The following documents are progress reports that follow chemical research studies in subjects such as ruthenium tetroxile distillations, extraction-scrub studies of zirconium and niobium, and oxidation of plutonium and stabilization of plutonium(VI) during extraction of IAF solutions.

From statement of objectives: The purposes of the work described in this report are to provide data useful for designing and operating the dissolver solution clarification equipment to be installed in the Redox production plant.

From introduction: "In this report an attempt was made to summarize the results of recent research on the effective height of smoke stacks. In this summary attention is paid only to the case in which the density of the stack effluent is the same as that of the surrounding air."

The following report discusses laboratory investigations of the suitability of some commercially available limestone for neutralization of slightly acidic distillates.

From introduction: This report summarizes a study of the composution and physical properties of a number of hydrocarbon diluents together with some generalizations regarding relations between [vapor pressure, density and viscosity] properties.

The following report observes infrared measurements in the region of OH bands, the C2O band vicinity, the low frequency end of the spectrum, and the region of the UO2 band on the system hexone - water - uranyl nitrate.

Introduction: "The adoption of aluminum nitrate as salting agent in the Redox process made it imperative that a method be available for determining plutonium in the presence of aluminum. However, large amounts of aluminum have been found to interfere with the determination of plutonium by the lanthanum fluoride procedure. Previous attempts to increase the accuracy of the lanthanum fluoride method, by precipitating LaF3 from 4 M HF (rather than 2 M), have been successful only when the initial plutonium level was high."

This report covers an investigation made to develop a gasometric determination that can determine 1.2 x 10-(-5) g. of nitrite with a precision (99% limits) of +/- 8%, and discusses how this procedure works.

Introduction: "The need for a method of acid determination which could be used for small samples and easily adapted to remote control led to the investigation of the use of electrolytically generated base for the titration of acid in certain solutions. The use of electrolytically generated base for the titration of acetic acid in the presence of nitric acid has been reported (1)."

Objective: "The observations summarized in the present report were made to determine the stability of ferrous and sulfamate ions and sulfamic acid in RA Column scrub solution (RAS) and in aqueous solution comparable to the RA Column feed tee composition (RAFS). Knowledge of the stability of the reducing agent (ferrous iron) is necessary to properly plan the method of preparation and introduction of this component into the RA system and to assure dependable and reproducible performance."

Objective: The objective of this study is to develop a simple method of either removing the C1- ion from the RAW or converting the ion into a less corrosive valence state.

The reports aims to determine the solubility limitation of concentrations of uranium in the food preparation step of the tributyl phosphate waste metal recovery process, and the subsequent solubilities in the RA column.

Abstract: This report gives the results of a radiochemical analysis of particles collected by electrostatic precipitation from ventilation air of the "B" plant at Hanford Works.

The following report analyzes the nitrogen mustard found in mustard gas.

Introduction: "Evidence of masonite deterioration in test hole plugs was interpreted to mean that a previous estimate of the minimum lifetime of the masonite in a Hanford biological shield might be somewhat optimistic. The importance of understanding the effects of radiations on masonite for both present and future pile shields dictated that masonite be sampled from an operating pile shield and studied. The results and techniques are discussed in the following sections of this report."

The following report examines a rapid method used to eliminate the possibility of explosive perchlorate-organic mixtures in a control laboratory in order to determine radiocesium. These methods include the usage of chloroplatinic acid as a precipitate of radocesium.

A report which intends to acquaint the reader with the planning of the radiochemical laboratory designed for the analytical control of the radiolanthanum process and to define the terminal status of the design of this laboratory and its equipment.

Summary: "This investigation showed that a sound , weather-resistant coating can be applied to uranium that the surface to be plated is cleaned and etched properly. Using the proposed two-bath plating method at 80 C., a four-mil nickel coat can be deposited in thirteen hours."

A report which discusses the data submitted for evaluation. This data is about optical densities from infrared spectrometer readings on eight standard samples, ranging in percent TBP from 6.71 to 17.85.

This report provides data on production test 105-329-P and solid graphite samples used to analyze damage obtained from controlled natural erosion tests. The data provided will help establish current ideas on the status of filler block graphite and interpretation of the data will assist in establishing pile operating temperature limits based on stored energy.

Summary: "Six different types of solutions of various concentrations were used to deoxidize uranium chips on a laboratory scale. None of the solutions tested appears to be more desirable than 50% nitric acid for deoxidizing uranium chip on a production scale."

Introduction:"A corrosion test program in support of the Redox Project was carried out during the second quarter of 1950 to determine the corrosion rates of several austenitic stainless steels in simulated 202-B Waste Storage solution containing HF, HN03, and H2SO4 acids. The results of this program are contained herein and all original data are recorded in laboratory notebook HW-3282-T."

The following report provides the results of laboratory corrosion tests held to investigate the behavior of austenitic stainless steel, Type 347, in selected O.R.N.L. #1 Redox streams.

Introduction: "A laboratory investigation of the relative corrosion resistance of several austenitic stainless steels to the RAW stream of the Tributyl Phosphate Waste Metal Recovery Process was made during the first quarter of 1950. The results of this investigation are reported herein; all original data are recorded in laboratory notebook HW-3282-T."