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This report itemizes the irradiations performed by Testing and Irradiation Services for Battelle-Northwest. It lists the material being irradiated, awaiting disposition and material shipped during the report period. Specific data given is TISR No., Request number, Material, Piece number, operating time, CMK Absorbed, charge date, location, exposure to date, discharge date and time, and shipping date.

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Engineering Work Requests ESE-48 & 49 established a program for performance of Qualification Approval Tests on RPC`s 0.2 and 40 meghom Carbon Composition Resistors. This report is an accounting of these tests wherein (50) samples of each component were subjected to QA tests per drawings 8O2C250 and 802C251. Tests are explained and results tabulated.

In a previous study the trimer of rhenium tetracarbonyl was found to be diamagnetic, suggesting the presence of hydrogen in the compound. This was supported by chemical analysis, which indicated about one hydrogen per rhenium, and the compound was formulated as [Re(C0)4H] 3• Subsequently a proton resonance was observed on a broad line spectrometer. In the original work the infrared spectra were compared for the hydride and deuteride; cyclohexane solutions were used for the CO stretching region and KBr discs were used for the rest of the spectrum. Surprisingly, the spectra of the hydride and deuteride showed only minor differences, insufficient to confirm the presence of hydrogen. No evidence of a hydrogen stretching frequency was found. In the present work, the previously unobserved Raman spectra were measured for the hydride and deuteride . In the solid state ratber striking shifts were observed in the CO stretching region. Also there is some evidence for a metal-hydrogen stretching band at the rather low frequency of 1100 cm-1. In an attempt to support the interpretation of the Raman spectra more detailed infrared studies of the solid in KBr discs were made. The hope was to observe a metal-hydrogen stretching frequency and to explain …

To evaluate the crudding characteristics of ammonium hydroxide conditioned coolant it is necessary to use a thermocouple element. The present design has accentuated structural integrity, reliability and constant heat flux. A radical departure from past designs was made by selecting a stainless steel cladding and enriched ceramic fuel. Three thermocouples are inserted in the cladding to increase the reliability. By the use of two thermocouple elements it will be possible to obtain important preliminary information on preferential crud deposition while simultaneously evaluating the crudding characteristics of ammonium hydroxide conditioned coolant.

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The new sector-focused cyclotrons have more energetic and better focused beams at the extraction radius than do ordinary cyclotrons. While the first characteristic requires a more intense electric field, the second permits this field to extend over a smaller volume. By tailoring the electrode geometry to these characteristics of the beam, the required deflector gap and electrode surface become smaller, and a higher gradient can be held without sparking. A different compromise between radioactivity, power dissipation, and resistance to spark damage must be made in selecting electrode materials. Carefully designed electrostatic deflectors perform very well in sector-focused cyclotrons of intermediate energy. Deflector efficiencies of about 50% and external-beam intensities of 20 {micro}A have been obtained in the Lawrence Laboratory's 88 -Inch Cyclotron.

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The Blake Rhometer operating range was extended from 600 to 1000 deg F and a variable-orifice plugging meter was developed. Both instruments were evaluated in the Atomic Power Development Associates Scdium Technology Loop against weighed or metered contaminants. The loop injection series included: water, hydrogen, carbon monoxide, carbon dioxide, and methane gases; and tea bag injections of sodium carbonate, sodium hydride, sodium hydroxide, and sodium monoxide. Cover gas was monitored and temperature varied during and after each injection run, and the test loop cleaned by cold trapping after each run. A Continuous Hydrogen Monitor attached to the loop cover gas system and a Nickel Diffusion-Tube Hydrogen Monitor connected to the loop proper were evaluated for sensitivity and response. (auth)

The N-Reactor Department Research and Development Program for FY 1965, 1966, and later years is structured to achieve the following general goals. (1) Assurance of a high level of nuclear safety; (2) Assurance of achieving full plant life; (3) Reduction in operating costs for a given production rate; (4) Increase in production rate without proportionate increase in operating costs; (5) Savings in capital outlays necessary to achieve stated reductions in operating cost or increases in production; (6) Production of new products of value; (7) Savings in capital outlays or operating costs to achieve a given level of plant safety. The program is divided into three general categories; Reactor, Metallurgy, and Co-Product. The Reactor category is further divided into physics studies, thermal hydraulics studies, zircaloy process tube development, control, instrument and system analyses, chemistry, engineering research and development, gas, atmosphere studies, graphite studies, and nuclear safety research.