Contamination in groundwater at Canada, Kansas, was discovered in 1997, during limited private well sampling near former grain storage facilities of the Commodity Credit Corporation, U.S. Department of Agriculture (CCC/USDA). Subsequent investigations by the Kansas Department of Health and Environment (KDHE) confirmed carbon tetrachloride and nitrate concentrations in groundwater above the respective maximum contaminant levels (MCLs) of 5.0 {micro}g/L and 10.0 mg/L. The KDHE investigations identified both the former CCC/USDA grain storage facility and a private grain storage facility as likely sources for the carbon tetrachloride contamination. The CCC/USDA funded extension of a rural water district line to provide a permanent alternate water supply, and the KDHE has conducted long-term monitoring under the State Water Plan. This document presents an analysis of the available information for the Canada site, acquired in previous investigations and the long-term KDHE monitoring. This analysis forms the technical justification for a request to reclassify the former CCC/USDA grain storage facility at Canada as a site requiring no further action under the Intergovernmental Agreement (IGA) between the KDHE and the USDA's Farm Service Agency. The KDHE's long-term water level monitoring results indicate a consistent groundwater flow direction to the east-southeast. Consequently, the wells with the highest …

As part of a small scale sequestration test (about 1500 tonsof CO2) in a saline aquifer, time-lapse borehole seismic surveys wereconducted to aid in characterization of subsurface CO2 distribution andmaterial property changes induced by the injected CO2. A VSP surveydemonstrated a large increase (about 75 percent) in seismic reflectivitydue to CO2 injection and allowed estimation of the spatial extent of CO2induced changes. A crosswell survey imaged a large seismic velocitydecrease (up to 500 m/s) within the injection interval and provided ahigh resolution image of this velocity change which maps the subsurfacedistribution of CO2 between two wells. Numerical modeling of the seismicresponse uses the crosswell measurements to show that this small CO2volume causes a large response in the seismic reflectivity. This resultdemonstrates that seismic detection of small CO2 volumes in salineaquifers is feasible and realistic.

This report describes the main features of the results obtained in the course of this project. A new approach to the systematic development of closure relations for the averaged equations of disperse multiphase flow is outlined. The focus of the project is on spatially non-uniform systems and several aspects in which such systems differ from uniform ones are described. Then, the procedure used in deriving the closure relations is given and some explicit results shown. The report also contains a list of publications supported by this grant and a list of the persons involved in the work.