LIP: The Livermore Interpolation Package, Version 1.3 (open access)

LIP: The Livermore Interpolation Package, Version 1.3

This report describes LIP, the Livermore Interpolation Package. Because LIP is a stand-alone version of the interpolation package in the Livermore Equation of State (LEOS) access library, the initials LIP alternatively stand for the ''LEOS Interpolation Package''. LIP was totally rewritten from the package described in [1]. In particular, the independent variables are now referred to as x and y, since the package need not be restricted to equation of state data, which uses variables {rho} (density) and T (temperature). LIP is primarily concerned with the interpolation of two-dimensional data on a rectangular mesh. The interpolation methods provided include piecewise bilinear, reduced (12-term) bicubic, and bicubic Hermite (biherm). There is a monotonicity-preserving variant of the latter, known as bimond. For historical reasons, there is also a biquadratic interpolator, but this option is not recommended for general use. A birational method was added at version 1.3. In addition to direct interpolation of two-dimensional data, LIP includes a facility for inverse interpolation (at present, only in the second independent variable). For completeness, however, the package also supports a compatible one-dimensional interpolation capability. Parametric interpolation of points on a two-dimensional curve can be accomplished by treating the components as a pair of one-dimensional …
Date: January 4, 2011
Creator: Fritsch, F N
Object Type: Report
System: The UNT Digital Library
Nanotechnology applications to desalination : a report for the joint water reuse & desalination task force. (open access)

Nanotechnology applications to desalination : a report for the joint water reuse & desalination task force.

Nanomaterials and nanotechnology methods have been an integral part of international research over the past decade. Because many traditional water treatment technologies (e.g. membrane filtration, biofouling, scale inhibition, etc.) depend on nanoscale processes, it is reasonable to expect one outcome of nanotechnology research to be better, nano-engineered water treatment approaches. The most immediate, and possibly greatest, impact of nanotechnology on desalination methods will likely be the development of membranes engineered at the near-molecular level. Aquaporin proteins that channel water across cell membranes with very low energy inputs point to the potential for dramatically improved performance. Aquaporin-laced polymer membranes and aquaporin-mimicking carbon nanotubes and metal oxide membranes developed in the lab support this. A critical limitation to widespread use of nanoengineered desalination membranes will be their scalability to industrial fabrication processes. Subsequent, long-term improvements in nanoengineered membranes may result in self-healing membranes that ideally are (1) more resistant to biofouling, (2) have biocidal properties, and/or (3) selectively target trace contaminants.
Date: January 1, 2011
Creator: Brady, Patrick Vane; Mayer, Tom & Cygan, Randall Timothy
Object Type: Report
System: The UNT Digital Library
FY2010 ANNUAL REVIEW E-AREA LOW-LEVEL WASTE FACILITY PERFORMANCE ASSESSMENT AND COMPOSITE ANALYSIS (open access)

FY2010 ANNUAL REVIEW E-AREA LOW-LEVEL WASTE FACILITY PERFORMANCE ASSESSMENT AND COMPOSITE ANALYSIS

The E-Area Low-Level Waste Facility (ELLWF) consists of a number of disposal units described in the Performance Assessment (PA)(WSRC, 2008b) and Composite Analysis (CA)(WSRC, 1997; WSRC, 1999): Low-Activity Waste (LAW) Vault, Intermediate Level (IL) Vault, Trenches (Slit Trenches [STs], Engineered Trenches [ETs], and Component-in-Grout [CIG] Trenches), and Naval Reactor Component Disposal Areas (NRCDAs). This annual review evaluates the adequacy of the approved 2008 ELLWF PA along with the Special Analyses (SAs) approved since the PA was issued. The review also verifies that the Fiscal Year (FY) 2010 low-level waste (LLW) disposal operations were conducted within the bounds of the PA/SA baseline, the Savannah River Site (SRS) CA, and the Department of Energy (DOE) Disposal Authorization Statement (DAS). Important factors considered in this review include waste receipts, results from monitoring and research and development (R&D) programs, and the adequacy of controls derived from the PA/SA baseline. Sections 1.0 and 2.0 of this review are a summary of the adequacy of the PA/SA and CA, respectively. An evaluation of the FY2010 waste receipts and the resultant impact on the ELLWF is summarized in Section 3.1. The results of the monitoring program, R&D program, and other relevant factors are found in Section 3.2, …
Date: January 1, 2011
Creator: Butcher, T.; Swingle, R.; Crapse, K.; Millings, M. & Sink, D.
Object Type: Report
System: The UNT Digital Library
Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement Summary and Guide for Stakeholders (open access)

Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement Summary and Guide for Stakeholders

Pursuant to the Mercury Export Ban Act of 2008 (P.L. 110-414), DOE was directed to designate a facility or facilities for the long-term management and storage of elemental mercury generated within the United States. Therefore, DOE has analyzed the storage of up to 10,000 metric tons (11,000 tons) of elemental mercury in a facility(ies) constructed and operated in accordance with the Solid Waste Disposal Act, as amended by the Resource Conservation and Recovery Act (74 FR 31723). DOE prepared this Final Mercury Storage EIS in accordance with the National Environmental Policy Act of 1969 (NEPA), as amended (42 U.S.C. 4321 et seq.), the Council on Environmental Quality (CEQ) implementing regulations (40 CFR 1500–1508), and DOE’s NEPA implementing procedures (10 CFR 1021) to evaluate reasonable alternatives for a facility(ies) for the long-term management and storage of elemental mercury. This Final Mercury Storage EIS analyzes the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven candidate locations: Grand Junction Disposal Site near Grand Junction, Colorado; Hanford Site near Richland, Washington; Hawthorne Army Depot near Hawthorne, Nevada; Idaho National Laboratory near Idaho Falls, Idaho; Kansas City Plant in Kansas City, Missouri; Savannah River Site near Aiken, South Carolina; and …
Date: January 1, 2011
Creator: unknown
Object Type: Report
System: The UNT Digital Library

Active Power Control Testing at the U.S. National Wind Technology Center (NWTC)

In order to keep the electricity grid stable and the lights on, the power system relies on certain responses from its generating fleet. This presentation evaluates the potential for wind turbines and wind power plants to provide these services and assist the grid during critical times.
Date: January 1, 2011
Creator: Ela, E.
Object Type: Presentation
System: The UNT Digital Library

Community-Based Social Marketing

Presents how to create effective community weatherization assistance programs to foster sustainable behavior.
Date: January 1, 2011
Creator: Hollander, A.
Object Type: Presentation
System: The UNT Digital Library
A measurement of neutrino oscillations with muon neutrinos in the MINOS experiment (open access)

A measurement of neutrino oscillations with muon neutrinos in the MINOS experiment

Experimental evidence has established that neutrino flavor states evolve over time. A neutrino of a particular flavor that travels some distance can be detected in a different neutrino flavor state. The Main Injector Neutrino Oscillation Search (MINOS) is a long-baseline experiment that is designed to study this phenomenon, called neutrino oscillations. MINOS is based at Fermilab near Chicago, IL, and consists of two detectors: the Near Detector located at Fermilab, and the Far Detector, which is located in an old iron mine in Soudan, MN. Both detectors are exposed to a beam of muon neutrinos from the NuMI beamline, and MINOS measures the fraction of muon neutrinos that disappear after traveling the 734 km between the two detectors. One can measure the atmospheric neutrino mass splitting and mixing angle by observing the energy-dependence of this muon neutrino disappearance. MINOS has made several prior measurements of these parameters. Here I describe recently-developed techniques used to enhance our sensitivity to the oscillation parameters, and I present the results obtained when they are applied to a dataset that is twice as large as has been previously analyzed. We measure the mass splitting {Delta}m{sub 23}{sup 2} = (2.32{sub -0.08}{sup +0.12}) x 10{sup -3} eV{sup …
Date: January 1, 2011
Creator: Coleman, Stephen James & Coll., /William-Mary
Object Type: Thesis or Dissertation
System: The UNT Digital Library
REACTOR GROUT THERMAL PROPERTIES (open access)

REACTOR GROUT THERMAL PROPERTIES

Savannah River Site has five dormant nuclear production reactors. Long term disposition will require filling some reactor buildings with grout up to ground level. Portland cement based grout will be used to fill the buildings with the exception of some reactor tanks. Some reactor tanks contain significant quantities of aluminum which could react with Portland cement based grout to form hydrogen. Hydrogen production is a safety concern and gas generation could also compromise the structural integrity of the grout pour. Therefore, it was necessary to develop a non-Portland cement grout to fill reactors that contain significant quantities of aluminum. Grouts generate heat when they set, so the potential exists for large temperature increases in a large pour, which could compromise the integrity of the pour. The primary purpose of the testing reported here was to measure heat of hydration, specific heat, thermal conductivity and density of various reactor grouts under consideration so that these properties could be used to model transient heat transfer for different pouring strategies. A secondary purpose was to make qualitative judgments of grout pourability and hardened strength. Some reactor grout formulations were unacceptable because they generated too much heat, or started setting too fast, or required …
Date: January 28, 2011
Creator: Steimke, J.; Qureshi, Z.; Restivo, M. & Guerrero, H.
Object Type: Report
System: The UNT Digital Library
Neutrino-nucleus interactions (open access)

Neutrino-nucleus interactions

The study of neutrino oscillations has necessitated a new generation of neutrino experiments that are exploring neutrino-nuclear scattering processes. We focus in particular on charged-current quasi-elastic scattering, a particularly important channel that has been extensively investigated both in the bubble-chamber era and by current experiments. Recent results have led to theoretical reexamination of this process. We review the standard picture of quasi-elastic scattering as developed in electron scattering, review and discuss experimental results, and discuss additional nuclear effects such as exchange currents and short-range correlations that may play a significant role in neutrino-nucleus scattering.
Date: January 1, 2011
Creator: Gallagher, H.; Garvey, G. & Zeller, G. P.
Object Type: Article
System: The UNT Digital Library
Search for hadronic resonance in multijet final states with the CDF detector (open access)

Search for hadronic resonance in multijet final states with the CDF detector

This thesis describes a search for a new hadronic resonance in 3.2 fb{sup -1} of data using the Collider Detector at Fermilab. The Fermilab Tevatron accelerator collides beams of protons and antiprotons at a center of mass energy of {radical}s = 1.96 TeV. A unique approach is presented to extract multijet resonances from the large QCD background. Although the search is model independent, a pair produced supersymmetric gluino decaying through R-parity violation into three partons each is used to test our sensitivity to new physics. We measure these partons as jets, and require a minimum of six jets in an event. We make use of the kinematic features and correlations and use an ensemble of jet combinations to distinguish signal from multijet QCD backgrounds. Our background estimates also include all-hadronic t{bar t} decays that have a signature similar to signal. We observe no significant excess in an invariant mass range of 77 GeV/c{sup 2} to 240 GeV/c{sup 2} and place 95% C.L. limits on {sigma}(p{bar p} {yields} {tilde g}{tilde g} {yields} 3jets + 3jets) as a function of gluino invariant mass.
Date: January 1, 2011
Creator: Seitz, Claudia
Object Type: Report
System: The UNT Digital Library
Application of Developed APCVD Transparent Conducting Oxides and Undercoat Technologies for Economical OLED Lighting (open access)

Application of Developed APCVD Transparent Conducting Oxides and Undercoat Technologies for Economical OLED Lighting

Economics is a key factor for application of organic light emitting diodes (OLED) in general lighting relative to OLED flat panel displays that can handle high cost materials such as indium tin oxide (ITO) or Indium zinc oxide (IZO) as the transparent conducting oxide (TCO) on display glass. However, for OLED lighting to penetrate into general illumination, economics and sustainable materials are critical. The issues with ITO have been documented at the DOE SSL R&D and Manufacturing workshops for the last 5 years and the issue is being exacerbated by export controls from China (one of the major sources of elemental indium). Therefore, ITO is not sustainable because of the fluctuating costs and the United States (US) dependency on other nations such as China. Numerous alternatives to ITO/IZO are being evaluated such as Ag nanoparticles/nanowires, carbon nanotubes, graphene, and other metal oxides. Of these other metal oxides, doped zinc oxide has attracted a lot of attention over the last 10 years. The volume of zinc mined is a factor of 80,000 greater than indium and the US has significant volumes of zinc mined domestically, resulting in the ability for the US to be self-sufficient for this element that can be …
Date: January 2, 2011
Creator: Bluhm, Martin; Coffey, James; Korotkov, Roman; Polsz, Craig; Salemi, Alexandre; Smith, Robert et al.
Object Type: Report
System: The UNT Digital Library
LESSONS LEARNED FROM A RECENT LASER ACCIDENT (open access)

LESSONS LEARNED FROM A RECENT LASER ACCIDENT

A graduate student received a laser eye injury from a femtosecond Ti:sapphire laser beam while adjusting a polarizing beam splitter optic. The direct causes for the accident included failure to follow safe alignment practices and failure to wear the required laser eyewear protection. Underlying root causes included inadequate on-the-job training and supervision, inadequate adherence to requirements, and inadequate appreciation for dimly visible beams outside the range of 400-700nm. This paper describes how the accident occurred, discusses causes and lessons learned, and describes corrective actions being taken.
Date: January 26, 2011
Creator: Woods, Michael
Object Type: Article
System: The UNT Digital Library
LiWall Fusion - The New Concept of Magnetic Fusion (open access)

LiWall Fusion - The New Concept of Magnetic Fusion

Utilization of the outstanding abilities of a liquid lithium layer in pumping hydrogen isotopes leads to a new approach to magnetic fusion, called the LiWall Fusion. It relies on innovative plasma regimes with low edge density and high temperature. The approach combines fueling the plasma by neutral injection beams with the best possible elimination of outside neutral gas sources, which cools down the plasma edge. Prevention of cooling the plasma edge suppresses the dominant, temperature gradient related turbulence in the core. Such an approach is much more suitable for controlled fusion than the present practice, relying on high heating power for compensating essentially unlimited turbulent energy losses.
Date: January 12, 2011
Creator: Zakharov, L. E.
Object Type: Report
System: The UNT Digital Library
AGR-1 Irradiated Test Train Preliminary Inspection and Disassembly First Look (open access)

AGR-1 Irradiated Test Train Preliminary Inspection and Disassembly First Look

The AGR-1 irradiation experiment ended on November 6, 2009, after 620 effective full power days in the Advanced Test Reactor, achieving a peak burnup of 19.6% FIMA. The test train was shipped to the Materials and Fuels Complex in March 2010 for post-irradiation examination. The first PIE activities included non-destructive examination of the test train, followed by disassembly of the test train and individual capsules and detailed inspection of the capsule contents, including the fuel compacts and the graphite fuel holders. Dimensional measurements of the compacts, graphite holders, and steel capsules shells were performed using a custom vision measurement system (for outer diameters and lengths) and conventional bore gauges (for inner diameters). Gamma spectrometry of the intact test train gave a preliminary look at the condition of the interior components. No evidence of damage to compacts or graphite components was evident from the isotopic and gross gamma scans. Neutron radiography of the intact Capsule 2 showed a high degree of detail of interior components and confirmed the observation that there was no major damage to the capsule. Disassembly of the capsules was initiated using procedures qualified during out-of-cell mockup testing. Difficulties were encountered during capsule disassembly due to irradiation-induced changes …
Date: January 1, 2011
Creator: Demkowicz, Paul; Cole, Lance; Ploger, Scott; Winston, Philip; Pham, Binh & Abbott, Michael
Object Type: Report
System: The UNT Digital Library
Laser Safety: A Laser Alignment Practical Training Course (open access)

Laser Safety: A Laser Alignment Practical Training Course

SLAC National Accelerator Laboratory has developed a Laser Alignment Practical Training Course as one of its core laser safety classes. The course is taught to small groups of up to three students and takes 1-3 hours to complete. This practical course is not a substitute for site-specific On-the-Job Training; it does, however, provide a good introduction in core laser safety practices that can be broadly applied. Alignment and diagnostic tasks are performed with low power lasers. Students learn safe alignment and diagnostic techniques and how to avoid common mistakes that might lead to an accident. The class is taught by laser supervisors, enabling them to assess the skill level of new laser personnel and determine the subsequent level of supervision needed. The course has six alignment tasks. For each task, discussion points are given for the instructor to review with the students. The optics setup includes different wavelength lasers, a beam expander, mirrors, irises, a periscope, a beam-splitting polarizer and a diffraction grating. Diagnostic tools include viewing cards, an IR viewer and a ccd camera. Laser eyewear is available to block some laser wavelengths in the setup.
Date: January 26, 2011
Creator: Woods, Michael & Edstrom, Steve
Object Type: Article
System: The UNT Digital Library
NGNP Process Heat Applications: Hydrogen Production Accomplishments for FY2010 (open access)

NGNP Process Heat Applications: Hydrogen Production Accomplishments for FY2010

This report summarizes FY10 accomplishments of the Next Generation Nuclear Plant (NGNP) Engineering Process Heat Applications group in support of hydrogen production technology development. This organization is responsible for systems needed to transfer high temperature heat from a high temperature gas-cooled reactor (HTGR) reactor (being developed by the INL NGNP Project) to electric power generation and to potential industrial applications including the production of hydrogen.
Date: January 1, 2011
Creator: Park, Charles V
Object Type: Report
System: The UNT Digital Library
Evidence for a Mass Dependent Forward-Backward Asymmetry in Top Quark Pair Production (open access)

Evidence for a Mass Dependent Forward-Backward Asymmetry in Top Quark Pair Production

We present a new measurement of the inclusive forward-backward t{bar t} production asymmetry and its rapidity and mass dependence. The measurements are performed with data corresponding to an integrated luminosity of 5.3 fb{sup -1} of p{bar p} collisions at {radical}s = 1.96 TeV, recorded with the CDF II Detector at the Fermilab Tevatron. Significant inclusive asymmetries are observed in both the laboratory frame and the t{bar t} rest frame, and in both cases are found to be consistent with CP conservation under interchange of t and {bar t}. In the t{bar t} rest frame, the asymmetry is observed to increase with the t{bar t} rapidity difference, {Delta}y, and with the invariant mass M{sub t{bar t}} of the t{bar t} system. Fully corrected parton-level asymmetries are derived in two regions of each variable, and the asymmetry is found to be most significant at large {Delta}y and M{sub t{bar t}}. For M{sub t{bar t}} {ge} 450 GeV/c{sup 2}, the parton-level asymmetry in the t{bar t} rest frame is A{sup t{bar t}} = 0.475 {+-} 0.114 compared to a next-to-leading order QCD prediction of 0.088 {+-} 0.013.
Date: January 1, 2011
Creator: Aaltonen, T.; Phys., /Helsinki Inst. of; Alvarez Gonzalez, B.; Phys., /Cantabria Inst. of; Amerio, S.; /INFN, Padua et al.
Object Type: Article
System: The UNT Digital Library
Heavy hadron spectroscopy at CDF (open access)

Heavy hadron spectroscopy at CDF

We present recent CDF results on the properties of hadrons containing heavy quarks. These include measurements of charm and {Sigma}{sub b}{sup -}{Sigma}*{sub b}{sup -} baryon's masses, lifetimes and masses of {Omega}{sub b}{sup -}, {Xi}{sub b}{sup -} and B{sub c}{sup -} and a measurement of exclusive B{sup +}, B{sup 0} and {Lambda}{sub b} lifetimes as well as lifetime ratios (charge conjugate modes are implied throughout the text). We also summarize new measurements of exotic particles X(3872) and Y(4140).
Date: January 1, 2011
Creator: Fernandez Ramos, Juan Pablo & /Madrid, CIEMAT
Object Type: Article
System: The UNT Digital Library
Quantum Dot Light Enhancement Substrate for OLED Solid-State Lighting (open access)

Quantum Dot Light Enhancement Substrate for OLED Solid-State Lighting

With DOE Award No. DE-EE00000628, QD Vision developed and demonstrated a cost-competitive solution for increasing the light extraction efficiency of OLEDs with efficient and stable color rendering index (CRI) for solid state lighting (SSL). Solution processable quantum dot (QD) films were integrated into OLED ITO-glass substrates to generate tunable white emission from blue emitting OLED) devices as well as outcouple light from the ITO film. This QD light-enhancement substrate (QD-LED) technology demonstrated a 60% increase in OLED forward light out-coupling, a value which increases to 76% when considering total increase in multi-directional light output. The objective for the first year was an 80% increase in light output. This project seeks to develop and demonstrate a cost-competitive solution for realizing increased extraction efficiency organic light emitting devices (OLEDs) with efficient and stable color rendering index (CRI) for SSL. Solution processible quantum dot (QD) films will be utilized to generate tunable white emission from blue emitting phosphorescent OLED (Ph-OLED) devices.
Date: January 21, 2011
Creator: Perkins, James; Stevenson, Matthew; Mahan, Gagan; Coe-Sullivan, Seth & Kazlas, Peter
Object Type: Report
System: The UNT Digital Library
QCD Results from the Tevatron (open access)

QCD Results from the Tevatron

None
Date: January 1, 2011
Creator: Bandurin, Dmitry V.
Object Type: Article
System: The UNT Digital Library
Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada, For Fiscal Year 2010 (open access)

Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada, For Fiscal Year 2010

This report serves as the combined annual report for post-closure activities for the following closed Corrective Action Units (CAUs): (1) CAU 90, Area 2 Bitcutter Containment; (2) CAU 91, Area 3 U-3fi Injection Well; (3) CAU 92, Area 6 Decon Pond Facility; (4) CAU 110, Area 3 WMD U-3ax/bl Crater; and (5) CAU 112, Area 23 Hazardous Waste Trenches. The locations of the sites are shown in Figure 1. This report covers fiscal year 2010 (October 2009-September 2010). The post-closure requirements for these sites are described in Resource Conservation and Recovery Act Permit Number NEV HW0021 and summarized in each CAU-specific section in Section 1.0 of this report. Site inspections are conducted semiannually at CAUs 90 and 91 and quarterly at CAUs 92, 110, and 112. Additional inspections are conducted at CAU 92 if precipitation occurs in excess of 0.50 inches in a 24-hour period. Inspections include an evaluation of the condition of the units and identification of any deficiencies that may compromise the integrity of the units. The condition of covers, fencing, signs, gates, and locks is documented. In addition, soil moisture monitoring and subsidence surveys are conducted at CAU 110. The results of the inspections, summary of maintenance …
Date: January 26, 2011
Creator: National Security Technologies, LLC
Object Type: Report
System: The UNT Digital Library
Optimization of the safety factor profile for high noninductive current fraction discharges in DIII-D (open access)

Optimization of the safety factor profile for high noninductive current fraction discharges in DIII-D

None
Date: January 19, 2011
Creator: Ferron, J.; Holcomb, C.; Luce, T.; Politzer, P.; Turco, F.; White, A. et al.
Object Type: Article
System: The UNT Digital Library
A high-order finite-volume method for hyperbolic conservation laws on locally-refined grids (open access)

A high-order finite-volume method for hyperbolic conservation laws on locally-refined grids

We present a fourth-order accurate finite-volume method for solving time-dependent hyperbolic systems of conservation laws on Cartesian grids with multiple levels of refinement. The underlying method is a generalization of that in [5] to nonlinear systems, and is based on using fourth-order accurate quadratures for computing fluxes on faces, combined with fourth-order accurate Runge?Kutta discretization in time. To interpolate boundary conditions at refinement boundaries, we interpolate in time in a manner consistent with the individual stages of the Runge-Kutta method, and interpolate in space by solving a least-squares problem over a neighborhood of each target cell for the coefficients of a cubic polynomial. The method also uses a variation on the extremum-preserving limiter in [8], as well as slope flattening and a fourth-order accurate artificial viscosity for strong shocks. We show that the resulting method is fourth-order accurate for smooth solutions, and is robust in the presence of complex combinations of shocks and smooth flows.
Date: January 28, 2011
Creator: McCorquodale, Peter & Colella, Phillip
Object Type: Article
System: The UNT Digital Library
Development & Optimization of Materials and Processes for a Cost Effective Photoelectrochemical Hydrogen Production System (open access)

Development & Optimization of Materials and Processes for a Cost Effective Photoelectrochemical Hydrogen Production System

The overall project objective was to apply high throughput experimentation and combinatorial methods together with novel syntheses to discover and optimize efficient, practical, and economically sustainable materials for photoelectrochemical production of bulk hydrogen from water. Automated electrochemical synthesis and photoelectrochemical screening systems were designed and constructed and used to study a variety of new photoelectrocatalytic materials. We evaluated photocatalytic performance in the dark and under illumination with or without applied bias in a high-throughput manner and did detailed evaluation on many materials. Significant attention was given to -Fe2O3 based semiconductor materials and thin films with different dopants were synthesized by co-electrodeposition techniques. Approximately 30 dopants including Al, Zn, Cu, Ni, Co, Cr, Mo, Ti, Pt, etc. were investigated. Hematite thin films doped with Al, Ti, Pt, Cr, and Mo exhibited significant improvements in efficiency for photoelectrochemical water splitting compared with undoped hematite. In several cases we collaborated with theorists who used density functional theory to help explain performance trends and suggest new materials. The best materials were investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM), ultraviolet-visual spectroscopy (UV-Vis), X-ray photoelectron spectroscopy (XPS). The photoelectrocatalytic performance of the thin films was evaluated and their incident photon
Date: January 17, 2011
Creator: McFarland, Eric W.
Object Type: Text
System: The UNT Digital Library