Calcination of liquid radioactive wastes, the process of converting metal nitrates and sulfates to oxides by heat, is under development at Hanford as a means of reducing these liquids to a dry powder or solid which can be stored safely. Radiant-heat spray calcination, one of the methods under study, was first investigated at the Oak Ridge K-25 Plant (1) as a possible method of calcining uranyl nitrate to uranium trioxide. The process has also been under extensive development at the Pulp and Paper Research Institute of Canada (2) and is designated by them as the Atomized Suspension Technique.

aluminum has been considered as a material for cladding fuel elements to be used in reactors cooled by high-temperature recirculating water. Aluminum is abundant, chap, has a relatively low cross section for thermal neutrons, and is readily fabricated into complex shapes. For these reasons, it appears that the use of aluminum rather than steel, Zircaloy or other candidate materials for fuel element cladding, would result in considerable savings in operating expense. The actual economics will of course depend on specific factors such as core materials and design of the reactor/. Aluminum appears particularly attractive for cladding the cores of aluminum-plutonium alloy proposed for the Plutonium Recycle Test Reactor since, in this case, the physical characteristics of the core and cladding would be practically identical.

This document presents the bases for those PRTR Process Specifications involving considerations of heat transfer and fluid flow. It will be noted that some of the bases incorporate information gained from laboratory experiments with electrically heated test sections simulating PRTR fuel elements. These experiments are described in some detail elsewhere.

A previous study has been completed on the buildup and decay of xenon poisoning in the PRTR by simulating the reactor as a single region. The results of this study indicated that a study using a more refined model of the reactor would be valuable.

A correlation between the optical densities if the Pb-Sn alloy system and UO2 with respect to Co^60 gamma radiation has been determined. This enables one to fabricate density standards of whatever geometry may be desired for one in the gamma absorptiometer by simply casting a Pb-Sn alloy of the proper composition to correspond to the density required.

Objective: "The observations summarized in the present report were made to determine the stability of ferrous and sulfamate ions and sulfamic acid in RA Column scrub solution (RAS) and in aqueous solution comparable to the RA Column feed tee composition (RAFS). Knowledge of the stability of the reducing agent (ferrous iron) is necessary to properly plan the method of preparation and introduction of this component into the RA system and to assure dependable and reproducible performance."

The primary purpose of a cleanup system in a recirculating water loop is to maintain the best possible water quality conditions. This is normally accomplished by continuously purifying all or a portion of the coolant. A secondary objective of the cleanup system is to help maintain the system pH at a constant value. A system that will satisfactorily accomplish both of these objectives is at times difficult to obtain. Generally the pH control characteristics are sacrificed in favor of the more important cleanup requirements. A somewhat new approach to the problem pf cleanup system design appears to offer a solution to this problem for high pH systems.

Facilities shall be provided in the 221-U Building for storing the metal solution product of the dissolution step in existing tankage from U, T, and B Plants until a reprocessing campaign is scheduled through Redox. This section shall provide a sampling tank for fuel accountability sampling and a pump tank from which the solution will be pumped via a cross-country pipeline to Redox for further processing.

At the request of 234-5 Development, studies of a system for controlling plutonium powder transfer were undertaken by Process Equipment Development. This report presents details of equipment designed to fulfill requirements and proposes equipment for installation on additional Hot Button Line prototypes.

A series of tests conducted in an attempt to reduce the observed O2 content of primary recirculation loop water to a value of <0.14ppm by the current loop method which is a combination of pressurizer degasification and venting flow.

The ambient temperature of the Columbia River is of interest to the Aquatic Biology Operation since it provides a basis for controlling the temperatures in various experimental tanks which contain Columbia River organisms and since it provides some indication of whether conditions are favorable for the valuable species of fish living in the river. Since the start-up of the plant, temperatures of the river water have been taken in the several water treatment plants.

Basic Studies. It has been reported previously that mixed crystals of PuO2 and UO2 have a higher sintering rate than UO2 alone. However, results to the contrary were obtained on addition to 1/4, 1/2, 1, 2, 5, and 10 w/o PuO2 to PWR grade UO2. Pellets of the above concentrations were heated for one hour in hydrogen at 100 C intervals from 1000 to 1600C.

In the past several years the use of neutron monitors for Pu concentration monitoring has been expanded in the Chemical Processing Department. Most of these monitors have been quite successful, and considerable effort is being made to improve the operation of both existing and future monitoring systems. One of the major improvements has been the development and use of a transistorized pre-amplifier or impedance matching circuits. This unit solves several problems associated with the use of boron trifluoride (BF3) neutron detectors in process monitoring; e.g., vacuum tube pre-amp failure because heat is not being conducted away.

Introduction: "A laboratory investigation of the relative corrosion resistance of several austenitic stainless steels to the RAW stream of the Tributyl Phosphate Waste Metal Recovery Process was made during the first quarter of 1950. The results of this investigation are reported herein; all original data are recorded in laboratory notebook HW-3282-T."

Introduction: Static, total immersion corrosion tests were carried out at room temperatures with Carboloy grades 44-A, 78, 907, X-3119-A and X-3119-B in Redox process solutions (ANL, June 1, 1949 Flowsheet) 1AX, 1AF, and 1AS.

In October 1959, a combination testing station developed at HAPO was reported to the Sheath committee. This testing station consisted of electronic instrumentation and mechanical scanning equipment to check coextruded fuel elements (rod and tube) for clad thickness, clad integrity, bond, and core integrity. The clad tests are performed by eddy current methods and the other are ultrasonic.

The build up of contaminated film on the internal surfaces of high temperature in-reactor recirculating water loops has created serious radiation exposure problems to operational and maintenance personnel. A considerable amount of work has been applied to develop an effective decontamination process for the decontamination of these loops and their components.

Startup and testing of the PRTR has been divided into three parts, Design Tests, Critical Tests and Power Tests. This document is the third of the series and describes the performance tests which will be made under nuclear power and the general schedule of operation. Responsibility for the startup of the reactor has been assigned to the PRTR Startup Council. The Power Test Sub-Council, which has done the planning of the initial power operation, was established by the Startup Council. Operation of the reactor will be the responsibility of the PRTR Operation (PRTRO).

The majority of two-phase flow problems involving equations of state are solved by use of point-wise utilization steam table values. In this manner, problems involving the use of the various flow equations of continuity, momentum and energy are generally forced into iterative solutions. Considerable effort towards the development of an analytical expression for the state equation seems indicated so as to simplify the analysis of two-phase problems, particularly the transient cases. The question of instability of state and mixture condition is particularly apparent in the analysis of systems undergoing phase transformation as demonstrated by the significant difference between simple theory and experimental critical flow determinations. The assumption of homogeneous, equilibrium mixtures is indicated as a first attack upon the problem.

Summary: "Criticality was considered impossible in any contingency encountered in practice under either of the following conditions which include no safety factor: (a) In any isolated cylinder not more than 5 in. in disruptor, if the total amount of U235 present does not exceed 7.5 Eg. (b) In an isolated vessel of any shape and size, if the total amount of U235 present does not exceed 880 g. An "isolated" vessel is one which does not "see" more than 0.1 [...] other vessels containing fissionable material."

Limitations on the service life of a fuel element imposed by degradation of the fissile core during irradiation have been a matter of great concern. Limitations imposed by changes in cladding properties during irradiation should be evaluated with equal care. Zircaloy-2, stainless steel, and aluminum alloys have been irradiated in the form of cladding on metallic and ceramic fuel elements. Several aspects of fuel behavior as influenced by these clad materials will be discussed. All observations related to irradiation behavior in this paper have been made on fuel specimens irradiated in water coolant.

The following report examines methods to determine uranium nitrate hexahydrate on pretreated hexone in the range of 0 to 40 g./l. by infrared absorption measurements.

Abstract: "The critical mass both of an untamped and water-tamped sphere with parabolic radial variation of the intrinsic buckling is calculated by a perturbation method. The result is applied to finding the minimum critical mass of plutonium in water suspension with infinite water temper; the calculations show that the minimum critical mass at constant concentration may be reduced by an amount of the order of 7.6% when the concentration of plutonium is permitted to vary throughout the suspension."

Crib evaluation studies showed the soil uptake of plutonium from the Recuplex process (CAW) waste to be low. Preliminary studies of the low soil adsorption of plutonium revealed the presence of a plutonium nitrate anion complex which could be removed by adsorption on a strong base anion exchange resin.