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The Crucial Role of Solvation Forces in the Steric Stabilization of Nanoplatelets (open access)

The Crucial Role of Solvation Forces in the Steric Stabilization of Nanoplatelets

Article says that the steric stability of inorganic colloidal particles in an apolar solvent is usually described in terms of the balance between three contributions: the van der Waals attraction, the free energy of mixing, and the ligand compression. The authors demonstrate that for sufficiently large nanoplatelets, solvation forces are proportional to the interacting facet area, and their strength is intrinsically tied to the softness of the ligand shell.
Date: December 9, 2022
Creator: Petersen, Nanning; Girard, Martin; Riedinger, Andreas & Valsson, Omar
System: The UNT Digital Library
An experimental and chemical kinetic modeling study of the role of potassium in the moist oxidation of CO (open access)

An experimental and chemical kinetic modeling study of the role of potassium in the moist oxidation of CO

Article investigates the effect of KCl on moist CO oxidation in a laminar flow quartz reactor. Experiments were conducted in the absence of O2 (gasification), as well as under reducing and fuel-lean conditions, in the temperature range 873–1573 K, and the results were interpreted in terms of a chemical kinetic model.
Date: December 9, 2022
Creator: Chanpirak, Arphaphon; Wu, Hao; Glarborg, Peter & Marshall, Paul
System: The UNT Digital Library