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Electrical Properties of the Tungsten Bronzes (open access)

Electrical Properties of the Tungsten Bronzes

From abstract: "The electrical resistivity of NaxWO3, LixWO3, and KxWO3 has been measured at 300°K. The range of x-values was 0.25 < x < 0.9. All resistivities were characteristic of a metal and lie on a single curve. An extrapolation of the conductivity curve to zero conductivity indicated that the tungsten bronzes should be semiconductors for x < 0.25. The resistivities that have been measured for tungsten bronzes with x < 0.25 showed semiconducting behavior. The resistivity of LixWO3 exhibited an anomalous peak in the ρ vs Τ cuve. The Hall coefficient of Li0.37WO3 indicated one free electron per alkali atom as was previously found for NaxWO3. The Seebeck coefficient of NaxWO3 depended linearly on x[superscript]-2/3 as expected from free electron theory. The implications of these and some other data are discussed."
Date: March 21, 1962
Creator: Shanks, H. R.; Sidles, Paul Howard & Danielson, G. C.
System: The UNT Digital Library
Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane (open access)

Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane

From abstract: "A study has been made of the yields of gaseous products labeled with C11 from the C12(γ, n) reaction in liquid cyclohexane. The effects of variations in the radiation dose and in the concentration of dissolved iodine during irradiation on the yields of these products were studied in order to elucidate the reaction mechanisms. A reaction model was developed as a method of assessing the relative importance of radical and molecular processes. The data suggest (1) that the formation of C11 labeled CH4, C2H4 + C2H6, and C3H6 involves a hot radical process while (2) the formation of C2H2 is by a molecular reaction with cyclohexane."
Date: March 21, 1962
Creator: Rack, Edward P. & Voigt, Adolf F.
System: The UNT Digital Library
Separation of Iron by Liquid-Liquid Column Extraction (open access)

Separation of Iron by Liquid-Liquid Column Extraction

From abstract: "Iron(III) can be separated from many elements by extraction from 6 to ͟8M hydrochloric acid. The extraction is carried out by passing the aqueous hydrochloric acid solution through a column packed with 2-octanone adsorbed onto a poly-fluorocarbon resin. Fluoride, phosphate, sulfate or citrate cause no interference. Traces if iron(III) can be separated quantitatively from large amounts of copper(II) or zinc(II); traces of titanium(IV) can be separated from large amounts of iron(III)."
Date: March 21, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Hedrick, C. E.
System: The UNT Digital Library
αZ Correction to the Bethe-Maximon Pair Production Cross Section (open access)

αZ Correction to the Bethe-Maximon Pair Production Cross Section

From abstract: "The first order correction in αZ to the Bethe-Maximon pair production cross section is calculated for the case where the incident photon and one of the electrons has an energy much greater than mc2. Comparison of these calculations to the experimental data of Plimpton and Hammer shows an improvement ina greement between theory and experiment of approximately a factor of 1+(αZ4π/15) for low positron kinetic energies. However, for positron kinetic energies of the order of 1 Mev no improvement is obtained."
Date: March 21, 1962
Creator: Moroi, David S. & Hammer, C. L.
System: The UNT Digital Library
Erosion Experiments of Powder Compacted Uranium Dioxide Under Dynamic Steam Flow (Preliminary Report) (open access)

Erosion Experiments of Powder Compacted Uranium Dioxide Under Dynamic Steam Flow (Preliminary Report)

Experiments were carried out to determine the erosion, oxidation and dimensional characteristics of purposely defected fuel elements containing unsintered UO2 powder prepared by the swaging technique. The experiments were conducted in an out-of-reactor loop under superheat conditions of pressure, temperature, flow velocity and steam chemical composition.
Date: March 21, 1961
Creator: Spalaris, C. N.; Comprelli, F. A. & Siegler, M.
System: The UNT Digital Library
The Pilot Plant Operation of a Vertical Tube, Recirculating Dissolver for the Dissolution of Uranium Dioxide in Nitric Acid (open access)

The Pilot Plant Operation of a Vertical Tube, Recirculating Dissolver for the Dissolution of Uranium Dioxide in Nitric Acid

The need for criticality control in the proposed reprocessing of slightly enriched non-production fuels at Hanford has led to the development of a geometrically "safe", vertical tube, recirculating dissolver. A study of the nitric acid dissolution of uranium dioxide in a pilot plant dissolver of this type is reported here. The study was pointed toward the comparison of uranium dioxide dissolution rates in a batch and a recirculating dissolver and the definition of hydraulic problems associated with the recirculation of nitric acid, by air lift, technique through beds of reacting uranium dioxide.
Date: March 21, 1960
Creator: Smith, P. W.
System: The UNT Digital Library
Induction Melting of Uranium Dioxide Powder (open access)

Induction Melting of Uranium Dioxide Powder

Fused uranium dioxide has desirable characteristics for fabricating high density nuclear fuel elements by swaging. Methods of preparing dense uranium dioxide particles being investigated at HAPO include are arc fusion, and sintering and crushing of low density powder. This paper reports the results of exploratory experiments to prepare fused uranium dioxide by induction heating of low density powder in graphite crucibles.
Date: March 21, 1959
Creator: Newkirk, H. W.
System: The UNT Digital Library
Anisotropic Elastic Scattering of Neutrons (open access)

Anisotropic Elastic Scattering of Neutrons

In an elastic collision the neutron loses part of its kinetic energy to the nucleus with both the kinetic and momentum of the system being conserved. However, for many elements the scattering is not isotropic in the center-of-mass system at the higher neutron energies. Many of the present reactor multigroup codes include anisotropic scattering at the high neutron energies, while many others assume isotropic scattering at all energies. In order to consider some of the effects of including anisotropic scatting, reference is made t the multigroup equation generally assumed for the slowing-down density.
Date: March 21, 1957
Creator: Copenhaver, C. M.
System: The UNT Digital Library
Beryllium (open access)

Beryllium

The information concerning beryllium assembled herein has been selected primarily to provide information that might be pertinent to the design of the ART. The creep-rupture data in the literature have been obtained from vacuum cast and extruded beryllium, rather than from the hot-pressed beryllium which will be used in the ART. A research program is being conducted by the Brush Beryllium Company, under contract to the Oak Ridge National Laboratory, which will eventually provide the design engineers with data on the high temperature strength properties of hot-pressed beryllium. In the interim, it will be necessary for the metallurgists and design engineers to make judicious estimates and extrapolations from the data available.
Date: March 21, 1957
Creator: Whitman, M. J.
System: The UNT Digital Library
Transient Temperature Variations During the Self-Heating of a Plasma by Thermonuclear Reactions (open access)

Transient Temperature Variations During the Self-Heating of a Plasma by Thermonuclear Reactions

Abstract: "The possibility of transient temperature variations during the self-heating of a plasma by thermonuclear reactions was investigated. Calculations were performed on an IBM Card Program Calculator. Estimates of the time scale for self-heating were obtained. It was concluded that it would be unsafe to assume that the nuclear temperature is always equal to or greater than the electron temperature in a discussion of plasma instabilities for a plasma with 10 percent or greater tritium concentration."
Date: March 21, 1955
Creator: Greyber, Howard D.
System: The UNT Digital Library
Statistical evaluation of calibrartion data-infrared method for determination of % TBP (open access)

Statistical evaluation of calibrartion data-infrared method for determination of % TBP

A report which discusses the data submitted for evaluation. This data is about optical densities from infrared spectrometer readings on eight standard samples, ranging in percent TBP from 6.71 to 17.85.
Date: March 21, 1950
Creator: Healy, W. C.
System: The UNT Digital Library