This article, as an alternative route to empirical models, shows that a structural descriptor based on the number of topological constraints per atom can be used to predict the initial dissolution rate of aluminosilicate and borosilicate glasses after being parameterized on different families of glasses (specific series of borosilicate glasses). Results show that, provided that corrections are made for high alkali content glasses that dissolve incongruently (preferential release of Na), the model gives reasonable predictions, even far from its training domain.

This article assembles large, pediatric-sized stents (Ø10 - Ø20 mm) from poly(L-lactide) fibers (DH-BDS) at two thicknesses, 250 µm and 300 µm. DH-BDS exhibiting hoop strength similar to metal stents and demonstrating minimal degradation and strength loss over the first year before completely disappearing within 3 to 4.5 years show promise as a pediatric interventional alternative to current strategies.

This article is a review that categorizes the compositional and microstructural approaches that exhibit potential for a combination of shear induced phase transformation and twinning, thereby expanding beyond the slip based mechanisms.

This article applies cryo-based atom probe tomography to directly reveal the water-solid interface and hydrated corrosion layers making up the nanoscale porous structure of a corroded borosilicate glass in its native aqueous environment. The analysis includes morphology and compositional mapping of the inner gel/glass interface, isolation of a tomographic sub-volume of the tortuous water-filled gel, and comparison of the gel structure with simulations.

Data management plan for the grant, "CAREER: Manufacturing of Mechanically Stable Nanoporous Ceramic Structures Via Selective Infiltration of Polymer Templates." This Faculty Early Career Development (CAREER) grant from the National Science Foundation supports fundamental research to elucidate a new strategy of manufacturing nanoporous ceramic structures with controllable structure and composition and programmable mechanical stability. The specific goal of this research is to discover processing-structure-property relationships in ceramic coatings and heterostructures by providing fundamental insights on the mechanism of liquid phase swelling-based infiltration of spin-coated polymer templates with inorganic precursors and defining the rules that control the resulting structure and, thus, access to various materials surfaces and interfaces.

Data management plan for the grant, "CAREER: Liquid Crystal-Templated Sequential Infiltration Synthesis of Hybrid Organic/Inorganic Materials with Multidimensional Chiral Structures"