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Stellarmak a hybrid stellarator: Spheromak (open access)

Stellarmak a hybrid stellarator: Spheromak

This paper discusses hybridization of modified Stellarator-like transform windings (T-windings) with a Spheromak or Field-Reversed-Mirror configuration. This configuration, Stellarmak, retains the important topological advantage of the Spheromak or FRM of having no plasma linking conductors or blankets. The T-windings provide rotational transformation in toroidal angle of the outer poloidal field lines, in effect creating a reversed B/sub Toroidal/ Spheromak or adding average B/sub T/ to the FRM producing higher shear, increased limiting ..beta.., and possibly greater stability to kinks and tilt. The presence of field ripple in the toroidal direction may be sufficient to inhibit cancellation of directed ion current by electron drag to allow steady state operation with the toroidal as well as poloidal current maintained by neutral beams.
Date: January 4, 1980
Creator: Hartman, C. W.
System: The UNT Digital Library
Recovering the Elemental Composition of Comet Wild 2 Dust in Five Stardust Impact Tracks and Terminal Particles in Aerogel (open access)

Recovering the Elemental Composition of Comet Wild 2 Dust in Five Stardust Impact Tracks and Terminal Particles in Aerogel

The elemental (non-volatile) composition of five Stardust impact tracks and terminal particles left from capture of Comet 81P/Wild 2 dust were mapped in a synchrotron x-ray scanning microprobe with full fluorescence spectra at each pixel. Because aerogel includes background levels of several elements of interest, we employ a novel 'dual threshold' approach to discriminate against background contaminants: an upper threshold, above which a spectrum contains cometary material plus aerogel and a lower threshold below which it contains only aerogel. The difference between normalized cometary-plus-background and background-only spectra is attributable to cometary material. The few spectra in between are discarded since misallocation is detrimental: cometary material incorrectly placed in the background spectrum is later subtracted from the cometary spectrum, doubling the loss of reportable cometary material. This approach improves precision of composition quantification. We present the refined whole impact track and terminal particle elemental abundances for the five impact tracks. One track shows mass increases in Cr and Mn (1.4x), Cu, As and K (2x), Zn (4x) and total mass (13%) by dual thresholds compared to a single threshold. Major elements Fe and Ni are not significantly affected. The additional Cr arises from cometary material containing little Fe. We exclude Au …
Date: January 4, 2007
Creator: Ishii, H. A.; Brennan, S.; Bradley, J. P.; Luening, K.; Ignatyev, K. & Pianetta, P.
System: The UNT Digital Library
Emergence of Strong Exchange Interaction in the Actinide Series: The Driving Force for Magnetic Stabilization of Curium (open access)

Emergence of Strong Exchange Interaction in the Actinide Series: The Driving Force for Magnetic Stabilization of Curium

Using electron energy-loss spectroscopy in a transmission electron microscope, many-electron atomic spectral calculations and density functional theory, we examine the electronic and magnetic structure of Cm metal. We show that angular momentum coupling in the 5f states plays a decisive role in the formation of the magnetic moment. The 5f states of Cm in intermediate coupling are strongly shifted towards the LS coupling limit due to exchange interaction, unlike most actinide elements where the effective spin-orbit interaction prevails. It is this LS-inclined intermediate coupling that is the key to producing the large spin polarization which in turn dictates the newly found crystal structure of Cm under pressure.
Date: January 4, 2007
Creator: Moore, K; der Laan, G v; Haire, D; Wall, M; Schwartz, A & Soderlind, P
System: The UNT Digital Library
Booming Plutons: Source of microearthquakes in South Carolina (open access)

Booming Plutons: Source of microearthquakes in South Carolina

None
Date: January 4, 2006
Creator: Stevenson, Donald
System: The UNT Digital Library
Radiative and Dynamical Feedbacks Over the Equatorial Cold-Tongue: Results from Seven Atmospheric GCMs (open access)

Radiative and Dynamical Feedbacks Over the Equatorial Cold-Tongue: Results from Seven Atmospheric GCMs

The equatorial Pacific is a region with strong negative feedbacks. Yet coupled GCMs have exhibited a propensity to develop a significant SST bias in that region, suggesting an unrealistic sensitivity in the coupled models to small energy flux errors that inevitably occur in the individual model components. Could this 'hypersensitivity' exhibited in a coupled model be due to an underestimate of the strength of the negative feedbacks in this region? With this suspicion, the feedbacks in the equatorial Pacific in seven atmospheric GCMs (AGCMs) have been quantified using the interannual variations in that region and compared with the corresponding calculations from the observations. The seven AGCMs are: the NCAR CAM1, the NCAR CAM2,the NCAR CAM3, the NASA/NSIPP Atmospheric Model, the Hadley Center Model, the GFDL AM2p10, and the GFDL AM2p12. All the corresponding coupled runs of these seven AGCMs have an excessive cold-tongue in the equatorial Pacific. The net atmospheric feedback over the equatorial Pacific in the two GFDL models is found to be comparable to the observed value. All other models are found to have a weaker negative net feedback from the atmosphere--a weaker regulating effect on the underlying SST than the real atmosphere. A weaker negative feedback from …
Date: January 4, 2005
Creator: Sun, D.; Zhang, T.; Covey, C.; Klein, S.; Collins, W.; Kiehl, J. et al.
System: The UNT Digital Library
Reply to Comment on "Ab Initio Study of 40Ca with an Importance Truncated No-Core Shell Model" (open access)

Reply to Comment on "Ab Initio Study of 40Ca with an Importance Truncated No-Core Shell Model"

In their comment on our recent Letter [1] Dean et al. [2] criticize the calculations for the ground-state energy of {sup 40}Ca within the importance truncated no-core shell model (NCSM). In particular they address the role of configurations beyond the 3p3h level, which have not been included in the {sup 40}Ca calculations for large N{sub max} {h_bar}{Omega} model spaces. Before responding to this point, the following general statements are in order. For the atomic nucleus as a self-bound system, translational invariance is an important symmetry. The only possibility to preserve translational invariance when working with a Slater determinant basis is to use the harmonic oscillator (HO) basis in conjunction with a basis truncation according to the total HO excitation energy, i.e. N{sub max} {h_bar}{Omega}, as done in the ab initio NCSM. This is important not only for obtaining proper binding or excitation energies, but also for a correct extraction of physical wavefunctions. The spurious center-of-mass components can be exactly removed only if the HO basis and the N{sub max} {h_bar}{Omega} truncation are employed. The minimal violation of the translational invariance was one of the main motivations for developing the importance-truncation scheme introduced in the Letter. In this scheme, we start …
Date: January 4, 2008
Creator: Roth, R & Navratil, P
System: The UNT Digital Library
Analysis of closed-pool boilup using the TRANSIT-HYDRO code. [LMFBR] (open access)

Analysis of closed-pool boilup using the TRANSIT-HYDRO code. [LMFBR]

The benign termination of the transition phase of a hypothetical LMFBR accident rests on the avoidance of highly energetic recriticalities prior to escape of bottled molten core materials from the active core region. In scenarios where molten fuel is trapped due to axial blockages, the maintenance of subcritical configurations until radial flow paths develop requires stable boil-up of the molten fuel/steel mixture. This paper describes the analysis of an experiment investigating the behavior of closed boiling pools using the two-fluid hydrodynamics module of TRANSIT-HYDRO, a deterministic transition-phase analysis code.
Date: January 4, 1983
Creator: Graff, D.L.
System: The UNT Digital Library
Thermal Conductivity, Diffusivity and Expansion of Avery Island Salt at Pressure and Temperature (open access)

Thermal Conductivity, Diffusivity and Expansion of Avery Island Salt at Pressure and Temperature

Preliminary data on the thermal properties of a coarse-grained rock salt from Avery Island, Louisiana, indicates that hydrostatic pressure to 50 MPa has little effect on the thermal conductivity, diffusivity and linear expansion at temperatures from 300 to 573 K. The measurements were made in a new apparatus under conditions of true hydrostatic loading. At room temperature and effective confining pressure increasing from 10 to 50 MPa, thermal conductivity and diffusivity are constant at roughly 7W/mK and 3.6 x 10/sup -6/ m/sup 2//s, respectively. At 50 MPa and temperature increasing from 300 to 573K, both conductivity and diffusivity drop by a factor of 2. Thermal linear expansion at 0 MPa matches that at 50 MPa, increasing from roughly 4.2 x 10/sup -5//K at 300 K to 5.5 x 10/sup -5/ at 573 K. The lack of a pressure effect on all three properties is confirmed by previous work. Simple models of microcracking suggest that among common geological materials the lack of pressure dependence is unique to rock salt.
Date: January 4, 1980
Creator: Durham, W. B.; Abey, A. E. & Trimmer, D. A.
System: The UNT Digital Library
X-band microwave backscattering from ocean waves (open access)

X-band microwave backscattering from ocean waves

Backscattering experiments at microwave frequencies were conducted off the west coast of Scotland in the summer of 1991. Using a dual-polarization, 8-frequency X-band coherent scatterometer mounted on the bow of a boat, we measured time-resolved backscattering from ocean waves at a range of grazing angles from 10{degrees} to 70{degrees}. From the grazing-angle-dependent signals and their Doppler spectra, we differentiate Bragg scattering from non-Bragg scattering and resolve ``peak separation`` between the vertical and horizontal polarizations. We observe instances of ``super`` events, i.e., instances when the horizontal polarization return power equals or exceeds the vertical polarization power. We find that ``super`` events occur not only at low grazing angles but at any grazing angle for against-wind viewing directions. Statistics for such occurrences as a function of grazing angle are obtained. We study the coherence properties of scatterers and find strong evidence that at low grazing angles, lifetime-dominated, non-Bragg scattering contributes noticeably to returns of both polarizations, but is dominant in providing returns for the horizontal polarization. We examine ``spiking`` events and find that they can be related to, but need not be limited to, breaking wave events. By comparing the data of against-wind runs with cross-wind and circle runs, we obtain wind-direction …
Date: January 4, 1994
Creator: Lee, P. H. Y.; Barter, J. D. & Beach, K. L.
System: The UNT Digital Library
MODELING ANALYSIS FOR GROUT HOPPER WASTE TANK (open access)

MODELING ANALYSIS FOR GROUT HOPPER WASTE TANK

The Saltstone facility at Savannah River Site (SRS) has a grout hopper tank to provide agitator stirring of the Saltstone feed materials. The tank has about 300 gallon capacity to provide a larger working volume for the grout nuclear waste slurry to be held in case of a process upset, and it is equipped with a mechanical agitator, which is intended to keep the grout in motion and agitated so that it won't start to set up. The primary objective of the work was to evaluate the flow performance for mechanical agitators to prevent vortex pull-through for an adequate stirring of the feed materials and to estimate an agitator speed which provides acceptable flow performance with a 45{sup o} pitched four-blade agitator. In addition, the power consumption required for the agitator operation was estimated. The modeling calculations were performed by taking two steps of the Computational Fluid Dynamics (CFD) modeling approach. As a first step, a simple single-stage agitator model with 45{sup o} pitched propeller blades was developed for the initial scoping analysis of the flow pattern behaviors for a range of different operating conditions. Based on the initial phase-1 results, the phase-2 model with a two-stage agitator was developed …
Date: January 4, 2012
Creator: Lee, S.
System: The UNT Digital Library
Stockpile Stewardship and the National Ignition Facility (open access)

Stockpile Stewardship and the National Ignition Facility

The National Ignition Facility (NIF), the world's most energetic laser system, is operational at Lawrence Livermore National Laboratory (LLNL). Since the completion of the construction project in March 2009, NIF has completed nearly 150 target experiments for the National Ignition Campaign (NIC), High Energy Density Stewardship Science (HEDSS) in the areas of radiation transport, material dynamics at high pressure in the solid state, as well as fundamental science and other national security missions. NIF capabilities and infrastructure are in place to support all of its missions with over 50 X-ray, optical and nuclear diagnostic systems and the ability to shoot cryogenic targets and DT layered capsules. NIF is now qualified for use of tritium and other special materials as well as to perform high yield experiments and classified experiments. DT implosions with record indirect-drive neutron yield of 4.5 x 10{sup 14} neutrons have been achieved. A series of 43 experiments were successfully executed over a 27-day period, demonstrating the ability to perform precise experiments in new regimes of interest to HEDSS. This talk will provide an update of the progress on the NIF capabilities, NIC accomplishments, as well as HEDSS and fundamental science experimental results and an update of the …
Date: January 4, 2012
Creator: Moses, E.
System: The UNT Digital Library
Universality of Unintegrated Gluon Distributions at small x (open access)

Universality of Unintegrated Gluon Distributions at small x

We systematically study dijet production in various processes in the small-x limit and establish an effective kt-factorization for hard processes in a system with dilute probes scattering on a dense target. In the large-Nc limit, the unintegrated gluon distributions involved in different processes are shown to be related to two widely proposed ones: the Weizsacker-Williams gluon distribution and the dipole gluon distribution.
Date: January 4, 2011
Creator: Dominguez, Fabio; Marquet, Cyrille; Xiao, Bowen & Yuan, Feng
System: The UNT Digital Library
Boron and hydrogen in Ni{sub 3}Al: Part 2, Mechanical testing of bicrystals (open access)

Boron and hydrogen in Ni{sub 3}Al: Part 2, Mechanical testing of bicrystals

To provide a sensitive measurement of the effect of boron segregation on the strength and ductility of Ni{sub 3}Al grain boundaries, bicrystal tensile tests were performed on small specimens of boron doped Ni{sub 76}Al{sub 24} cut from extremely large-grained boules. Five specimens with the same ``random`` or low-symmetry grain boundary (disorientations measured by means of backscattered Kikuchi patterns) and two specimens with a second random grain boundary were tested in quenched and slow-cooled conditions. Duplicate tests performed in a low (7 ppM) water-vapor environment showed that the fracture mode and the stress and strain at fracture are altered by environmental embrittlement at individual, partially strengthened grain boundaries.
Date: January 4, 1994
Creator: Johnson, P. E.; Gourdin, W.; Gonis, A.; Kioussis, N. & Vaudin, M.
System: The UNT Digital Library
DISTRIBUTION AND RANGE OF RADIONUCLIDE SORPTIOIN COEFFICIENTS IN A SAVANNAH RIVER SITE SUBSURFACE: STOCHASTIC MODELING CONSIDERATIONS - 10259 (open access)

DISTRIBUTION AND RANGE OF RADIONUCLIDE SORPTIOIN COEFFICIENTS IN A SAVANNAH RIVER SITE SUBSURFACE: STOCHASTIC MODELING CONSIDERATIONS - 10259

The uncertainty associated with the sorption coefficient, or K{sub d} value, is one of the key uncertainties in estimating risk associated with burying low-level nuclear waste in the subsurface. The objective of this study was to measure >648 K{sub d} values and provide a measure of the range and distribution (normal or log-normal) of radionuclide K{sub d} values appropriate for the E-Area disposal site, within the Savannah River Site, near Aiken South Carolina. The 95% confidence level for the mean K{sub d} was twice the mean in the Aquifer Zone (18-30.5 m depth), equal to the mean for the Upper Vadose Zone (3.3-10 m depth), and half the mean for the Lower Vadose Zone (3.3-18 m depth). The distribution of K{sub d} values was log normal in the Upper Vadose Zone and Aquifer Zone, and normal in the Lower Vadose Zone. To our knowledge, this is the first report of natural radionuclide K{sub d} variability in the literature. Using ranges and distribution coefficients that are specific to the hydrostratigraphic unit improved model accuracy and reduced model uncertainty. Unfortunately, extension of these conclusions to other sites is likely not appropriate given that each site has its own sources of hydrogeological variability. …
Date: January 4, 2010
Creator: Kaplan, D.
System: The UNT Digital Library
HIGH ALUMINUM HLW (HIGH LEVEL WASTE ) GLASSES FOR HANFORDS WTP (WASTE TREATMENT PROJECT) (open access)

HIGH ALUMINUM HLW (HIGH LEVEL WASTE ) GLASSES FOR HANFORDS WTP (WASTE TREATMENT PROJECT)

This paper presents the results of glass formulation development and melter testing to identify high waste loading glasses to treat high-Al high level waste (HLW) at Hanford. Previous glass formulations developed for this HLW had high waste loadings but their processing rates were lower that desired. The present work was aimed at improving the glass processing rate while maintaining high waste loadings. Glass formulations were designed, prepared at crucible-scale and characterized to determine their properties relevant to processing and product quality. Glass formulations that met these requirements were screened for melt rates using small-scale tests. The small-scale melt rate screening included vertical gradient furnace (VGF) and direct feed consumption (DFC) melter tests. Based on the results of these tests, modified glass formulations were developed and selected for larger scale melter tests to determine their processing rate. Melter tests were conducted on the DuraMelter 100 (DMIOO) with a melt surface area of 0.11 m{sup 2} and the DuraMelter 1200 (DMI200) HLW Pilot Melter with a melt surface area of 1.2 m{sup 2}. The newly developed glass formulations had waste loadings as high as 50 wt%, with corresponding Al{sub 2}O{sub 3} concentration in the glass of 26.63 wt%. The new glass formulations …
Date: January 4, 2010
Creator: AA, KRUGER; BW, BOWAN; I, JOSEPH; H, GAN; WK, KOT; KS, MATLACK et al.
System: The UNT Digital Library
A step closer to visualizing the electron___phonon interplay (open access)

A step closer to visualizing the electron___phonon interplay

The origin of the very high superconducting transition temperature (Tc) in ceramic copper oxide superconductors is one of the greatest mysteries in modern physics. In the superconducting state, electrons form pairs (known as Cooper pairs) and condense into the superfluid state to conduct electric current with zero resistance. For conventional superconductors, it is well established that the 2 electrons in a Cooper pair are 'bonded' by lattice vibrations (phonons), whereas in high-Tc superconductors, the 'glue' for the Cooper pairs is still under intense discussion. Although the high transition temperature and the unconventional pairing symmetry (d-wave symmetry) have led many researchers to believe that the pairing mechanism results from electron-electron interaction, increasing evidence shows that electron-phonon coupling also significantly influences the low-energy electronic structures and hence may also play an important role in high-Tc superconductivity. In a recent issue of PNAS, Carbone et al. use ultrafast electron diffraction, a recently developed experimental technique, to attack this problem from a new angle, the dynamics of the electronic relaxation process involving phonons. Their results provide fresh evidence for the strong interplay between electronic and atomic degrees of freedom in high-Tc superconductivity. In general, ultrafast spectroscopy makes use of the pump-probe method to study …
Date: January 4, 2011
Creator: Chen, Y. L.; Lee, W. S.; Shen, Z. X. & /Stanford U., Appl. Phys. Dept. /Stanford U., Phys. Dept. /SLAC, PULSE
System: The UNT Digital Library
Plenary Session: Fluid Instabilities and Mixing in Extreme Conditions (open access)

Plenary Session: Fluid Instabilities and Mixing in Extreme Conditions

None
Date: January 4, 2011
Creator: Schilling, O
System: The UNT Digital Library
Recent Advances in the Mercury Monte Carlo Particle Transport Code (open access)

Recent Advances in the Mercury Monte Carlo Particle Transport Code

None
Date: January 4, 2013
Creator: Brantley, P S; Dawson, S A; McKinley, M S; O'Brien, M J; Stevens, D E; Beck, B R et al.
System: The UNT Digital Library
Construction of the Magnetic Phase Diagram of FeMn/Ni/Cu(001) Using Photoemission Electron Microscopy (open access)

Construction of the Magnetic Phase Diagram of FeMn/Ni/Cu(001) Using Photoemission Electron Microscopy

Single crystalline FeMn/Ni bilayer was epitaxially grown on Cu(001) substrate and investigated by photoemission electron microscopy (PEEM). The FeMn and Ni films were grown into two cross wedges to facilitate an independent control of the FeMn (0-20 ML) and Ni (0-20 ML) film thicknesses. The Ni magnetic phases were determined by Ni domain images as a function of the Ni thickness (d{sub Ni}) and the FeMn thickness (d{sub FeMn}). The result shows that as the Ni thickness increases, the Ni film undergoes a paramagnetic-to-ferromagnetic state transition at a critical thickness of d{sub FM} and an in-plane to out-of-plane spin reorientation transition at a thicker thickness d{sub SRT}. The phase diagram shows that both d{sub FM} and d{sub SRT} increase as the FeMn film establishes its antiferromagnetic order.
Date: January 4, 2011
Creator: Wu, J.; Scholl, A.; Arenholz, E.; Hwang, C. & Qiu, Z. Q.
System: The UNT Digital Library
high-temperature phonons in uranium from relativistic first-principles theory (open access)

high-temperature phonons in uranium from relativistic first-principles theory

None
Date: January 4, 2012
Creator: Soderlind, P; Grabowski, B; Yang, L; Landa, A; Bjorkman, T; Souvatzis, P et al.
System: The UNT Digital Library
Molecular cytogenetic characterization of a human thyroid cancercell line (open access)

Molecular cytogenetic characterization of a human thyroid cancercell line

The incidence of papillary thyroid carcinoma (PTC) increases significantly after exposure of the head and neck region to ionizing radiation, yet we know neither the steps involved in malignant transformation of thyroid epithelium nor the specific carcinogenic mode of action of radiation. Such increased tumor frequency became most evident in children after the 1986 nuclear accident in Chernobyl, Ukraine. In the twelve years following the accident, the average incidence of childhood PTCs (chPTC) increased over one hundred-fold compared to the rate of about 1 tumor incidence per 10{sup 6} children per year prior to 1986. To study the etiology of radiation-induced thyroid cancer, we formed an international consortium to investigate chromosomal changes and altered gene expression in cases of post-Chernobyl chPTC. Our approach is based on karyotyping of primary cultures established from chPTC specimens, establishment of cell lines and studies of genotype-phenotype relationships through high resolution chromosome analysis, DNA/cDNA micro-array studies, and mouse xenografts that test for tumorigenicity. Here, we report the application of fluorescence in situ hybridization (FISH)-based techniques for the molecular cytogenetic characterization of a highly tumorigenic chPTC cell line, S48TK, and its subclones. Using chromosome 9 rearrangements as an example, we describe a new approach termed ''BAC-FISH'' …
Date: January 4, 2006
Creator: Weier, Heinz-Ulrich G.; Tuton, Tiffany B.; Ito, Yuko; Chu, LisaW.; Lu, Chung-Mei; Baumgartner, Adolf et al.
System: The UNT Digital Library
Protonation of D-gluconate and its complexation with Np(V) inacidic to nearly neutral solutions (open access)

Protonation of D-gluconate and its complexation with Np(V) inacidic to nearly neutral solutions

None
Date: January 4, 2006
Creator: Zhang, Zhicheng; Clark, Sue B.; Tian, Guoxin; Zanonato,PierLuigi & Rao, Linfeng
System: The UNT Digital Library
Behavior of Uranium (VI) during HEDPA Leaching for Aluminum Dissolution in Tank Waste Sludges (open access)

Behavior of Uranium (VI) during HEDPA Leaching for Aluminum Dissolution in Tank Waste Sludges

Batch adsorption/dissolution experiments were conducted toexamine the interactions between 233U(VI) and a synthetic aluminumoxyhydroxide (boehmite, g-AlOOH) in 1.0M NaCl suspensions containing1-hydroxyethane-1,1-diphosphonic acid (HEDPA). In the pH range 4 to 9,complexation of Al(III) by HEDPA significantly enhanced dissolution ofboehmite. This phenomenon was especially pronounced in the neutral pHregion where the solubility of aluminum, in the absence of complexants,is limited by the formation of sparsely soluble aluminum hydroxides. Athigh pH levels, dissolution of synthetic boehmite was inhibited by HEDPA,likely due to sorption of Al(III)/HEDPA complexes. Addition of HEDPA toequilibrated U(VI)-synthetic boehmite suspensions yielded an increase inthe aqueous phase uranium concentration. The concentration of uraniumcontinually increased over 59 days. Partitioning of uranium between thesolid and aqueous phase was found to correlate well with HEDPApartitioning.
Date: January 4, 2006
Creator: Powell, Brian A.; Rao, Linfeng; Nash, Kenneth L. & Martin, Leigh
System: The UNT Digital Library
An in-situ cell for characterization of solids by soft X-rayabsorption (open access)

An in-situ cell for characterization of solids by soft X-rayabsorption

An in-situ cell using ''lab-on-a-chip'' technologies has been designed and tested for characterization of catalysts and environmental materials using soft X-ray absorption spectroscopy and spectromicroscopy at photon energies above 250 eV. The sample compartment is 1.0 mm in diameter with a gas path length of 0.8 mm to minimize X-ray absorption in the gas phase. The sample compartment can be heated to 533 K by an Al resistive heater and gas flows up to 5.0 cm{sup 3} min{sup -1} can be supplied to the sample compartment through microchannels. The performance of the cell was tested by acquiring Cu L{sub 3}-edge XANES data during the reduction and oxidation of a silica-supported Cu catalyst using the beam line 11.0.2 Scanning Transmission X-ray Microscope (STXM) at the Advanced Light Source of LBNL. Two-dimensional images of individual catalyst particles were recorded at photon energies between 926 eV and 937 eV, the energy range in which the Cu(II) and Cu(I) L{sub 3} absorption edges are observed. Oxidation state specific images of the catalyst clearly show the disappearance of Cu(II) species during the exposure of the oxidized sample to 4% CO in He while increasing the temperature from 308 K to 473 K. Reoxidation restores the …
Date: January 4, 2007
Creator: Drake, Ian J.; Liu, Teris C.N.; Gilles, Mary; Tyliszczak, Tolek; Kilcoyne, A.L. David; Shuh, David K. et al.
System: The UNT Digital Library