraham model solvent coefficients (open access)

Predicting Abraham model solvent coefficients

Article on predicting Abraham model solvent coefficients.
Date: March 22, 2015
Creator: Bradley, Jean-Claude; Abraham, M. H. (Michael H.); Acree, William E. (William Eugene) & Lang, Andrew S. I. D.
Object Type: Article
System: The UNT Digital Library