Results from modeling of transformation toughening in brittle materials using a discrete micromechanical model are presented. The material is represented as a two-dimensional triangular array of nodes connected by elastic springs. Microstructural effects are included by varying the spring parameters for the bulk, grain boundaries, and transforming particles. Using the width of the damage zone and the effective compliance (after the initial creation of the damage zone) as measures of fracture toughness, we find that there is a strong dependence of toughness on the amount, size, and shape of the transforming particles, with the maximum toughness achieved with the higher amounts of the larger particles.

Clouds of low energy electrons in the vacuum beam pipes of accelerators of positively charged particle beams present a serious limitation for operation at high currents. Furthermore, it is difficult to probe their density over substantial lengths of the beam pipe. We have developed a novel technique to directly measure the electron cloud density via the phase shift induced in a TE wave transmitted over a section of the accelerator and used it to measure the average electron cloud density over a 50 m section in the positron ring of the PEP-II collider at the Stanford Linear Accelerator Center.

High brightness electron beam sources such as rf photo-injectors as proposed for SASE FELs must consistently produce the desired beam quality. We report the results of a study in which a combined neural network (NN) and first-principles (FP) model is used to model the transverse phase space of the beam as a function of quadrupole strength, while beam charge, solenoid field, accelerator gradient, and linac voltage and phase are kept constant. The parametric transport matrix between the exit of the linac section and the spectrometer screen constitutes the FP component of the combined model. The NN block provides the parameters of the transport matrix as functions of quad current. Using real data from SLAC Gun Test Facility, we will highlight the significance of the constrained training of the NN block and show that the phase space of the beam is accurately modeled by the combined NN and FP model, while variations of beam matrix parameters with the quad current are correctly captured. We plan to extend the combined model in the future to capture the effects of variations in beam charge, solenoid field, and accelerator voltage and phase.

By analyzing the pulse to pulse intensity fluctuations of the radiation emitted by a charge particle in the incoherent part of the spectrum, it is possible to extract information about the spatial distribution of the beam. At the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory, we have developed and tested a simple scheme based on this principle that allows for the absolute measurement of the bunch length. A description of the method and the experimental results are presented.

We consider the properties of {Omega} graphs ({Omega} vs f(z)) obtained from Gouy interferometry on multicomponent systems with constant diffusion coefficients. We show that they must have (a) either a maximum or else a minimum between f(z)=0 and f(z)=1 and (b) an inflection point between the f(z) value at the extremum and f(z)=1. Consequently, an {Omega} graph cannot have both positive and negative {Omega} values.

The experimental study of the water-rock interaction shows that the secondary mineral assemblage depends on the water composition. For example, granite-pure water interaction produces zeolites (relatively low-dense, Mg-poor minerals), whereas seawater yields chlorites (high-dense, Mg-rich minerals). The reactions have volumetric effects from several % to 20 % in magnitude. Volume deformations in the heterogeneous matrix cause uneven mechanical strains. Reactions with the effect of about 0,1 vol.% may cause strains of the order of 100-1000 bars being enough for destruction of rocks. Signs and magnitudes of local volume changes depend on the mineral composition of the secondary assemblage. Hence, one can provide either healing or cracking of primary fractures, as desired, by changing the composition of water in the water-felsic rock system where some elements (Mg, Fe) are in lack. The techniques of "chemical hydrofracturing" looks promising as applied to a granite HDR massif. One can regulate the permeability of fractured flow paths by changing in concord the composition and pressure of the injected water. This approach should promote efficient extraction of the petrothermal energy.

The U.S. Department of Energy, Division of Geothermal Energy and Division of Geothermal Resource Management, sponsored a Resource Assessment/Commercialization Planning meeting in Salt Lake City on January 21-24, 1980. The meeting included presentations by state planning and resource teams from all DOE regions. An estimated 130 people representing federal, state and local agencies, industry and private developers attended.

The orientation relationship, habit plane, parent-product interface at the atomic level, twin relationship, and plastic deformation resulting from the {delta} {yields} {alpha}{prime} isothermal martensitic transformation in Pu-Ga alloys are examined using optical microscopy, transmission electron microscopy, and finite element calculations. The {delta} {yields} {alpha}{prime} transformation exhibits a {approx}20% volume collapse when the face-centered cubic {delta} phase transforms to the monoclinic {alpha}{prime} phase, which results in unique and intriguing crystallography and morphology. Here, we show that the orientation relationship is very close to that previously reported by Zocco et al. (1990), but has small rotational misalignments between the two phases both parallel and perpendicular to the [110]{sub {delta}} {parallel}[100]{sub {alpha}{prime}} direction. The amount of plastic deformation is exceedingly large due to the {approx}20% volume collapse and transmission electron microscopy is used to quantify the difference in dislocation density between untransformed {delta}-matrix and regions of {delta} adjacent to the transformed {alpha}{prime}. The twins contained in {alpha}{prime} plates are shown to have a (205){sub {alpha}} orientation as the lattice invariant deformation and are found to be composed of two alternating variants that share a common <020>{sub {alpha}{prime}} direction, but differ by a 60 degree rotation about <020>{sub {alpha}{prime}}. A combination of electron diffraction …

Incoherent electron effects could seriously limit the beam lifetime in proton or ion storage rings, such as LHC, SPS, or RHIC, or blow up the vertical emittance of positron beams, e.g., at the B factories or in linear-collider damping rings. Different approaches to modeling these effects each have their own merits and drawbacks. We describe several simulation codes which simplify the descriptions of the beam-electron interaction and of the accelerator structure in various different ways, and present results for a toy model of the SPS. In addition, we present evidence that for positron beams the interplay of incoherent electron-cloud effects and synchrotron radiation can lead to a significant increase in vertical equilibrium emittance. The magnitude of a few incoherent e{sup +}e{sup -} scattering processes is also estimated. Options for future code development are reviewed.

Recent studies of nuclear mass models show that it is essential to account for the Coulomb redistribution energy when calculating the nuclear potential energy in the heavy-element region. Results obtained by use of a mass model that includes Coulomb redistribution effects on analyzed. Q values of {alpha} and {beta} decay are calculated. Half-lives for {alpha} decay are estimated by use of the Viola-Seaborg systematics. For EC, {beta}{sup +} decay and {beta}{sup {minus}} decay, half-lives are calculated in a microscopic QRPA model. Calculated single-particle level structures in the heavy-element regions are presented. These indicate possible regions of isomers that would be unusually stable with respect to spontaneous fission and {alpha} decay. Finally, we discuss the implications of earlier extensive work on fission properties of nuclei in this region.

The beam-target interaction in heavy ion fusion is theoretically understood, but experimental verification at appropriate beam intensities is not possible using existing accelerators. If fusion-intensity ion beams were to lose significantly less energy in passing through matter than calculated it would increase the cost of heavy ion fusion. In the worst case the cost scaling is such that a 25% decrease in energy loss would increase the cost of the accelerator by roughly 10%. In this paper we show that fundamental considerations place a lower bound on ion energy loss. The lower bound is not significantly less than the expected energy loss obtained from detailed calculations.

Recent studies of nuclear mass models show that it is essential to account for the Coulomb redistribution energy when calculating the nuclear potential energy in the heavy-element region. Results obtained by use of a mass model that includes Coulomb redistribution effects on analyzed. Q values of {alpha} and {beta} decay are calculated. Half-lives for {alpha} decay are estimated by use of the Viola-Seaborg systematics. For EC, {beta}{sup +} decay and {beta}{sup {minus}} decay, half-lives are calculated in a microscopic QRPA model. Calculated single-particle level structures in the heavy-element regions are presented. These indicate possible regions of isomers that would be unusually stable with respect to spontaneous fission and {alpha} decay. Finally, we discuss the implications of earlier extensive work on fission properties of nuclei in this region.

Remediation of the Department of Energy (DOE) Fernald site located north of Cincinnati will generate large quantities of low-level radwaste. This volume includes approximately 1,050,000 tons of material to be removed from eight waste pits comprising Operable Unit 1 (OU-1). The remedial alternative selected includes waste material excavation, drying and transportation by rail to a burial site in the arid west for disposal. Rail transportation was selected not only because rail transportation is safer than truck transportation, but also because of the sheer magnitude of the project and the availability of bulk rail car unloading facilities at a representative disposal site. Based upon current waste quantity estimates as presented in the Feasibility Study for OUI, a fully-loaded 47-car unit train would depart the Fernald site weekly for five years. This paper illustrates the steps taken to obtain agency and public acceptance of the Record of Decision for the remedy which hinged on rail transportation. A preliminary, but detailed, rail transportation plan was prepared for the project to support a series of CERCLA public meetings conducted in late 1994. Some of the major issues addressed in the plan included the following: (1) Scope of project leading to selection of rail transportation; …

The vector fields of the quantum Lie algebra are described for the quantum groups GL{sub q}(n), SL{sub q}(N) and SO{sub q}(N) as pseudodifferential operators on the linear quantum spaces covariant under the corresponding quantum group. Their expressions are simple and compact. It is pointed out that these vector fields satisfy certain characteristic polynomial identities. The real forms SU{sub q}(N) and SO{sub q}(N,R) are discussed in detail.

The detection, localization and classification of acoustic sources (targets) in a hostile ocean environment is a difficult problem -- especially in light of the improved design of modern submarines and the continual improvement in quieting technology. Further the advent of more and more diesel-powered vessels makes the detection problem even more formidable than ever before. It has recently been recognized that the incorporation of a mathematical model that accurately represents the phenomenology under investigation can vastly improve the performance of any processor, assuming, of course, that the model is accurate. Therefore, it is necessary to incorporate more knowledge about the ocean environment into detection and localization algorithms in order to enhance the overall signal-to-noise ratios and improve performance. An alternative methodology to matched-field/matched-mode processing is the so-called model-based processor which is based on a state-space representation of the normal-mode propagation model. If state-space solutions can be accomplished, then many of the current ocean acoustic processing problems can be analyzed and solved using this framework to analyze performance results based on firm statistical and system theoretic grounds. The model-based approach, is (simply) ``incorporating mathematical models of both physical phenomenology and the measurement processes including noise into the processor to extract the …

Tomographic images of tissue phantoms and a sample of breast tissue have been produced from an acoustic synthetic array system for frequencies near 500 kHz. The images for sound speed and attenuation show millimeter resolution and demonstrate the feasibility of obtaining high-resolution tomographic images with frequencies that can deeply penetrate tissue. The image reconstruction method is based on the Born approximation to acoustic scattering and is a simplified version of a method previously used by Andre (Andre, et. al., Int. J. Imaging Systems and Technology, Vol 8, No. 1, 1997) for a circular acoustic array system. The images have comparable resolution to conventional ultrasound images at much higher frequencies (3-5 MHz) but with lower speckle noise. This shows the potential of low frequency, deeply penetrating, ultrasound for high-resolution quantitative imaging.

A task was undertaken to characterize glovebox gloves that are currently used in the facilities at Savannah River Site (SRS) as well as some experimental and advanced compound gloves that have been proposed for use. Gloves from four manufacturers were tested for permeation in hydrogen and air, thermal stability, tensile properties, puncture resistance and dynamic mechanical response. The gloves were compared to each other within the type and also to the butyl rubber glove that is widely used at the SRS. The permeation testing demonstrated that the butyl compounds from three of the vendors behaved similarly and exhibited hydrogen permeabilities of .52‐.84 x10{sup ‐7} cc H{sub 2}*cm / (cm{sup 2}*atm). The Viton� glove performed at the lower edge of this bound, while the more advanced composite gloves exhibited permeabilities greater than a factor of two compared to butyl. Thermogravimetric analysis was used to determine the amount of material lost under slightly aggressive conditions. Glove losses are important since they can affect the life of glovebox stripper systems. During testing at 90, 120, and 150�C, the samples lost most of the mass in the initial 60 minutes of thermal exposure and as expected increasing the temperature increased the mass loss and …

The release of {sup 222}Radon to the atmosphere is controlled by the rate of its gas transport through earthen materials. Of the many soil-related parameters, radon diffusion coefficient is the key parameter that characterizes this transport. We compared the radon diffusion coefficients measured at the laboratories for the UMTRA Project with simple empirical correlations developed by others. The empirical correlations predict the radon diffusion coefficient based on the fraction of moisture saturation and porosity. One of the more recent correlations agrees reasonably well with the measurements. In addition, by using a series of correlation curves, we studied the empirical relationships of the. radon diffusion coefficient with the saturated hydraulic conductivity, the fines content, and the moisture saturation in soil. The results reveal that a reliable determination of the long-term moisture and porosity is essential in the design of an adequate radon barrier with respect to the radon diffusion coefficient.

Supported catalysts are widely used in industry and can be optimized by tuning the composition and interface of the metal nanoparticles and oxide supports. Rational design of metal-metal oxide interfaces in nanostructured catalysts is critical to achieve better reaction activities and selectivities. We introduce here a new class of nanocrystal tandem catalysts that have multiple metal-metal oxide interfaces for the catalysis of sequential reactions. We utilized a nanocrystal bilayer structure formed by assembling platinum and cerium oxide nanocube monolayers of less than 10 nm on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2-Pt and Pt-SiO2, can be used to catalyse two distinct sequential reactions. The CeO2-Pt interface catalysed methanol decomposition to produce CO and H2, which were subsequently used for ethylene hydroformylation catalysed by the nearby Pt-SiO2 interface. Consequently, propanal was produced selectively from methanol and ethylene on the nanocrystal bilayer tandem catalyst. This new concept of nanocrystal tandem catalysis represents a powerful approach towards designing high-performance, multifunctional nanostructured catalysts

Well SN-12 in the Seltjarnarnes low-temperature field in SW-Iceland was drilled to a depth of 2714 m in the fall of 1994. The well appeared to be almost non-productive at the end of drilling. A comprehensive ten day stimulation program was, therefore, initiated. The program involved, firstly, high-pressure wellhead injection and, secondly, high-pressure injection below a packer placed at 1412 m depth. After about twelve hours of wellhead stimulation the pressure dropped suddenly, indicating that the well had been stimulated. At the same time the water level response increased suddenly in two near-by monitoring wells. During the second stimulation phase (packer at 1412 m) the well appeared to be stimulated even further. The well eventually produced about 35 l/s with a drawdown of roughly 60 m, and the stimulation had increased the yield of the well by a factor of nearly 60. Thus well SN-12, which appeared to be almost non-productive at the completion of drilling, had turned into a good production well. It is believed that during the stimulation some previously closed fractures, or interbed contacts, reopened connecting well SN-12 to the main fracture system of the geothermal reservoir.

High-temperature hydrothermal systems are physically and chemically zoned with depth. The energy input is from a magmatic zone, intruded by igneous bodies, that may also contribute variable amounts of magmatic fluid to the system. The heat source is directly overlain by a section of rocks, that due to their elevated temperature, respond to stress in a ductile fashion. The ductile zone is, in turn, overlain by a section of rocks that respond to stress in a brittle fashion, where water is able to circulate through fractures (the geothermal reservoir) and will be termed the hydrothermal circulation zone. Ancient and modern high-temperature geothermal systems show a predictable sequence of evolutionary events affecting these stratified zones. Metamorphic core complexes are uplifts, formed in highly extended terrains, that expose fossil brittle-ductile transition zones. Formerly ductile rocks have had brittle fractures superimposed on them, and meteoric hydrothermal systems are associated with the brittle fracturing. Porphyry copper deposits typically evolve from magmatic to meteoric hydrothermal systems. At the Larderello geothermal system, the brittle- ductile transition has been mapped using reflection seismology, and the zone has been penetrated by the San Pompeo 2 well where temperatures >420°C were encountered. Although neo-granitic dikes have been penetrated by …

Well AH-4_bis, at the Ahuachapan Geothermal Field is planned to be drilled on the same pad as the former AH-4. A simulation study was carried out for two casing dameters 13 5/8 and 9 5/8” in order to estimate its production and to know its economic feasibility. The simulation results indcate a high probability of production in the range of 7 Mwe, equivalent to 120 kg/s total mass flow rate, 1250 kJ/kg at 6 bar-a for the new well AH-4_bis. Well AH- 17 is good producer, during 1991 after ten years of production, the well was shut-in due to silica scaling problems. A wellbore simulation was carried out in order to predict the new production conditions after the work-over, mainly to estimate the water flow rate in order to reduce the silica scaling. The results indicate a very low water flow rate. The match between the simulated and measured production curves after the work-over was successful. The well AH-18 is located at the southern part of the actual bore field. CEL is planning to expand the borefield at this area and it is neccessary to estimate the possible production condtions at that zone. The results indicate a high probabilty of …

Previous measurements of acoustic velocities on NEGU- 17 cores indicate that saturation effects are significant enough to cause V_p/V_s anomalies observed in the field. In this study we report on the results of new measurements on core recently recovered from SB-15-D along with some additional measurements on the NEGU-17 cores. The measurements indicate correlations between mechanical, transport, and water storage properties of the matrix which may prove useful for reservoir assessment and management. The SB-15-D material is found to be similar to the NEGU-17 material in terms of acoustic velocities, being characterized by a notably weak pressure dependence on the velocities and a modest V_p/V_s signature of saturation. The effect of saturation on V_p/V_s appears to result in part from a chemo-mechanical weakening of the shear modulus due to the presence of water. Electrical properties of SB-15-D material are qualitatively similar to those of the NEGU-17 cores, although resistivities of SB-15-D cores are notably lower and dielectric permittivities higher than in their NEGU- 17 counterparts. While some limited correlations of measured properties with depth are noted, no clear change in character is observed within SB-15-D cores which can be associated with the proposed cap-rock/reservoir boundary.

A numerical simulation model for the Heber geothermal field in Southern California is being developed under a technology transfer agreement between the Department of Energy/Lawrence Berkeley National Laboratory (LBNL) and the California Department of Conservation, Division of Oil, Gas, and Geothermal Resources (DOGGR). The main objectives of the cooperation are (1) to train DOGGR personnel in the use of the TOUGH2PC computer code; and (2) to develop a module compatible with TOUGH2 to investigate the effects of production/injection operations on the ground surface subsidence-rebound phenomenon observed in the Heber geothermal field. Initial-state calibration (undisturbed system) runs are being conducted to calibrate the model.