We present a new approach for investigating the kinetics of defect migration during annealing of low-energy, ion-implanted silicon, employing a combination of computer simulations and atomic-resolution tunneling microscopy. Using atomically-clean Si(111)-7x7 as a sink for bulk point defects created by 5 keV Xe and Ar irradiation, we observe distinct, temperature-dependent surface arrival rates for vacancies and interstitials. A combination of simulation tools provides a detailed description of the processes that underly the observed temperature-dependence of defect segregation, and the predictions of the simulations agree closely with the experimental observations.

This paper focuses on the design consideration, fabrication processes and preliminary testing of the stretchable micro-electrode array. We are developing an implantable, stretchable micro-electrode array using polymer-based microfabrication techniques. The device will serve as the interface between an electronic imaging system and the human eye, directly stimulating retinal neurons via thin film conducting traces and electroplated electrodes. The metal features are embedded within a thin ({approx}50 micron) substrate fabricated using poly (dimethylsiloxane) (PDMS), a biocompatible elastomeric material that has very low water permeability. The conformable nature of PDMS is critical for ensuring uniform contact with the curved surface of the retina. To fabricate the device, we developed unique processes for metalizing PDMS to produce robust traces capable of maintaining conductivity when stretched (5%, SD 1.5), and for selectively passivating the conductive elements. An in situ measurement of residual strain in the PDMS during curing reveals a tensile strain of 10%, explaining the stretchable nature of the thin metalized devices.

None

The U.S. Department of Energy's mission is to protect the Columbia River and the public living in communities surrounding the Hanford Site while cleaning up and shrinking the Site. Pacific Northwest National Laboratory is contributing to the cleanup mission and protection of the Columbia River and public. This booklet summarizes work PNNL performed directly for DOE. Work done for Hanford contractors and the Waste Treatment Plant is summarized in the other booklets in this series.

Lowering the costs of front-end processes in the geologic sequestration of CO{sub 2} can dramatically lower the overall costs. One approach is to sequester less-pure CO{sub 2} waste streams that are less expensive or require less energy to separate from flue gas, a coal gasification process, etc. The objective of this research is to evaluate the impacts of an impure CO{sub 2} waste stream on geologic sequestration using both reaction progress and reactive transport simulators. The simulators serve as numerical laboratories within which a series of computational experiments can be designed, carried out, and analyzed to quantify sensitivity of the overall injection/sequestration process to specific compositional, hydrologic, structural, thermodynamic, and kinetic parameters associated with the injection fluid and subsurface environment.

A chemical ionization mass spectrometry (CIMS) technique has been developed for precise in situ measurements of hydrochloric acid (HCl) from a high-altitude aircraft. In measurements at subtropical latitudes, minimum HCl values found in the upper troposphere (UT) are often near or below the 0.005-ppbv detection limit of the measurements, indicating that background HCl values are much lower than a global mean estimate. However, significant abundances of HCl were observed in many UT air parcels as a result of stratosphere-to-troposphere transport events. A method for diagnosing the amount of stratospheric ozone in these UT parcels was developed using the compact linear correlation of HCl with ozone found throughout the lower stratosphere (LS). Expanded use of this method will lead to improved quantification of cross-tropopause transport events and validation of global chemical transport models.

Pacific Northwest National Laboratory managed a variety of technical and scientific efforts to support Fluor Hanford's work in cleaning up the Hanford Site. Work done for other Hanford contractors, the Waste Treatment Plant, and directly for the U.S. Department of Energy is summarized in the other booklets in this series.

In 2004, Pacific Northwest National Laboratory provided analyses, reviews, testing, and new tools to assist CH2M HILL Hanford Group, Inc. in accomplishing their River Protection Project objectives. These objectives are safe storage, retrieval, and treatment of radioactive waste from Hanford's tanks, closure of tanks, and disposal of treated wastes.

Unresolved transitions in the nuclear {gamma}-ray cascade produced in the decay of excited nuclei are best described by statistical concepts: a continuous radiative strength function (RSF) and level density yield mean values of transition matrix elements. Data on the soft (E{sub {gamma}} < 3-4 MeV) RSF for transitions between warm states (i.e. states several MeV above the yrast line) have, however, remained elusive.

A real-time radiological sensor network for emergency response was developed and deployed at the Lawrence Livermore National Laboratory (LLNL). The Real-Time Radiological Area Monitoring (RTRAM) network is comprised of 16 Geiger-Mueller (GM) sensors positioned on the LLNL Livermore site perimeter to continuously monitor for a radiological condition resulting from a terrorist threat to site security and the health and safety of LLNL personnel. The RTRAM network sensor locations coincide with wind sector directions to provide thorough coverage of the one square mile site. These low-power sensors are supported by a central command center (CCC) and transmit measurement data back to the CCC computer through the LLNL telecommunications infrastructure. Alarm conditions are identified by comparing current data to predetermined threshold parameters and are validated by comparison with plausible dispersion modeling scenarios and prevailing meteorological conditions. Emergency response personnel are notified of alarm conditions by automatic radio and computer based notifications. A secure intranet provides emergency response personnel with current condition assessment data that enable them to direct field response efforts remotely. The RTRAM network has proven to be a reliable system since initial deployment in August 2001 and maintains stability during inclement weather conditions.

In support of the Waste Treatment Plant (WTP), Battelle conducted tests on mixing specific wastes within the plant, removing troublesome materials from the waste before treatment, and determining if the final waste forms met the established criteria. In addition, several Battelle experts filled full-time positions in WTP's Research and Testing and Process and Operations departments.

It is known that focusing of an acoustic field by a time-reversal mirror (TRM) is equivalent to a spatio-temporal matched filter under conditions where the Green's function of the field satisfies reciprocity and is time invariant, i.e. the Green's function is independent of the choice of time origin. In this letter, it is shown that both reciprocity and time invariance can be replaced by a more general constraint on the Green's function that allows a TRM to implement the spatio-temporal matched filter even when conditions are time varying.

Event horizons and closed time-like curves cannot exist in the real world for the simple reason that they are inconsistent with quantum mechanics. Following ideas originated by Robert Laughlin, Pawel Mazur, Emil Mottola, David Santiago, and the speaker it is now possible to describe in some detail what happens physically when one approaches and crosses a region of space-time where classical general relativity predicts there should be an infinite red shift surface. This quantum critical physics provides a new perspective on a variety of enigmatic astrophysical phenomena including supernovae explosions, gamma ray bursts, positron emission, and dark matter.

Pacific Northwest National Laboratory supports Bechtel Hanford, Inc., in identifying and applying new technologies to clean up contaminated sites on the land bordering the Columbia River where nine nuclear reactors operated. During fiscal year 2004, PNNL screened more than 100 different technologies for potential application to site clean up.

Present-day global anthropogenic emissions contribute more than half of the mass in submicron particles primarily due to sulfate and carbonaceous aerosol components derived from fossil fuel combustion and biomass burning. These anthropogenic aerosols modify the microphysics of clouds by serving as cloud condensation nuclei (CCN) and enhance the reflectivity of low-level water clouds, leading to a cooling effect on climate (the Twomey effect or first indirect effect). The magnitude of the first aerosol indirect effect is associated with cloud frequency as well as a quantity representing the sensitivity of cloud albedo to changes in cloud drop number concentration. This quantity is referred to as cloud susceptibility [Twomey, 1991]. Analysis of satellite measurements demonstrates that marine stratus clouds are likely to be of higher susceptibility than continental clouds because of their lower number concentrations of cloud drops [Platnick and Twomey, 1994]. Here, we use an improved version of the fully coupled climate/chemistry model [Chuang et al., 1997] to calculate the global concentrations Of sulfate, dust, sea salt, and carbonaceous aerosols (biomass smoke and fossil fuel organic matter and black carbon). We investigated the impact of anthropogenic aerosols on cloud susceptibility and calculated the associated changes of shortwave radiative fluxes at the …

This note describes a simple model developed to explore some of the properties of the pulse-line ion accelerator [1], here represented as a series of lumped elements, in the general parameter regime for the ''NDCX-1d'' experiments. The goals of this modeling are: to understand the evolution of various possible input pulses in the presence of dispersive effects and imperfect termination of the line; to examine scenarios for beam acceleration; and to explore the effects of ''beam loading'', that is, changes to the voltages along the helical line that result from the interaction of the beam's return current with the ''circuitry'' of that line. In Section 1 below, the model is described and the method of solution outlined; in Section 2, a low-current example of beam acceleration is presented; in Section 3, runs are presented showing the development of beam loading-induced voltages as model pulses are followed; in section 4, the modeling of a higher-current beam under acceleration is presented, and the effects of beam loading quantified; and in section 5, a brief summary of complementary efforts and of plans to extend the modeling is presented.

This letter dated March 8, 1957 summarizes the results of preliminary studies on the stepwise expansion of Purex facilities to the ultimate rate of 4.0 capacity factor, using a two-cycle flow-sheet. Briefly, it was suggested that Purex be expanded to the intermediate capacity of 3.5 capacity factor using available FY-1958 funds insofar as possible; decision to expand Purex to 4.0 capacity factor, could have been deferred for subsequent budgetary consideration.

This paper presents a coupled thermal-hydrological-mechanical (THM) analysis of the Drift Scale Test (DST) conducted at Yucca Mountain, Nevada. The DST is a large-scale, long-term thermal test designed to investigate coupled thermal-mechanical-hydrological-chemical behavior in a fractured, welded tuff rock mass in support of nuclear waste isolation efforts. The model used for this analysis utilizes temperature distributions predicted by a thermal-hydrological code as input to a distinct element thermal mechanical code. This paper presents a brief discussion of the test and the coupled model, followed by comparison of predicted and measured displacements. Results show that the model predicts the trend and magnitude of the displacements observed in a cross section monitored in the test through four years of heating. Maximum principal stress levels of 60 MPa are predicted in the crown and floor of the heated drift (HD) after 4 years of heating. Comparison of predicted and observed displacements shows that the model closely predicts vertical displacement above the HD and provides a good estimate of horizontal displacement perpendicular to the HD. These results indicate that a thermal expansion coefficient of 9e-6/{Lambda}C is generally appropriate for the rockmass forming this test. Normal displacements on joints in the cross section examined here …

Fracture deformations were measured in a 3m x 3m x 4.5m block of Topopah Spring tuff as part of a larger effort to characterize coupled thermal-hydrologic-mechanical-chemical processes in an isolated rock mass subjected to a one-dimensional thermal gradient. The fracture deformations were measured in three orthogonal directions at 17 points on the vertical faces of the block over a time span of 19 months. Eight fractures, including a major sub-horizontal fracture near the top of the block and five large, sub-vertical fractures, were selected for study. The data provide point measurements of apparent aperture change and slip motions parallel and perpendicular to the block faces. The fracture aperture and slip motions, though only a few tenths of a millimeter, form a significant portion of the total block deformation. The data reveal some fairly complex behaviors, such as nonuniform slip motions along individual fractures and sub-vertical fractures that sometimes open and close simultaneously at different elevations. Slip motions along sub-vertical fractures near the heater plane were relatively large and well correlated with temperature. The heating phase deformations were only partially recovered during cool-down. The fracture deformation data show that fractures deformed in conjunction with water movements and associated temperature fluctuations during …

The purpose of this report is to estimate the consequences of a Hanford reactor accident with emphasis on the effects at distant points. The potential effects in Canada are estimated as well as the consequences within the United States.

Preliminary data have been obtained on the effect of temperature on the tensile properties of a Pu-0.9 w/o Ga delta stabilized alloy. Contoured castings for tensile specimen fabrication were obtained by pouring in vacuo from 900 {degrees}C into a MgO coated graphite mold heated to 475-500 {degrees}C.

The specific objective of the research is to demonstrate that the characteristics of wastewater from stripper oil wells and marginal gas wells are sufficiently similar to be treated under a standardized treatment methodology, that the environmental impacts of the discharge of treated brines from both stripper oil and marginal gas wells can be adequately regulated, and that the inclusion of marginal gas wells in the same category as stripper oil wells is appropriate, especially for wells operating in the Appalachian Basin. The work accomplished during 1992 for both the field-scale and the laboratory-scale treatment facilities focused on iron removal from the field and synthetic brines. The laboratory work also included single-element kinetics studies to determine the effect of one metal on another with respect to the rates of the various reactions. The laboratory process studies investigated such parameters as the sand bed thickness, the temperature of the system, the angle of the aeration unit, and the presence of the retention tank. All of these laboratory parametric studies provided insight into how each component of the treatment process contributes to the removal of iron from the synthetic brine. Similar studies have begun for investigating copper removal effectiveness. As for the field …

Objective was to study reactions at superthermal collision energies using a fast neutral beam produced by photodetachment. Systems under initial study included basic oxygen-hydrogen reactions. Although progress was made on each stage of the experiment, conflicting requirements (maximizing photodetachment efficiency and maximizing transmission through reaction zone) precluded ultimate success. Parameters described refer to the model system O+H{sub 2}{r_arrow}OH+H. 2 figs.

Cleanup of hazardous waste sites under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) is a complicated and painstaking process, particularly at facilities with a multitude of individual hazardous waste sites, each having a multitude of chemicals and radonuclides. The US Department of Energy-Oak Ridge, Environmental Restoration Division (DOE-OR/ERD) administers five such facilities which are undergoing environmental cleanup under the CERCLA Remedial Investigation and Feasibility Study (RI/FS) process or the Resource Conservation and Recovery Act (RCRA) investigation process. The nature of the wastes treated, stored, or disposed of at the US DOE-OR sites is heterogeneous and often unknown. The amount of environmental sampling, chemical analysis, and document preparation and review required to support a baseline risk assessment alone at each facility often requires years before arriving at a final Record of Decision. Therefore, there is clearly a need to streamline the investigative and decision processes in order to realize the US Environmental Protection Agency`s (EPA) goal of reducing contaminant levels to those that are protective human health and the environment in a timely and cost-effective manner.