Color copies of photomicrograph figures that accompany a report studying uranium in granites in the southwestern United States.

The 1,1-reductive elimination of ethane from three cis-bis(phosphine)-dimethylpalladium complexes, L/sub 2/Pd(CH/sub 3/)/sub 2/ (L = PPh/sub 3/, PPh/sub 2/,CH/sub 3/ and L/sub 2/ = Ph/sub 2/PCH/sub 2/CH/sub 2/PPh/sub 2/), and three trans analogs (L = PPh/sub 3/, PPh/sub 2/CH/sub 3/ and L/sub 2/ = 2,11-bis(diphenylphosphinomethyl)benzo(c)phenanthrene (TRANSPHOS)) was carried out. The three cis complexes underwent reductive elimination in the presence of coordinating solvents (DMSO, DMF, and THF). The trans complexes which could isomerize to cis (L = PPh/sub 3/, PPh/sub 2/CH/sub 3/) did so in polar solvents and then underwent reductive elimination. TRANSPHOS dimethylpalladium would not undergo reductive elimination of ethane. The eliminations from the cis isomers were intramolecular and displayed first order kinetics. Although TRANSPHOS dimethylpalladium(II) would not undergo a 1,1-reductive elimination of ethane, the addition of CD/sub 3/I to a DMSO solution of this complex at 25/sup 0/C rapidly produced CD/sub 3/-CH/sub 3/, implicating a transient palladium(IV) intermediate. E- and Z-bromostyrylbis(diphenylmethylphosphine)palladium(0) react with methyl lithium in THF at ambient temperature to give the E- and Z- propenylbenzenes, respectively. At -78/sup 0/C, the intermediate E- and Z-styrylmethylbis(diphenylmethylphosphine)palladium(II) complexes (9a,b) can be isolated. On raising the temperature of solutions of 9a,b in THF, E- and Z-propenylbenzenes are produced. The reductive elimination …

Efforts have been primarily directed toward evaluation of the room temperature molten salt electrolyte in terms of its overall performance for photovoltaic cells. Mass transport processes may prove to be the rate-limiting factor for such electrolytes, unless the concentration of the photo-active redox component can be increased and the solvent viscosity reduced. Acid-base surface chemistry of n-GaAs as occurs in aqueous systems, has been found present and its consequences will be further explored. The selection and optimization of PEC electrolytes is a complex task and we believe that a systems approach would facilitate in identifying the basic electrolyte properties needed. A preliminary analysis reveals that although some of the criteria for an electrolyte are definable precisely, others do require empirical experimentation. It can be concluded that relatively few electrolytes in current use are adequate and it would appear that greater efforts to develop electrolytes would be advantageous. The various types of electrolytes that could be used for PEC's have been identified. Good quality MoSe/sub 2/ single crystals can be grown and short circuit currents greater than previously reported have been achieved in an I/sub 2//I/sup -//Pt cell. A novel technique to produce photo-active films by anodization is being investigated, initially …

"This report consists of engineering details, statistics, individual borehole histories, and logistics for the 27 boreholes drilled in the project. Geophysical logs are included." (from Introduction)

"This report consists of engineering details, statistics, and logistics of the 19 boreholes drilled in the project. Geophysical logs are included on microfiche in the back of this report." (from Introduction)

This report is an issue of the original draft copy of the "Interim Staff Report on Uranium Exploration on the Colorado Plateau", dated June 1951. The original draft copy was only recently located and is being published at this time because of the interest in the contained historical content.

From purpose of study: The Vallecito Conglomerate of the Needle Mountains area in southwestern Colorado was studied to evaluate the uranium potential of the unit and to test the applicability of the uraniferous Precambrian pebble-conglomerate exploration model in this area. The main thrust of this project is the Vallecito Conglomerate, but the Uncompahgre Formation, which is also in the Needle Mountains area has basal conglomerate that was investigated in a reconnaissance mode. Five specific objectives have been formulated to meet the overall purpose of this project, and these include: a) Determine the uranium distribution in the Vallecito Conglomerate and the basal conglomerate of the Uncompahgre Formation. b) Evaluate the uranium resources of the area to the degree possible utilizing available information and personal field investigations. c) Test the validity of application of the Precambrian quartz-pebble conglomerate model to this area. d) Recommend detailed studies and delineate drilling sites in the area to further evaluate the uranium resources if warranted. e) Recommend additional geologic, geophysical and geochemical studies which would bear directly on evaluation of uranium resources of the Precambrian pebble conglomerates in the Needle Mountains area.

From introduction: This study is part of the United States Department of Energy's National Uranium Resource Evaluation Program to understand the geologic setting, amount, and availability of uranium resources within the boundaries of the United States.

Multivariate statistical analysis to support the National Uranium Resource Evaluation and to evaluate strategic and other commercially important mineral resources

Characteristics of the oceanic mixed layer over the North Pacific were examined utilizing a number of statistical methods. Based on the analyses of twelve years of data, a quasi-meridional differentiation (QMD) in sea surface temperature (SST) spectra across the North Pacific was observed. The SST spectra became increasingly red as an increasing function of latitude. A strong 21 to 26 day cycle in SST anomalies is discussed which may be a reflection of heat fluxes. These fluxes also vacillate significantly on this time-scale in conjunction with cycles observed in the atmospheric energy modes of available potential and kinetic energy. Examination of an oceanic heat budget on a spatial and temporal basis suggest that the impact of latent and sensible heat fluxes upon ..delta..SST is partially a function of the magnitude of the heat fluxes as well as of the depth to which their effects are mixed. The heat budget analyses and the fitting of power spectra of SST anomalies over the North Pacific to a two-parameter oceanic model, suggest that SST behavior over the mid-oceanic regions of the North Pacific is dominated by the influence of latent and sensible heat fluxes. On the other hand, over the remainder of the …

Work carried out at the Nuclear Physics Laboratory of the University of Colorado from November 1, 1979 through October 31, 1980 is summarized. Emphasis was on light ion reaction studies with the AVF cyclotron. The high resolution magnetic spectrometer has allowed studies of nucleon transfer, scattering, and charge exchange reactions throughout the periodic table. More experiments have been run with solid state counters this year than has been the case recently, as a broad range spectra of the light nuclei where only moderate resolution is demanded were examined. Several of these experiments were undertaken for more detailed studies of excitations seen with higher energy probes. Multiple coincidence measurements with neutron and gamma-ray counters have opened a new program in pre-equilibrium reactions and provided a new signature for the study of neutron-deficient final nuclei. The neutron time of flight program has expanded to higher excitation and to use of the (d,n) and (..cap alpha..,n) direct nucleon transfer reactions. Three important experiments were completed at the EPICS pion scattering facility at LAMPF, and other low energy pion scattering data were obtained at TRIUMF. Several (p,d) runs at high energies were accomplished, some with polarized beams at TRIUMF. High-lying structures in medium mass …

Report documenting the results of chemical analysis for 422 water and 1552 sediment samples in the Vernal quadrangle, Utah/Colorado. It includes an overview of the area, methods, data analysis, and evaluation.

From introduction: "The U.S. Geological Survey began a 5-year study of the High Plains regional aquifer during the 1978 to provide the hydrologic information needed for the development of computer models to evaluate the aquifer's response to ground-water management alternatives." It contains maps, graphs, and tables.

From introduction: This report relates to the first of the above objectives by describing stream quality in the Yampa River basin through 1976, with particular emphasis on conditions from August 1975 through September 1976. The content of this report is, at times, relatively technical. This is intentional. The report is aimed not at planners and decision makers but rather at those persons assigned the task of having to design, implement, and interpret a river basin assessment. The techniques and procedures used to determine ambient stream quality in the Yampa River basin have been presented in detail so that their applicability to other river basins can be determined. For the planner and decision maker, the results presented in this report are summarized in less technical terms in phase-l (Steele and others, 1979) and phase-ll summary reports.

This report describes the study made to define areas showing surface indications of a generally higher uranium content where detailed exploration for uranium would most likely be successful in the Trinidad quadrangle.

Second volume of data from a radiometric and magnetic reconnaissance survey of the Trinidad quadrangle in Colorado, including "Results of the interpretation in the form of a preferred anomaly map, along with significance-factor profile maps stacked profiles, histograms, and descriptions of the geology and known uranium occurrences" (vol. 1, p. 1).

Abstract: Multivariate statistical analyses were carried out on Hydrogeochemical and Stream Sediment Reconnaissance data from the Craig quadrangle, Colorado, to support the National Uranium Resource Evaluation and to evaluate strategic or other important commercial mineral resources. A few areas for favorable uranium mineralization are suggested for parts of the Wyoming Basin, Park Range, and Gore Range. Six potential source rocks for uranium are postulated based on factor score mapping. Vanadium in stream sediments is suggested as a pathfinder for carnotite-type mineralization. A probable northwest trend of lead-zinc-copper mineralization associated with Tertiary intrusions is suggested. A few locations are mapped where copper is associated with cobalt. Concentrations of placer sands containing rare earth elements, probably of commercial value, are indicated for parts of the Sand Wash Basin.

Report describing chemical analysis of 62 water and 620 sediment samples during a follow-up geochemical survey to search for uranium in the Pueblo quadrangle.

From introduction: The purpose of the investigation was to identify and describe the hydrologic units and to evaluate the availability and chemical quality of groundwater in the 1,100 square mile study area.

From abstract: This report provides "a hydrologic analysis of the proposed Badger-Beaver Creeks artificial-recharge project . . . made with the aid of three digital computer models." It includes maps, graphs, and tables.

From abstract: This report studies a group of wetlands in the Cottonwood Lake area in Stutsman County to explore "the role of lakes and wetlands in the hydrology of the prairie environment." It contains maps, graphs, and tables.

This report describes "a method for estimating flow characteristics of flood hydrographs between Portland, Colorado, and John Martin Reservoir." It contains maps, graphs, and tables.

A computer analysis of NURE-HSSR data.

Drilling logs recorded for various holes as part of the Sand Wash Basin Intermediate Grade Project.