This thesis outlines advancements in Raman scatter enhancement techniques by applying evanescent fields, standing-waves (waveguides) and surface enhancements to increase the generated mean square electric field, which is directly related to the intensity of Raman scattering. These techniques are accomplished by employing scanning angle Raman spectroscopy and surface enhanced Raman spectroscopy. A 1064 nm multichannel Raman spectrometer is discussed for chemical analysis of lignin. Extending dispersive multichannel Raman spectroscopy to 1064 nm reduces the fluorescence interference that can mask the weaker Raman scattering. Overall, these techniques help address the major obstacles in Raman spectroscopy for chemical analysis, which include the inherently weak Raman cross section and susceptibility to fluorescence interference.

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We perform a survey of the proton, K^+, K^- -3 charged track data, taken by the CLAS detector for the HyCLAS experiment during the g12 run-period at Jefferson Lab. We aim to study the strong decay amplitudes, partial widths and production channels of strangeonia from the CLAS g12 dataset. HyCLAS was motivated by the experimental results for gluonic hybrid meson candidates, theoretical Lattice QCD, and Flux-tube Model calculations and predictions. The experiment was designed and conducted to search and observe new forms of hadronic matter through photoproduction.

The study of {Lambda} hypernuclear structure is very interesting in point of the understanding of the interaction between {Lambda} and nucleon ({Lambda}-N interaction) and its ”strange” structure itself due to the containment of a {Lambda} hyperon which has a strangeness as a new degree of freedom. In the several way to study the Lamda hypernuclei, the (e,e'K{sup +}) reaction spectroscopy is a powerful tool for the precise investigation of {Lamda} hypernuclear structure. The purpose of the preset thesis is the establishment of the experimental design with the efficient data analysis method for the (e,e'K{sup +}) hypernuclear spectroscopic experiment in the wide mass region (from A=7 to A=52). It is very challenging to perform the (e,e'K{sup +}) spectroscopic experiment with such a heavy target, because of the huge electron background due to the bremsstrahlung process. In the experiment, it is required to obtain the necessary hypernuclear yield, suppressing the background event ratio. We achieved these requirements by newly constructing the high resolution electron spectrometer (HES) and splitter magnet (SPL) dedicated to the (e,e'K{sup +}) spectroscopic experiment. The HES consists of two quadrupole magnets and a dipole magnets (Q-Q-D) with a momentum resolution of dp/p = 3x10^-4 at p = 0.84 GeV/c. …

Results for the first measurement of the inclusive branching and CP asymmetry of the charmless 3-body decay B{sup +} {yields} K{sup +}{pi}{sup 0}{pi}{sup 0} are presented. The analysis uses a data sample with an integrated luminosity of 429.0 fb{sup -1}, recorded by the BABAR detector at the PEP-II asymmetric B Factory. This sample corresponds to 470.9 {+-} 2.8 million B{bar B} pairs. Measurements of the branching fractions (B) and CP asymmetries (A{sub CP}) of some of the intermediate resonances in the K{sup +}{pi}{sup 0}{pi}{sup 0} Dalitz plot are also presented.

Laser wakefield acceleration of electrons holds great promise for producing ultra-compact stages of GeV scale, high quality electron beams for applications such as x-ray free electron lasers and high energy colliders. Ultra-high intensity laser pulses can be self-guided by relativistic plasma waves over tens of vacuum diffraction lengths, to give >1 GeV energy in cm-scale low density plasma using ionization-induced injection to inject charge into the wake at low densities. This thesis describes a series of experiments which investigates the physics of LWFA in the self-guided blowout regime. Beginning with high density gas jet experiments the scaling of the LWFA-produced electron beam energy with plasma electron density is found to be in excellent agreement with both phenomenological theory and with 3-D PIC simulations. It is also determined that self-trapping of background electrons into the wake exhibits a threshold as a function of the electron density, and at the densities required to produce electron beams with energies exceeding 1 GeV a different mechanism is required to trap charge into low density wakes. By introducing small concentrations of high-Z gas to the nominal He background the ionization-induced injection mechanism is enabled. Electron trapping is observed at densities as low as 1.3 x …

The absolute branching fractions for the decays D{sub s}{sup -} {yields} {ell}{sup -}{bar {nu}}{sub {ell}} ({ell} = e, {mu}, or {tau}) are measured using a data sample corresponding to an integrated luminosity of 521 fb{sup -1} collected at center of mass energies near 10.58 GeV with the BABAR detector at the PEPII e{sup +}e{sup -} collider at SLAC. The number of D{sub s}{sup -} mesons is determined by reconstructing the recoiling system DKX{gamma} in events of the type e{sup +}e{sup -} {yields} DKXD*{sub s}{sup -}, where D*{sub s}{sup -} {yields} D{sub s}{sup -} {gamma} and X represents additional pions from fragmentation. The D{sub s}{sup -} {yields} {ell}{sup -}{nu}{sub {ell}} events are detected by full or partial reconstruction of the recoiling system DKX{gamma}{ell}. The following results are obtained: {Beta}(D{sub s}{sup -} {yields} {mu}{sup -}{nu}) = (6.02 {+-} 0.38 {+-} 0.34) x 10{sup -3}, {Beta}(D{sub s}{sup -} {yields} {tau}{sup -}{nu}) = (5.00 {+-} 0.35 {+-} 0.49) x 10{sup -2}, and B(D{sub s}{sup -} {yields} e{sup -}{nu}) < 2.8 x 10{sup -4} at 90% C.L., where the first uncertainty is statistical and the second is systematic. The branching fraction measurements are combined to determine the D{sub s}{sup -} decay constant f{sub D{sub s}} …

Recently, our lab has developed monoanionic tridentate ligand, To{sup R}, showing the corresponding coordination chemistry and catalyst reactivity of magnesium, zirconium, zinc and iridium complexes. This thesis details synthetic chemistry, structural study and catalytic reactivity of the To{sup R}-supported rhodium compounds. Tl[To{sup R}] has been proved to be a superior ligand transfer agent for synthesizing rhodium complexes. The salt metathesis route of Tl[To{sup M}] with [Rh({mu}-Cl)(CO)]{sub 2} and [Rh({mu}- Cl)(COE)]{sub 2} gives To{sup M}Rh(CO){sub 2} (2.2) and To{sup M}RhH({eta}{sup 3}-C{sub 8}H{sub 13}) (3.1) respectively while Tl[To{sup P}] with [Rh({mu}-Cl)(CO)]{sub 2} affords To{sup P}Rh(CO){sub 2} (2.3). 2.2 reacts with both strong and weak electrophiles, resulting in the oxazoline N-attacked and the metal center-attacked compounds correspondingly. Using one of the metal center-attacked electrophiles, 2.3 was demonstrated to give high diastereoselectivity. Parallel to COE allylic C-H activation complex 3.1, the propene and allylbenzene allylic C-H activation products have also been synthesized. The subsequent functionalization attempts have been examined by treating with Brønsted acids, Lewis acids, electrophiles, nucleophiles, 1,3-dipolar reagents and reagents containing multiple bonds able to be inserted. Various related complexes have been obtained under these conditions, in which one of the azide insertion compounds reductively eliminates to give an allylic functionalization product …

The longitudinal beam dynamics in circular accelerators is mainly defined by the interaction of the beam current with the accelerating Radio Frequency (RF) stations. For stable operation, Low Level RF (LLRF) feedback systems are employed to reduce coherent instabilities and regulate the accelerating voltage. The LLRF system design has implications for the dynamics and stability of the closed-loop RF systems as well as for the particle beam, and is very sensitive to the operating range of accelerator currents and energies. Stability of the RF loop and the beam are necessary conditions for reliable machine operation. This dissertation describes theoretical formalisms and models that determine the longitudinal beam dynamics based on the LLRF implementation, time domain simulations that capture the dynamic behavior of the RF station-beam interaction, and measurements from the Positron-Electron Project (PEP-II) and the Large Hadron Collider (LHC) that validate the models and simulations. These models and simulations are structured to capture the technical characteristics of the system (noise contributions, non-linear elements, and more). As such, they provide useful results and insight for the development and design of future LLRF feedback systems. They also provide the opportunity to study diverse longitudinal beam dynamics effects such as coupled-bunch impedance driven …

We report on the search for heavy metastable particles that decay into quark pairs with a macroscopic lifetime (c{tau} {approx} 1 cm) using data taken with the CDF II detector at Fermilab. We use a data driven background approach, where they build probability density functions to model Standard Model secondary vertices from known processes in order to estimate the background contribution from the Standard Model. No statistically significant excess is observed above the background. Limits on the production cross section in a Hidden Valley benchmark phenomenology are set for various Higgs boson masses as well as metastable particle masses and lifetimes.

This thesis presents a measurement of the dijet invariant mass spectrum and search for new particles decaying to dijets at CMS in 7 TeV pp collisions using data corresponding to an integrated luminosity of 2.875 pb{sup -1}. The measured dijet mass distribution is compared to QCD prediction from PYTHIA . It is required the pseudorapidity separation of the two jets to satisfy |Dh| < 1.3 with each jet inside the region of |{eta}| < 2.5. The observed dijet mass spectrum is fitted by a smooth function to search for dijet resonances. Since there is no evidence for dijet resonances, the upper limits at 95% Confidence Level (C.L.) on the resonance cross section are set. These generic cross section limits are compared with theoretical predictions for the cross section for several models of new particles: string resonances, axigluons, colorons, excited quarks, E{sub 6} diquarks, Randall-Sundrum gravitons, W' and Z'. It is excluded at 95% C.L. string resonances in the mass range 0.50 < M(S) < 2.50 TeV, excited quarks in the mass range 0.50 < M(q*) < 1.58 TeV, axigluons and colorons in the mass ranges 0.50 < M(A) < 1.17 TeV and 1.47 < M(A) < 1.52 TeV, and E{sub …

A search for the standard model Higgs boson is performed in 6.4 fb{sup -1} of p{bar p} collisions at {radical}s = 1.96 TeV, collected with the D0 detector during Run II of the Fermilab Tevatron. The final state considered is a pair of jets originating from b quarks and missing transverse energy, as expected from p{bar p} {yields} ZH {yields} {nu}{bar {nu}}b{bar b} production. The search is also sensitive to the WH {yields} {ell}{nu}b{bar b} channel, where the charged lepton is not identified. Boosted decision trees are used to discriminate signal from background. Good agreement is observed between data and expected backgrounds, and a limit is set at 95% C.L. on the section multiplied by branching fraction of (p{bar p} {yields} (Z/W)H) x (H {yields} b{bar b}). For a Higgs boson mass of 115 GeV, the observed limit is a factor of 3.5 larger than the value expected from the standard model.

This thesis describes a search for singly produced top quarks via an electroweak vertex in head-on proton-antiproton collisions at a center of mass energy of √s = 1.96 TeV. The analysis uses a total of 2.3 fb^-1 of data collected with the D0 detector at Fermilab, corresponding to two different run periods of the Tevatron collider. Two channels contribute to single top quark production at the Tevatron, the s-channel and the t-channel. In the s-channel, a virtual W boson is produced from the aniquilation of a quark and an antiquark and a top and a bottom quarks are produced from the W decay. The top quark decays almost exclusively into a W boson and a bottom quark. Final states are considered in which the W boson decays leptonically into an electron or a muon plus a neutrino. Thus, at the detector level, the final state characterizing the s-channel contains one lepton, missing energy accounting for the neutrino, and two jets from the two bottom quarks. In the t-channel, the final state has an additional jet coming from a light quark. Clearly, a precise reconstruction of the events requires a precise measurement of the energy of the jets. A multivariate technique, …

Using data collected with the BABAR detector at the SLAC PEP-II electron-positron storage ring operating at a center-of-mass energy near 10.58 GeV, the branching fractions {Beta}({tau}{sup -} {yields} {pi}{sup -}{pi}{sup -}{pi}{sup +}{nu}{sub {tau}}) = (8.83 {+-} 0.01 {+-} 0.13)%, {Beta}({tau}{sup -} {yields} K{sup -}{pi}{sup -}{pi}{sup +}{nu}{sub {tau}}) = (0.273 {+-} 0.002 {+-} 0.009)%, {Beta}({tau}{sup -} {yields} K{sup -}{pi}{sup -}K{sup +}{nu}{sub {tau}}) = (0.1346 {+-} 0.0010 {+-} 0.0036)%, and {Beta}({tau}{sup -} {yields} K{sup -}K{sup -}K{sup +}{nu}{sub {tau}}) = (1.58 {+-} 0.13 {+-} 0.12) x 10{sup -5} are measured where the uncertainties are statistical and systematic, respectively. The invariant mass distribution for the {tau}{sup -} {yields} {pi}{sup -}{pi}{sup -}{pi}{sup +}{nu}{sub {tau}} {yields} K{sup -}{pi}{sup -}{pi}{sup +}{nu}{sub {tau}}, {tau}{sup -} {yields} K{sup -}{pi}{sup -}K{sup +}{nu}{sub {tau}} and {tau}{sup -} {yields} K{sup -}K{sup -}K{sup +}{nu}{sub {tau}} decays are unfolded to correct for detector effects. A measurement of {Beta}({tau}{sup -} {yields} {phi}{pi}{sup -}{nu}{sub {tau}}) = (3.42 {+-} 0.55 {+-} 0.25) x 10{sup -5}, a measurement of {Beta}({tau}{sup -} {yields} {phi}K{sup -}{nu}{sub {tau}}) = (3.39 {+-} 0.20 {+-} 0.28) x 10{sup -5} and an upper limit on {Beta}({tau}{sup -} {yields} K{sup -}K{sup -}K{sup +}{nu}{sub {tau}}[ex.{phi}]) {le} 2.5 x 10{sup -6} {at} 905 CL are determined from …

It is well known that the activity, selectivity, and deactivation behavior of heterogeneous catalysts are strongly affected by a wide variety of parameters, including but not limited to nanoparticle size, shape, composition, support, pretreatment conditions, oxidation state, and electronic state. Enormous effort has been expended in an attempt to understand the role of these factors on catalytic behavior, but much still remains to be discovered. In this work, we have focused on deepening the present understanding of the role of nanoparticle shape, nanoparticle composition, and hot electrons on heterogeneous catalysis in the oxidation of carbon monoxide by molecular oxygen and nitric oxide. These reactions were chosen because they are important for environmental applications, such as in the catalytic converter, and because there is a wide range of experimental and theoretical insight from previous single crystal work as well as experimental data on nanoparticles obtained using new state-of-the-art techniques that aid greatly in the interpretation of results on complex nanoparticle systems. In particular, the studies presented in this work involve three types of samples: ~ 6.5 nm Rh nanoparticles of different shapes, ~ 15 nm Rh_1-xPd_x core-shell bimetallic polyhedra nanoparticles, and Rh ultra-thin film (~ 5 nm) catalytic nanodiodes. The colloidal …

The measurement of the WW + WZ production cross section in a semileptonic decay mode is presented. The measurement is carried out with 4.6 fb{sup -1} of integrated luminosity collected by the CDF II detector in {radical}s = 1.96 TeV proton-antiproton collisions at the Tevatron. The main experimental challenge is identifying the signal in the overwhelming background from W+jets production. The modeling of the W+jets background is carefully studied and a matrix element technique is used to build a discriminant to separate signal and background. The cross section of WW + WZ production is measured to be {sigma}(p{bar p} {yields} WW + WZ) = 16.5{sub -3.0}{sup +3.3} pb, in agreement with the next-to-leading order theoretical prediction of 15.1 {+-} 0.9 pb. The significance of the signal is evaluated to be 5.4{sigma}. This measurement is an important milestone in the search for the Standard Model Higgs boson at the Tevatron.

Experimental coincidence cross section and transverse-longitudinal asymmetry A{sub TL} have been obtained for the quasielastic (e,e'p) reaction in {sup 16}O, {sup 12}C, and {sup 208}Pb in constant q-ω kinematics in the missing momentum range -350 < p{sub miss} < 350 MeV/c. In these experiments, performed in experimental Hall A of the Thomas Jefferson National Accelerator Facility (JLAB), the beam energy and the momentum and angle of the scattered electrons were kept fixed, while the angle between the proton momentum and the momentum transfer q was varied in order to map out the missing momentum distribution. The experimental cross section and A{sub TL} asymmetry have been compared with Monte Carlo simulations based on Distorted Wave Impulse Approximation (DWIA) calculations with both relativistic and non-relativistic spinor structure. The spectroscopic factors obtained for both models are in agreement with previous experimental values, while A{sub TL} measurements favor the relativistic DWIA calculation. This thesis describes the details of the experimental setup, the calibration of the spectrometers, the techniques used in the data analysis to derive the final cross sections and the A{sub TL}, the ingredients of the theoretical calculations employed and the comparison of the results with the simulations based on these theoretical models.

The MINOS experiment was designed to measure neutrino oscillation parameters with muon neutrinos. It achieves this by measuring the neutrino energy spectrum and flavor composition of the man-made NuMI neutrino beam 1km after the beam is formed and again after 735 km. By comparing the two spectra it is possible to measure the oscillation parameters. The NuMI beam is made up of 7.0%$\bar{v}$_μ, which can be separated from the v_μ because the MINOS detectors are magnetized. This makes it possible to study $\bar{v}$_μ oscillations separately from those of muon neutrinos, and thereby test CPT invariance in the neutrino sector by determining the $\bar{v}$_μ oscillation parameters and comparing them with those for v_μ, although any unknown physics of the antineutrino would appear as a difference in oscillation parameters. Such a test has not been performed with beam $\bar{v}$_μ before. It is also possible to produce an almost pure $\bar{v}$_μ beam by reversing the current through the magnetic focusing horns of the NuMI beamline, thereby focusing negatively, instead of positively charged particles. This thesis describes the analysis of the 7% $\bar{v}$_μ component of the forward horn current NuMI beam. The $\bar{v}$_μ of a data sample of 3.2 x 10{sup 20} protons on …

In the past decades, there has been increasing interest in pulsed high power RF sources for building high-gradient high-energy particle accelerators. Passive RF pulse compression systems have been used in many applications to match the available RF sources to the loads requiring higher RF power but a shorter pulse. Theoretically, an active RF pulse compression system has the advantage of higher efficiency and compactness over the passive system. However, the key component for such a system an element capable of switching hundreds of megawatts of RF power in a short time compared to the compressed pulse width is still an open problem. In this dissertation, we present a switch module composed of an active window based on the bulk effects in semiconductor, a circular waveguide three-port network and a movable short plane, with the capability to adjust the S-parameters before and after switching. The RF properties of the switch module were analyzed. We give the scaling laws of the multiple-element switch systems, which allow the expansion of the system to a higher power level. We present a novel overmoded design for the circular waveguide three-port network and the associated circular-to-rectangular mode-converter. We also detail the design and synthesis process of …

We present the search for the lepton flavour violating decay {tau} {yields} lK{sup 0}{sub s} with the BaBar experiment data. This process and many other lepton flavour violating {tau} decays, like {tau} {yields} {mu}{gamma} and {tau} {yields} lll, are one of the most promising channel to search for evidence of new physics. According to the Standard Model and the neutrino mixing parameters, branching fractions are estimated well below 10{sup -14}, but many models of new physics allow for branching fractions values close to the present experimental sensitivity. This analysis is based on a data sample of 469fb{sup -1} collected by BABAR detector at the PEP-II storage ring from 1999 to 2007, equivalent to 431 millions of {tau} pairs. the BABAR experiment, initially designed for studying CP violation in B mesons, has demonstrated to be one of the most suitable environments for studying {tau} decays. The tracking system, the calorimeter and the particle identification of BABAR, together with the knowledge of the {tau} initial energy, allow an extremely powerful rejection of background events that, for this analysis, is better than 10{sup -9}. Being {tau} {yields} lK{sup 0}{sub s} a decay mode without neutrinos, the signal {tau} decay can be fully reconstructed. …

Presented is a measurement of the simultaneous production of a W{sup {+-}} boson in association with a second weak boson (W{sup {+-}} or Z{sup 0}) in p{bar p} collisions at {radical}s = 1.96 TeV. Events are consider with one electron or one muon, missing transverse energy, and at least two hadronic jets. The data were collected by the D0 detector in Run IIa of the Tevatron accelerator and correspond to 1.07 fb{sup -1} of integrated luminosity for each of the two channels (WW/WZ {yields} e{nu}q{bar q} and WW/WZ {yields} {mu}{nu}q{bar q}). The cross section for WW + WZ production is measured to be 20.2 {+-} 2.5(stat) {+-} 3.6(sys) {+-} 1.2(lum) pb with a Gaussian significance of 4.4 standard deviations above the background-only scenario. This measurement is consistent with the Standard Model prediction and represents the first direct evidence for WW and WZ production with semi-leptonic decays at a hadron collider.

The standard model (SM) of particle physics is a theory, describing three out of four fundamental forces. In this model the Cabibbo-Kobayashi-Maskawa (CKM) matrix describes the transformation between the mass and weak eigenstates of quarks. The matrix properties can be visualized as triangles in the complex plane. A precise measurement of all triangle parameters can be used to verify the validity of the SM. The least precisely measured parameter of the triangle is related to the CKM element |V{sub td}|, accessible through the mixing frequency (oscillation) of neutral B mesons, where mixing is the transition of a neutral meson into its anti-particle and vice versa. It is possible to calculate the CKM element |V{sub td}| and a related element |V{sub ts}| by measuring the mass differences {Delta}m{sub d} ({Delta}m{sub s}) between neutral B{sub d} and {bar B}{sub d} (B{sub s} and {bar B}{sub s}) meson mass eigenstates. This measurement is accomplished by tagging the initial and final state of decaying B mesons and determining their lifetime. Currently the Fermilab Tevatron Collider (providing p{bar p} collisions at {radical}s = 1.96 TeV) is the only place, where B{sub s} oscillations can be studied. The first selection of the 'golden', fully hadronic decay …

Top quarks are predominantly produced in pairs via the strong interaction in {bar p}p collisions at {radical}s = 1.96 TeV . The top quark has a weak isospin 1/2, composing a weak isospin doublet with the bottom quark. This characteristic predicts not only top quark pair production via strong interaction but also single production together with a bottom quark via weak interaction. However, finding single top quark production is challenging since it is rarely produced ({sigma}{sub singletop} = 2.9 pb) against background processes with the same final state like W+jets and t{bar t}. A measurement of electroweak single top production probes the W-t-b vertex, which provides a direct determination of the Cabbibo-Kobayashi-Maskawa (CKM) matrix element |V{sub tb}|. The sample offers a source of almost 100% polarized top quarks. This thesis describes an optimized search for s-channel single top quark production and a measurement of the single top production cross section using 2.7 fb{sup -1} of data accumulated with the CDF detector. We are using events with one high-p{sub T} lepton, large missing E{sub T} and two identified b-quark jets where one jet is identified using a secondary vertex tagger, called SecVtx, and the other jet is identified using SecVtx or …

This thesis presents the measurement of energy dependence of the neutrino-nucleon inclusive charged current cross section on an isoscalar target in the range 3-50 GeV for neutrinos and 5-50 GeV energy range for antineutrinos. The data set was collected with the MINOS Near Detector using the wide band NuMI beam at Fermilab. The size of the charged current sample is 1.94 x 10{sup 6} neutrino events and 1.60 x 10{sup 5} antineutrino events. The flux has been extracted using a low hadronic energy sub-sample of the charged current events. The energy dependence of the cross section is obtained by dividing the charged current sample with the extracted flux. The neutrino and antineutrino cross section exhibits a linear dependence on energy at high energy but shows deviations from linear behavior at low energy. We also present a measurement of the ratio of antineutrino to neutrino inclusive cross section.