The relationship between adult attachment style and romantic relationship quality in marriage relationships was explored. Romantic relationship quality was measured at the working model (or perceptual) and the behavioral levels. No previous research had investigated romantic relationship quality as reflecting specific attachment related perceptions of self and spouse or as attachment related behaviors. Two hundred and six married subjects were recruited from university campuses, churches, and on an individual basis. Most of the subjects were white, middle class, and had children. Subjects completed self-report questionnaires measuring adult attachment style, working model of self and romantic partner, and reports of relationship behaviors of self and romantic partner. The first hypothesis proposed that attachment style differences would be seen in specific attachment related working models of self and romantic partner. The second hypothesis proposed that attachment style differences would be seen in reports of attachment related behaviors for self and romantic partner. Hypotheses were tested using multivariate analysis of variance.

The incidents at the Three Mile Island and Chernobyl have triggered the need for better personnel dosimetry methods in mixed radiation fields. This thesis presents a detailed computational study of a new method for mixed radiation field dosimetry using single-element TL dosimeters with pulsed laser heating schemes. The main objective of this study was to obtain an optimum heating scheme so that the depth-dose distribution in a thick TL dosimeter could be accurately determined. The major parts of the study include: (a) heat conduction calculations for TL dosimeters with various heating schemes, (b) glow curve calculations for TL dosimeters based on a first-order kinetic model, (c) unfolding of the depth-dose distribution based on the glow curve data, and (d) estimation of shallow and deep doses from the unfolded depth-dose distribution. Two optimum heating schemes were obtained in this study. The first one was obtained for a focused laser beam, and the second one was obtained for a uniform laser beam. Both heating schemes consist of two processes: top surface heating and bottom surface heating, and each process in turn consists of a sequence of laser pulses with various heating durations and power levels. Compared to the ``true`` depth-dose distribution obtained …

This report studied the elctronic structure of diamond (100) and diamond/metal interface and C{sub 60}, using angle-resolved and core level photoemission. The C(100)-(2X1) surface electronic structure was studied using both core level and angle resolved valence band photoemission spectroscopy. The surface component of the C 1s core level spectrum agrees with theoretical existence of only symmetrical dimers. In the case of metal/diamond interfaces, core level and valence photoelectron spectroscopy and LEED studies WERE MADE OF B and Sb on diamond (100) and (111) surfaces. In the case of single-crystal C{sub 60}, photoemission spectra show sharp molecular features, indicating that the molecular orbitals are relatively undisturbed in solid C{sub 60}.

The magnicon, a new high-power, radio frequency (rf) deflection- modulated amplifier, was recently developed at the Institute for Nuclear Physics in Novosibirsk, Russia. The first magnicon achieved a peak output power of 2.6 MW for 50-{mu}s pulses at a frequency of 915 MHz with a dc-to-rf conversion efficiency of 73%. The conversion efficiency achieved by the original magnicon represents a significant improvement over state-of-the-art conventional velocity- and density-modulated devices. Therefore, if properly exploited, the magnicon could substantially reduce the operating expenses of industrial, scientific, and military facilities that require large amounts of rf power. This dissertation describes the operational principles of the magnicon, provides small-signal analytical theory (where practical), presents a large-signal numerical model to characterize magnicon performance, and then utilizes this model to investigate the characteristics of the component magnicon structures. Using these modeling tools, the first-generation magnicon architecture is analyzed for its performance sensitivity to electron-beam size and is found to support beams of only limited diameter. Finally, an alternate magnicon geometry, called a ``uniform-field`` magnicon, is presented and shown to support beams of larger diameter.

The interaction of perfluorodiethoxymethane with a nickel single crystal, Ni(100); a nickel crystal with chemisorbed oxygen, Ni(100)-c(2x2)O; and a nickel crystal with nickel oxide crystallites, NiO(100) is investigated in an ultra high vacuum environment using thermal desorption spectroscopy and high resolution electron energy loss spectroscopy. Nickel, a component of hard disk drives and stainless steel, is used to represent metal surfaces in these {open_quotes}real{close_quotes} systems. Perfluorodiethoxymethane is used in this study as a model compound of industrial perfluoropolyether lubricants. These lubricants are known for their exceptional stability, except in the presence of metals. Perfluorodiethoxymethane contains the acetal group (-OCF{sub 2}O-), believed to be particularly vulnerable to attack in the presence of Lewis acids. Since the surfaces studied show increasing Lewis acidity at the nickel atom sites, one might expect to see increasing decomposition of perfluorodiethoxymethane due to acidic attack of the acetal group. No decomposition of perfluorodiethoxymethane is observed on the clean Ni(100) surface, while more research is needed to determine whether a small decomposition pathway is observed on the oxygenated surfaces, or whether sample impurities are interfering with results. The strength of the bonding of perfluorodiethoxymethane to the surface is found to increase as the nickel atoms sites become …

An experiment to measure the time reversal invariance violating (T-violating) triple correlation (D) in the decay of free polarized neutrons has been developed. The detector design incorporates a detector geometry that provides a significant improvement in the sensitivity over that used in the most sensitive of previous experiments. A prototype detector was tested in measurements with a cold neutron beam. Data resulting from the tests are presented. A detailed calculation of systematic effects has been performed and new diagnostic techniques that allow these effects to be measured have been developed. As the result of this work, a new experiment is under way that will improve the sensitivity to D to 3 {times} 10{sup {minus}4} or better. With higher neutron flux a statistical sensitivity of the order 3 {times} 10{sup {minus}5} is ultimately expected. The decay of free polarized neutrons (n {yields} p + e + {bar v}{sub e}) is used to search for T-violation by measuring the triple correlation of the neutron spin polarization, and the electron and proton momenta ({sigma}{sub n} {center_dot} p{sub p} {times} p{sub e}). This correlation changes sign under reversal of the motion. Since final state effects in neutron decay are small, a nonzero coefficient, D, …

Based on new diiodo aryl compounds a series of novel soluble polymers, poly(2,5-dialkoxy-1,4-phenyleneethynylene)s (PPE polymers) were synthesized using palladium-catalysis. The molecular weights (MW) range from 8,000 to 40,000. Properties such as absorption, fluorescence, and conductivity were studied. A PPE polymer with butoxy side chain exhibits a weak electrical conductivity ({sigma} = 10{sup {minus}3} S/cm) after doping with AsF{sub 5}. Absorption spectra in THF solution at room temperature (RT) show a maximum at 440 nm. However, absorption spectra of PPE polymers in the film state at (RT) show a maximum at 480 nm. PPE polymer-based light emitting diode (LED) devices have been prepared; greenish light from these LED devices can be observed. Poly(ethynylene-p-arylene-ethynylene-silylene)s were synthesized through the same palladium-catalyzed polymerization; MWs are between 6,000 and 82,000. Absorption and fluorescence were studied. Some of these polymers exhibit thermotropic liquid crystalline properties. In addition, nonlinear optical properties were briefly examined. Poly(silylene-ethynylene) homopolymers as well as alternating copolymers were synthesized through a novel palladium-catalyzed polymerization; MWs range from 56 {times} 10{sup 3} to 5.3 {times} 10{sup 3}. Thermal stability of these was also investigated; char yields range from 56 to 83%. One of these polymers exhibits thermotropic liquid crystalline properties.

Aqueous solutions of sodium sulfate and sodium sulfite are produced from sodium carbonate in flue-gas scrubbers; recovery of these salts often requires multi-effect evaporators; however, a new energy-efficient unit operation called extractive crystallization has been shown to have reduced energy costs. In this process, an organic solvent is added to the aqueous salt solution to precipitate salt. Acetone is a suitable solvent for this process, better than 2-propanol. Liquid/liquid/solid equilibria for ternary systems containing a salt, water, and an organic solvent were measured. Systems investigated were sodium sulfite/water/acetone and sodium sulfite/water/2-propanol. Experiments were conducted at salt saturation covering a temperature range between the lower consolute temperature and 48.6{degrees}C. In the attempt to improve the extractive crystallization process for recovery of sodium sulfate from flue-gas scrubbers, attention was given to a feed containing a mixture of sodium sulfite and sodium sulfate. Liquid-liquid equilibria for quaternary systems containing two salts, water, and an organic solvent were experimentally determined at 35{degrees}C. The systems investigated were sodium sulfate/sodium sulfite/water/acetone and sodium sulfate/sodium sulfite/water/2propanol. The systems were studied at three salt ratios. For each salt ratio, experiments were conducted starting at saturation, water was then added until the one-phase region was reached. Mixtures of the …