Resistance of carbon steel to corrosion in oxygenated high-temperature (250C) water was unexpectedly good at high oxygen concentration. Pertinent literature, critically examined, and toroid experiments indicted that at low oxygen concentration attack did increase with concentration, but as oxygen concentration was sufficiently increased, more protective films were formed on the metal. Some corrosion factors in the application of carbon steel to nuclear reactors systems are discussed.

After several failures had occurred in the HRT leak detector system, several lengths of this tubing were removed for metallurgical examination. The tubing was of type 304 stainless steel and was 1/4" in diameter with a 0.065 wall. The tubing had been purchased as three different lots, the first in 45 ft. lengths and the other two as standards lengths. Tubing from the first lot was used primarily for the shield penetration and, therefore, sections of it are present in all lines of the system. It appears that chloride contamination entered the system in a portion of the first lot of tubing used for the shield penetration. The exact source of the chloride cannot be determined, but after considering the results and visiting the manufacturer's plant, it appears most likely the contamination was during the manufacturing process.

A second test of the mockup of the Zircaloy - stainless steel transition joint as used in the HRT reactor vessel has been completed. The joint and bellows have now received 104 thermal cycles and 148 mechanical deflections. The joint and bellows have functioned properly; corrosion damage has been negligible, except for a small area on the bellows which has undergone pitting attack. Long-term runs with uranyl sulfate solutions of the concentration proposed or use in the HRT have shown the solution to be stable at 300 C. Substituting heavy water for normal water caused no difference in either corrosion or solution stability. Experiments in which chromic acid was used to pretreat stainless steel have shown that, under certain conditions, the pretreated film can exist in uranyl sulfate solutions at flow rates in excess of the critical velocity for relatively long periods of time. The practicability of using titanium inserts in high turbulent areas of stainless steel loops to minimize corrosion has been demonstrated. The corrosiveness of beryllium sulfate solutions containing dissolved uranium trioxide has been determined at 250 and 280 C. Laboratory studies with regard to stress-corrosion cracking have shown that high stressed type 347 stainless steel will crack …

Chloride-induced stress-corrosion cracking has been encountered in the Homogeneous Reactor Test during the preliminary testing. The rector is constructed of austenitic stainless steels. It is unique in that it will operate at 250 to 300 C with an aqueous uranyl sulfate solution fuel containing 200 to 500 ppm of dissolved oxygen. The cracking has occurred in a secondary system used for detecting leaks in the flanged joints of the primary systems and in the grooves of flanges in the primary systems. Tubing used in the leak-detection system was found to be contaminated with chloride introduced during manufacture.

Abstract: Experimentally measured promp-neutron decay constants for sub-critical systems are of considerable value as normalization data for calculations of prompt-neutron time constants. A method of measuring these decay constants with a pulsed neutron source, neutron detector and multi-channel time-delay analyzer has been developed and used on a number of fast-spectrum subcritical systems. An analysis of this method based on the one-energy group, one-delayed-neutron group reactor kinetic equations is presented and discussed. The curve of neutron flux versus time predicted by the kinetic equations is compared with the observed curve obtained with a 13.1-cm. diam. enriched-uranium sphere to indicate the application and limitations of the analysis.

This report describes the design, construction, and application of an electrical analogue for solution of the steady state problem. Teledeltos paper (an electrically conductive paper) was used to construct this analogue, and although this and other sheet materials has been used for heat transfer analogues in several previous investigations, it is believed that the present work is unique in the application of Teledeltos paper to three dimensional problems of radial symmetry.

Reconnaissance made of the Red Canyon area with the objective to locate areas favorable to the occurrence of uranium deposits, study the environment of the deposits, and to collect data for regional studies.

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Will Wilson, regarding a legal question submitted for clarification: Whether the Board of Insurance Commissioners may authorize the use of the "Homeowners Policy" in the State of Texas by following the procedures used in authorizing the sale of the "Comprehensive Dwelling Policy."

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Will Wilson, regarding a legal question submitted for clarification: Effect of the Ford Motor Company - UAW-CIO supplemental unemployment benefit plan upon the Texas Unemployment Compensation Act.

Catalysts for use in recombining the gases produced by the radiolytic decomposition of water in thorium oxide slurries under neutron irradiation were investigated in out-of-pile tests using stoichiometric mixtures of hydrogen and oxygen. Most favorable results were obtained with a molybdenum oxide catalyst. Satisfactory rate also were attained with palladium and silver oxides. Copper, nickel, vanadium and chromium compounds were less effective.

A promising scheme for the chemical processing of a thorium breeder reactor of the two-region aqueous homogeneous type consists of the following operations: concentration of insoluble fission and corrosion products from the core system into a small volume of fuel solution, combining this slurry with irradiated thorium oxide slurry taken from the blanket, recovery of D2O by evaporation, dissolution of the thorium and uranium in HNO3, and, after a suitable cooling period, recovery of the uranium and thorium by solvent extraction for return to the reactor. The use of a hydroclone and underflow container arrangement for concentrating insoluble fission and corrosion products under simulated reactor conditions has been successfully demonstrated on dynamic loops. Solids concentration factors greater than 103 were demonstrated, and equilibrium solids concentration in the circulating solution less than 1 ppm was attained in these tests. Present data indicate that proper design and operation will minimize solids deposition in the reactor system and that the insoluble impurities can be effectively removed by the hydroclone. An alternate method of processing the slurry removed from the core system by the hydroclone consists of removing the room temperature insolubles by centrifugation, recovering the uranium from the supernatant by peroxide precipitation, thermal …

When it was discovered that two HRT flange bolts of a lot of 16 spares contained serious cracks, a program was launched to (1) determine the cause for the cracking, and (2) find methods for non-destructive testing the remainder of the 672 bolts shipment, a large portion of which had been installed in the HRT. Concurrently, inspection of 8 ferrules removed from an HRT flange revealed hairline cracking in 4 of them. Magnaglo, a magnetic particle inspection method using a fluorescent dye, proved to be the only definitive method for inspecting the bolts. The evidence gathered on the bolts pointed to quench cracking as the cause for the defects. Nothing abnormal was disclosed in regard to the bolt material. The alloy and heat treatment at present prescribed for the HRT bolts and ferrules are considered suitable. However, recommendations are made for plating with zinc, instead of formerly prescribed cadmium, to a thickness of 0.0002 inch, followed by a hydrogen relief treatment and a final bichromate chemical dip.

The feasibility of determining particle sizes in the submicron range by employing an activation analysis - centrifugation method has been demonstrated. It is believed that this method is now applicable to the analysis of thorium oxide for submicron particles. The same techniques are, in most instance, usable in determining particle sized in other sample materials.

An inconel loop circulating fluoride fuel (62 1/2 make [unintelligible] NaF, 12 1/2 make [unintelligible] ZrF4, 25 make [unintelligible] UF4, 92 [unintelligible] enriched) was operated at 1485°F with a temperature difference of about 35°F in the Low Intensity Test Reactor for 645 hr. For 475 hr of this time the reactor was at full power, and fission power generation in the loop was 2.7 kw, with a max length power density of 0.4 kw/cc. The total volume of fuel was 1290 cc (5.o kg [unintelligible] and the the flow through the irradiated section was 8.6 fps (Reynolds number 5500). The loop has been disassembled and has been examined by chemical and metallographic analyses. Ne acceleration of corrosion of decomposition of fuel by irradiation was noted, although deposition of fission-product ruthenium was absorbed. Ne mass transfer of Inconel was formed, and the corrosive [unintelligible] was general and relatively light. The average corrosive generation, in the usual form of subsurface yields, was 0.5 [unintelligible], the maximum penetration was 2 to 3 miles.

Thorium and thorium-uranium oxide slurries were irradiation in the Low Intensity Test Reactor (LITR) at temperatures up to 300C in small stirred autoclaves. Stirring was accomplished by means of an electromagnetically operated lunger. Stirrer operations was monitored suing an oscilloscope. Relative slurry viscosities were determined both in and out-of-pile using calibration curves of apparent viscosity versus stirrer rise time. Post-irradiation examination of selected slurries indicated no gross changes occurred in the particulate properties.

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Will Wilson, regarding a legal question submitted for clarification: Are the provisions of Article 7880-23, V.C.S., in conflict with the provisions of Article VI, Sections 2 or 3(a) of the Constitution of Texas, in prescribing the qualifications of voters at a confirmation election?

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Will Wilson, regarding a legal question submitted for clarification: Classification for inheritance tax purposes of a deceased daughter's former husband who had remarried and had been divorced prior to decedent's death.

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Will Wilson, regarding a legal question submitted for clarification: Whether the authorization of the Texas Commission on Higher Education is required for the Agricultural and Mechanical College of Texas to establish and operate, in Arlington, a graduate engineering division of the A.&M. College, using the facilities of Arlington State College.

A promising nonaqueous process for the recovery of uranium from spent fuel elements is under development at Oak Ridge National Laboratory. This process consists of dissolution of the fuel element in a fluoride melt by hydrofluorination at 600 to 700°C, direct fluorination with fluorine for the production and volatilization of UF6, with further decontamination of the product UF6 from fission product activity being secured in a NaF absorption-desorption step. Good decontamination is obtained in the fluorination step due to the low volatility of most of the fission product fluorides. An over-all decontamination factor greater than 106 with adequate uranium recovery has been demonstrated in laboratory scale tests using a double bed procedure for the NaF step. A pilot plant has been constructed for testing the process with various heterogeneous fuel elements. The engineering and operational features of the pilot plant are described

The heat transfer and fluid friction characteristics have been determined for a liquid flowing parallel to the tube bundle of a heat exchanger consisting of one hundred and two 1/16-inch O.D. tubes arranged in a delta or triangular array. These results may be expressed by empirical equations.

A system for concentrating uranyl nitrate solutions was designed and installed in the Thorex Pilot Plant. A total of 16,060 g of uranium was concentrated in the system in 68 batch runs. A total of 14,400 g total uranium (14.180 g U/sup 233/) was recovered as product suitable for shipment. Uranium loss to the evaporator condensate was 0.03% of the total uranium processed. The material balance across the system was 98.4%. The average concentration of uranium in the evaporator feed solution was 29 g/liter; the average concentration in the evaporated solution was 298 g U/liter and in the product solution was 199 g/liter. Radiation readings of bottles containing product solutions were taken with a hard-shell cutie pie immediately after each run, and these readings ranged from 35 to 1100 mr/hr. The radiation levels of the bottles of product solution shipped averaged 78 mr/hr. Bottles of product solution reading in excess of 300 mr/hr, maximum allowable for shipment. were reprocessed in the second-cycle solvent extraction system (Thorex) and reconcentrated. The products from seven runs had radiation levels in excess of 300 mr/hr at the time of concentration, or the activities had grown to that level by the time of shipment. The …

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Will Wilson, regarding a legal question submitted for clarification: Liability of a volunteer fire department for payment of sales tax on motor vehicle to be used as a fire truck.

The General Electric Company is designing and building a 180,000 kilowatt nuclear power plant for the Commonwealth Edison Company at a site near the confluence of the Kankakee and Des Plaines Rivers in Grundy County, Illinois, about 47 miles southwest of Chicago. The plant will be known as the Dresden Nuclear Power Station, and will employ a nuclear reactor of the dual-cycle boiling water type.

An estimate has been made of the gamma radiation levels at access holes in the HRT Shielding when the plugs have been removed to service or maintain the reactor. In every case the radiation level at the holes was greater than the maximum permissible exposure rate of 0.3 roentgens per week. The radiation through the holes can be attenuated to some extent by flooding the reactor cell up to the flange to be disconnected. However, shielding would still be required and it is more practical to provide a small additional shield thickness to compensate for the moderate attenuation that could be gained from flooding.