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Chemical and thermal stability of refrigerant-lubricant mixture with metal (open access)

Chemical and thermal stability of refrigerant-lubricant mixture with metal

This report presents completed sealed tube stability test results for the R-123/mineral oil mixture and preliminary results for seven of the eighteen contracted refrigerant-lubricant mixtures. The R-123 mixture was tested at 105, 150, and 175{degrees}C. The results obtained indicate that prolonged exposure to temperatures of about 150{degree}C and higher will lead to rapid chemical deterioration of the R-123/mineral oil system. Chlorotrifluoroethane (R-133a) and trifluoroethane (R-143a) have been identified as decomposition products of R-123. Testing at 150 and 175{degrees}C have been completed for the HCFC refrigerants R-22, R-124, and R-142b with either mineral oil or alkylbenzene lubricants. These mixtures were very stable at the indicated temperatures. Testing at a higher temperature level will be necessary to define their upper temperature limits. Similarily, partial test results are available for HFC refrigerants R-32, R-125, R-134a (two esters), and R-143a with pentaerythritol ester lubricants at the 150 and 175{degrees}C temperature levels. Again, all five mixtures were found to be extremely stable at the test temperatures and additional testing will be needed to establish their upper temperature limits.
Date: March 31, 1992
Creator: Huttenlocher, D.F. (Spauschus Associates, Inc., Atlanta, GA (United States))
Object Type: Report
System: The UNT Digital Library
Resonance Raman and photophysical studies of transition metal complexes in solution and entrapped in zeolites (open access)

Resonance Raman and photophysical studies of transition metal complexes in solution and entrapped in zeolites

We have obtained convincing evidence for localization of the optical electron on a single-ring fragment of a chelated bipyridine-like'' ligand (ie., pyridylpyrazine or 4-Methyl-bipyridine). In addition we have completed studies of Ru(bipyrazine){sub 3}{sup 2+} in aqueous sulfuric acid (0--98% by weight) and find clear evidence for sequential addition of six-protons to the six peripheral nitrogen atoms. Studies of zeolite-entrapped complexes are continuing and a series of homo- and heteroleptic complexes have been prepared and characterized. Finally, the synthesis of zeolite-entrapped metallophthalocyanines has now been developed and the copper and cobalt analogues synthesized. The characterization of these materials is now in progress.
Date: March 31, 1992
Creator: Kincaid, J.R.
Object Type: Report
System: The UNT Digital Library

[Photograph 2012.201.B0172.0177]

Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Edmond, Churches, First Baptist Church"
Date: March 31, 1992
Creator: Klock, Roger
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B0172.0176]

Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Edmond, Churches, First Baptist Church"
Date: March 31, 1992
Creator: Klock, Roger
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B0172.0180]

Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Edmond, Churches, First Baptist Church"
Date: March 31, 1992
Creator: Klock, Roger
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B0172.0181]

Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Angle iron is laid out for construction at the planned location of the First Baptist Church's new sanctuary at E 33rd and Bryant in Edmond."
Date: March 31, 1992
Creator: Klock, Roger
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B0172.0179]

Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Edmond, Churches, First Baptist Church"
Date: March 31, 1992
Creator: Klock, Roger
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B0172.0178]

Photograph used for a newspaper owned by the Oklahoma Publishing Company. Caption: "Edmond, Churches, First Baptist Church"
Date: March 31, 1992
Creator: Klock, Roger
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B0108.0588]

Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Jo Ann shows some of the brochures from the convention and visitors bureau in Edmond"
Date: March 31, 1992
Creator: Gooch, Steve
Object Type: Photograph
System: The Gateway to Oklahoma History
Particulate Matter Ambient Air Quality Data Report for 1989 and 1990 (open access)

Particulate Matter Ambient Air Quality Data Report for 1989 and 1990

None
Date: March 31, 1992
Creator: Radiological/Environmental Field Programs Department
Object Type: Report
System: The UNT Digital Library
SRP baseline hydrogeologic investigation: Aquifer characterization (open access)

SRP baseline hydrogeologic investigation: Aquifer characterization

An investigation of the mineralogy and chemistry of the principal hydrogeologic units and the geochemistry of the water in the principal aquifers at Savannah River Site (SRS) was undertaken as part of the Baseline Hydrogeologic Investigation. This investigation was conducted to provide background data for future site studies and reports and to provide a site-wide interpretation of the geology and geochemistry of the Coastal Plain Hydrostratigraphic province. Ground water samples were analyzed for major cations and anions, minor and trace elements, gross alpha and beta, tritium, stable isotopes of hydrogen, oxygen, and carbon, and carbon-14. Sediments from the well borings were analyzed for mineralogy and major and minor elements.
Date: March 31, 1992
Creator: Strom, R. N. & Kaback, D. S.
Object Type: Report
System: The UNT Digital Library
Texas Register, Volume 17, Number 24, Pages 2305-2351, March 31, 1992 (open access)

Texas Register, Volume 17, Number 24, Pages 2305-2351, March 31, 1992

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: March 31, 1992
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
SRP baseline hydrogeologic investigation: Aquifer characterization. Groundwater geochemistry of the Savannah River Site and vicinity (open access)

SRP baseline hydrogeologic investigation: Aquifer characterization. Groundwater geochemistry of the Savannah River Site and vicinity

An investigation of the mineralogy and chemistry of the principal hydrogeologic units and the geochemistry of the water in the principal aquifers at Savannah River Site (SRS) was undertaken as part of the Baseline Hydrogeologic Investigation. This investigation was conducted to provide background data for future site studies and reports and to provide a site-wide interpretation of the geology and geochemistry of the Coastal Plain Hydrostratigraphic province. Ground water samples were analyzed for major cations and anions, minor and trace elements, gross alpha and beta, tritium, stable isotopes of hydrogen, oxygen, and carbon, and carbon-14. Sediments from the well borings were analyzed for mineralogy and major and minor elements.
Date: March 31, 1992
Creator: Strom, R. N. & Kaback, D. S.
Object Type: Report
System: The UNT Digital Library
Recovery of plutonium from solvent wash solutions (open access)

Recovery of plutonium from solvent wash solutions

A number of potential alternatives to the acid hydrolysis recovery of Pu were investigated. The most promising alternative for short-term use appears to be an anion exchange process that would eliminate the long boiling times and the multiple-pass concentration steps needed with the solvent extraction process because it separates the Pu from the dibutyl phosphate (DBP) while at the same time concentrating the Pu. However, restart of the Primary Recovery Column (PRC) to process this solution would require significant administrative effort. The original boiling recovery by acid hydrolysis followed by solvent extraction is probably the most expedient way to process the Pu-DBP-carbonate solution currently stored in tank 13.5 even with its long processing times and dilute product concentration. Anion exchange of a heat stabilized acidified solution is a more efficient process, but requires restart of the PRC. Extended-boiling acid hydrolysis or anion exchange of a heat stabilized acidified solution provide two well developed alternatives for recovery of the Pu from the tank 13.5 carbonate. Further work defining additional recovery processes is not planned at this time.
Date: March 31, 1992
Creator: Kyser, E. A.
Object Type: Report
System: The UNT Digital Library
Chemical and thermal stability of refrigerant-lubricant mixture with metal. Materials compatibility and lubricants research on CFC-refrigerant substitutes: Quarterly report, 1 February 1992--31 March 1992 (open access)

Chemical and thermal stability of refrigerant-lubricant mixture with metal. Materials compatibility and lubricants research on CFC-refrigerant substitutes: Quarterly report, 1 February 1992--31 March 1992

This report presents completed sealed tube stability test results for the R-123/mineral oil mixture and preliminary results for seven of the eighteen contracted refrigerant-lubricant mixtures. The R-123 mixture was tested at 105, 150, and 175{degrees}C. The results obtained indicate that prolonged exposure to temperatures of about 150{degree}C and higher will lead to rapid chemical deterioration of the R-123/mineral oil system. Chlorotrifluoroethane (R-133a) and trifluoroethane (R-143a) have been identified as decomposition products of R-123. Testing at 150 and 175{degrees}C have been completed for the HCFC refrigerants R-22, R-124, and R-142b with either mineral oil or alkylbenzene lubricants. These mixtures were very stable at the indicated temperatures. Testing at a higher temperature level will be necessary to define their upper temperature limits. Similarily, partial test results are available for HFC refrigerants R-32, R-125, R-134a (two esters), and R-143a with pentaerythritol ester lubricants at the 150 and 175{degrees}C temperature levels. Again, all five mixtures were found to be extremely stable at the test temperatures and additional testing will be needed to establish their upper temperature limits.
Date: March 31, 1992
Creator: Huttenlocher, D. F.
Object Type: Report
System: The UNT Digital Library
Resonance Raman and photophysical studies of transition metal complexes in solution and entrapped in zeolites. Progress report, August 1, 1991--March 31, 1992 (open access)

Resonance Raman and photophysical studies of transition metal complexes in solution and entrapped in zeolites. Progress report, August 1, 1991--March 31, 1992

We have obtained convincing evidence for localization of the optical electron on a single-ring fragment of a chelated ``bipyridine-like`` ligand (ie., pyridylpyrazine or 4-Methyl-bipyridine). In addition we have completed studies of Ru(bipyrazine){sub 3}{sup 2+} in aqueous sulfuric acid (0--98% by weight) and find clear evidence for sequential addition of six-protons to the six peripheral nitrogen atoms. Studies of zeolite-entrapped complexes are continuing and a series of homo- and heteroleptic complexes have been prepared and characterized. Finally, the synthesis of zeolite-entrapped metallophthalocyanines has now been developed and the copper and cobalt analogues synthesized. The characterization of these materials is now in progress.
Date: March 31, 1992
Creator: Kincaid, J. R.
Object Type: Report
System: The UNT Digital Library
Applicability of the sludge processing technical standard to type IV waste tanks with high fluoride concentration (open access)

Applicability of the sludge processing technical standard to type IV waste tanks with high fluoride concentration

Type IV waste tanks at the Savannah River Plant which contain ballast water (tanks 17, 18, 19, 20, and 24) have solution compositions that are generally within the database developed for corrosion protection of the sludge processing tanks. Therefore the technical standard covering tank chemistry limits during sludge processing is applicable to the Type TV tanks. However, Tank 20 contains levels of fluoride higher than those treated in the sludge processing database. To confirm the applicability of the sludge processing technical standard, cyclic potentiodynamic polarization scans for pitting susceptibility were run in a simulant of the Tank 20 contents. The nitrite inhibitor level specified by the standards did inhibit pitting corrosion in the simulant. Pitting was inhibited also at the same nitrite level but with 30 percent higher concentrations of chloride, fluoride, and sulfate. Thus the sludge processing technical standard has been shown to provide corrosion protection to type IV tanks containing ballast water.
Date: March 31, 1992
Creator: Zapp, P. E.
Object Type: Report
System: The UNT Digital Library
The Harper Herald (Harper, Tex.), Vol. 67, No. 13, Ed. 1 Tuesday, March 31, 1992 (open access)

The Harper Herald (Harper, Tex.), Vol. 67, No. 13, Ed. 1 Tuesday, March 31, 1992

Weekly newspaper from Harper, Texas that includes local, state, and national news along with advertising.
Date: March 31, 1992
Creator: Ernst, Peggy
Object Type: Newspaper
System: The Portal to Texas History
Sulphur Springs News-Telegram (Sulphur Springs, Tex.), Vol. 114, No. 77, Ed. 1 Tuesday, March 31, 1992 (open access)

Sulphur Springs News-Telegram (Sulphur Springs, Tex.), Vol. 114, No. 77, Ed. 1 Tuesday, March 31, 1992

Daily newspaper from Sulphur Springs, Texas that includes local, state, and national news along with advertising.
Date: March 31, 1992
Creator: Keys, Clarke
Object Type: Newspaper
System: The Portal to Texas History
SSCL Commissioning and Operations (open access)

SSCL Commissioning and Operations

The SSC, with an energy of 20 TeV/Beam, requires a sequence of individual accelerators of increasing energy in the injector chain. These are the Linac, Low Energy Booster, Medium Energy Booster, and High Energy Booster. Each accelerator system must be completed in sequence in order to provide beam to the next higher energy accelerator. The collider itself is comprised of ten sectors, each of which in terms of superconducting magnet bending strength, is equivalent to two HEB injectors. The completion of all injectors and collider sectors is required before stored beams can circulate in preparation for colliding beam operation. Four experimental halls are planned for the detector systems. Each major detector will be assembled in one of the halls by a world-wide collaboration of scientists. In addition, above ground facilities provide shops and test facilities for accelerator technical systems, superconducting magnet and materials research and development, and for detector assembly and operations. The purpose of this report is to present a plan for the sequential commissioning and operation of these individual accelerators and other technical facilities of the SSC. A central objective of this plan is to describe the activities at the SSCL that are not included as part of …
Date: March 31, 1992
Creator: unknown
Object Type: Report
System: The UNT Digital Library
The Baytown Sun (Baytown, Tex.), Vol. 70, No. 130, Ed. 1 Tuesday, March 31, 1992 (open access)

The Baytown Sun (Baytown, Tex.), Vol. 70, No. 130, Ed. 1 Tuesday, March 31, 1992

Daily newspaper from Baytown, Texas that includes local, state, and national news along with advertising.
Date: March 31, 1992
Creator: Dobbs, Gary
Object Type: Newspaper
System: The Portal to Texas History

[Photograph 2012.201.B0348.0424]

Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Putnam City High School teacher Nick Kyle is known nationally for his work in the arts."
Date: March 31, 1992
Creator: Hellstern, Paul
Object Type: Photograph
System: The Gateway to Oklahoma History

[Photograph 2012.201.B1112.0221]

Photograph used for a story in the Daily Oklahoman newspaper. Caption: "Tammi Rudlang of Capital Hill Mid-High School and Raymond Lithard of Douglass differ on how to celebrate a spring afternoon."
Date: March 31, 1992
Creator: Burnett, Roberta
Object Type: Photograph
System: The Gateway to Oklahoma History
[News Clip: Denton Car Dealer PKG] captions transcript

[News Clip: Denton Car Dealer PKG]

Video footage from the KXAS-TV/NBC station in Fort Worth, Texas, to accompany a news story. This story aired at 7 P.M.
Date: March 31, 1992
Creator: KXAS-TV (Television station : Fort Worth, Tex.)
Object Type: Video
System: The UNT Digital Library