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Carbon-Hydrogen Bond Activation, C-N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand (open access)

Carbon-Hydrogen Bond Activation, C-N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand

In this study, we describe reaction chemistry of the first nickel(II) complexes having a terminally bound imido ligand, (dtbpe)Ni=NR (R = 2,6-ⁱPr₂C₆H₃, 2,3,6-Me₃C₆H₂ (Mes), and Ad) with various small unsaturated molecules.
Date: December 1, 2014
Creator: Mindiola, Daniel J.; Waterman, Rory; Iluc, Vlad M.; Cundari, Thomas R., 1964- & Hillhouse, Gregory L.
Object Type: Article
System: The UNT Digital Library
Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies (open access)

Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies

Article discussing mechanistic and thermodynamic studies and reversible beta-hydrogen elimination of three-coordinate iron(II) alkyl complexes.
Date: October 1, 2004
Creator: Vela, Javier; Vaddadi, Sridhar; Cundari, Thomas R., 1964-; Smith, Jeremy M.; Gregory, Elizabeth A.; Lachicotte, Rene J. et al.
Object Type: Article
System: The UNT Digital Library
Applications of Hydrogen Gas Getters in Mass Spectrometry (open access)

Applications of Hydrogen Gas Getters in Mass Spectrometry

Patent relating to applications of hydrogen gas getters in mass spectrometry.
Date: December 30, 2009
Creator: Verbeck, Guido F.
Object Type: Patent
System: The UNT Digital Library
What Can We Learn about Dispersion from the Conformer Surface of n-Pentane? (open access)

What Can We Learn about Dispersion from the Conformer Surface of n-Pentane?

This article maps the torsional surface of n-pentane to 10-degree resolution at the CCSD(T)-F12 level near the basis set limit.
Date: February 8, 2013
Creator: Martin, Jan M. L.
Object Type: Article
System: The UNT Digital Library
Thermochemical Investigations of Nearly Ideal Binary Solvents. 6. Solubilities of Iodine and Benzil in Systems of Nonspecific Interactions (open access)

Thermochemical Investigations of Nearly Ideal Binary Solvents. 6. Solubilities of Iodine and Benzil in Systems of Nonspecific Interactions

Article on thermochemical investigations of nearly ideal binary solvents and the solubilities of iodine and benzil in systems of nonspecific interactions.
Date: February 1, 1983
Creator: Acree, William E. (William Eugene) & Bertrand, Gary L.
Object Type: Article
System: The UNT Digital Library
Solubility of Crystalline Nonelectrolyte Solutes in Organic Solvents: Mathematical Correlation of Benzil Solubilities with the Abraham General Solvation Model (open access)

Solubility of Crystalline Nonelectrolyte Solutes in Organic Solvents: Mathematical Correlation of Benzil Solubilities with the Abraham General Solvation Model

Article on the solubility of crystalline nonelectrolyte solutes in organic solvents and the mathematical correlation of benzil solubilities with the Abraham general solvation model.
Date: April 1, 2002
Creator: Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.)
Object Type: Article
System: The UNT Digital Library
Thermochemical Excess Properties of Multicomponent Systems: Representation and Estimation from Binary Mixing Data (open access)

Thermochemical Excess Properties of Multicomponent Systems: Representation and Estimation from Binary Mixing Data

Article on the thermochemical excess properties of multicomponent systems and representation and estimation from binary mixing data.
Date: May 1, 1983
Creator: Bertrand, Gary L.; Acree, William E. (William Eugene) & Burchfield, Thomas E.
Object Type: Article
System: The UNT Digital Library
Spectrochemical Investigation of Preferential Solvation. 2. Compatibility of Thermodynamic Models versus Spectrofluorometric Probe Methods for Tautomeric Solutes Dissolved in Binary Mixtures (open access)

Spectrochemical Investigation of Preferential Solvation. 2. Compatibility of Thermodynamic Models versus Spectrofluorometric Probe Methods for Tautomeric Solutes Dissolved in Binary Mixtures

Article discussing spectrochemical investigations of preferential solvation and the compatibility of thermodynamic models versus spectrofluorometric probe methods for tautomeric solutes dissolved in binary mixtures.
Date: March 1, 1994
Creator: Acree, William E. (William Eugene); Wilkins, Denise C.; Tucker, Sheryl A. (Sheryl Ann); Griffin, Jason M. & Powell, Joyce R.
Object Type: Article
System: The UNT Digital Library
Transition Metal Imido Complexes (open access)

Transition Metal Imido Complexes

Article discussing a wide range of transition metal imido (TMI) complexes using ab initio molecular orbital (MO) calculations.
Date: September 1, 1992
Creator: Cundari, Thomas R., 1964-
Object Type: Article
System: The UNT Digital Library
Does Alkyl Substitution Affect the Si-H Bond Strength in Silane? Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Trimethylsilane and an ab Initio Investigation (open access)

Does Alkyl Substitution Affect the Si-H Bond Strength in Silane? Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Trimethylsilane and an ab Initio Investigation

Article on kinetics studies of the reactions of atomic chlorine and bromine with trimethylsilane and an ab initio investigation.
Date: July 1, 1992
Creator: Ding, Luying & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Investigation of the Gas-Phase Reaction of Trimethylsilyl Radicals with HBr: Measurement of the (CH₃)₃ Si-H Bond Strength (open access)

Investigation of the Gas-Phase Reaction of Trimethylsilyl Radicals with HBr: Measurement of the (CH₃)₃ Si-H Bond Strength

Article on an investigation of the gas-phase reaction of trimethylsilyl radicals with HBr and measurement of the (CH₃)₃ Si-H bond strength.
Date: March 1, 1993
Creator: Goumri, Abdellatif; Yuan, W. J. & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Rate Coefficients for the H + NH₃ Reaction over a Wide Temperature Range (open access)

Rate Coefficients for the H + NH₃ Reaction over a Wide Temperature Range

Article on rate coefficients for the hydrogen atom + ammonia reaction over a wide temperature range.
Date: February 1, 1990
Creator: Ko, Taecho; Marshall, Paul & Fontijn, A. (Arthur)
Object Type: Article
System: The UNT Digital Library
High-Temperature Photochemistry Kinetics Studies of the Reactions of H(1²S) and D(1²S) with N₂O (open access)

High-Temperature Photochemistry Kinetics Studies of the Reactions of H(1²S) and D(1²S) with N₂O

Article on high-temperature photochemistry kinetics studies of the reactions of hydrogen atom(1²S) and deuterium atom (1²S) with nitrous oxide.
Date: March 1, 1989
Creator: Marshall, Paul; Ko, Taecho & Fontijn, A. (Arthur)
Object Type: Article
System: The UNT Digital Library
Kinetic and Thermochemical Studies of the Recombination Reaction Na + O₂ + N₂ from 590 to 1515 K by a Modified High-Temperature Photochemistry Technique (open access)

Kinetic and Thermochemical Studies of the Recombination Reaction Na + O₂ + N₂ from 590 to 1515 K by a Modified High-Temperature Photochemistry Technique

Article on kinetic and thermochemical studies of the recombination reaction sodium + oxygen + nitrogen from 590 to 1515 K by a modified high-temperature photochemistry technique.
Date: April 1, 1990
Creator: Marshall, Paul & Narayan, A. S.
Object Type: Article
System: The UNT Digital Library
Primary and Secondary Inner Filtering: Effect of K₂Cr₂O₇ on Fluorescence Emission Intensities of Quinine Sulfate (open access)

Primary and Secondary Inner Filtering: Effect of K₂Cr₂O₇ on Fluorescence Emission Intensities of Quinine Sulfate

Article on primary and secondary inner filtering and the effect of K₂Cr₂O₇ on fluorescence emission intensities of quinine sulfate.
Date: January 1, 1992
Creator: Tucker, Sheryl A. (Sheryl Ann); Amszi, Vicki L. & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Modern Laboratory Experiment for Instrumental Analysis: Analytical Method for Simultaneous Determination of Chloride and Bromide Ions Based Upon Fluorescence-Quenching Methods (open access)

Modern Laboratory Experiment for Instrumental Analysis: Analytical Method for Simultaneous Determination of Chloride and Bromide Ions Based Upon Fluorescence-Quenching Methods

Article on a modern laboratory experiment for instrumental analysis on an analytical method for simultaneous determination of chloride and bromide ions based upon fluorescence-quenching methods.
Date: February 1, 1995
Creator: Tucker, Sheryl A. (Sheryl Ann) & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
A Student-Designed Analytical Laboratory Method: Titrations and Indicator Ranges in Mixed Aqueous-Organic Solvents (open access)

A Student-Designed Analytical Laboratory Method: Titrations and Indicator Ranges in Mixed Aqueous-Organic Solvents

Article on a student-designed analytical laboratory method for titrations and indicator ranges in mixed aqueous-organic solvents
Date: January 1, 1994
Creator: Tucker, Sheryl A. (Sheryl Ann) & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Quantitative Determination of Cr(III) and Co(II) Using a Spectroscopic H-Point Standard Addition Method (open access)

Quantitative Determination of Cr(III) and Co(II) Using a Spectroscopic H-Point Standard Addition Method

Article on the quantitative determination of Cr(III) and Co(II) using a spectroscopic H-point standard addition method.
Date: July 1, 1997
Creator: Pandey, Siddharth; Powell, Joyce R.; McHale, Mary E. R. & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Quantitative Analysis Laboratory Experiment: Bilinear Regression Analysis as a Means to Reduce Matrix Effects in Simultaneous Spectrophotometric Determination of Cr(III) and Co(II) (open access)

Quantitative Analysis Laboratory Experiment: Bilinear Regression Analysis as a Means to Reduce Matrix Effects in Simultaneous Spectrophotometric Determination of Cr(III) and Co(II)

Article on bilinear regression analysis as a means to reduce matrix effects in simultaneous spectrophotometric determination of Cr(III) and Co(II) and a quantitative analysis laboratory experiment.
Date: July 1, 1998
Creator: Pandey, Siddharth; McHale, Mary E. R.; Coym, Karen S. & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Kinetics-Based Indirect Spectrophotometric Method for Simultaneous Determination of MnO4 (-) and Cr207 (2-): A Modern Instrumental Analysis Laboratory Experiment (open access)

Kinetics-Based Indirect Spectrophotometric Method for Simultaneous Determination of MnO4 (-) and Cr207 (2-): A Modern Instrumental Analysis Laboratory Experiment

Article on kinetics-based indirect spectrophotometric method for simultaneous determination of MnO4 (-) and Cr2O7 (2-) and a modern instrumental analysis laboratory experiment.
Date: April 1, 1998
Creator: Pandey, Siddharth; McHale, Mary E. R.; Horton, Ann-Sofi M.; Padilla, Sandra A.; Trufant, Ashantè L.; De La Sancha, Noé U. et al.
Object Type: Article
System: The UNT Digital Library
A Student-Designed Potentiometric Titration: Quantitative Determination of Iron(II) by Caro's Acid Titration (open access)

A Student-Designed Potentiometric Titration: Quantitative Determination of Iron(II) by Caro's Acid Titration

Article on a student-designed potentiometric titration and a quantitative determination of iron(II) by Caro's acid titration.
Date: October 1, 1996
Creator: Powell, Joyce R.; Tucker, Sheryl A. (Sheryl Ann); Acree, William E. (William Eugene); Sees, Jennifer A. & Hall, Lindsey H.
Object Type: Article
System: The UNT Digital Library
Studying Acid-Base Equilibria in Two-Phase Solvent Media: Analyzing Results Using Aqueous Surfactant Solutions with Organic Solvents in the Titration of Analytes with Low Solubilities and Low Dissociation Constants (open access)

Studying Acid-Base Equilibria in Two-Phase Solvent Media: Analyzing Results Using Aqueous Surfactant Solutions with Organic Solvents in the Titration of Analytes with Low Solubilities and Low Dissociation Constants

Article discussing studying acid-base equilibria in two-phase solvent media and analyzing results using aqueous surfactant solutions with organic solvents in the titration of analytes with low solubilities with low dissociation constants.
Date: January 1, 1993
Creator: Tucker, Sheryl A. (Sheryl Ann); Amszi, Vicki L. & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Computational studies of the potential energy surface for O(³P) + H₂S: Characterization of transition states and the enthalpy of formation of HSO and HOS (open access)

Computational studies of the potential energy surface for O(³P) + H₂S: Characterization of transition states and the enthalpy of formation of HSO and HOS

Article on computational studies of the potential energy surface for O(³P) + H₂S and the characterization of transition states and the enthalpy of formation of HSO and HOS.
Date: January 1, 1995
Creator: Goumri, Abdellatif; Laakso, Dianna; Rocha, John-David Ray; Smith, C. E. & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Computational studies of the potential energy surface for O(¹D) + H₂S: Characterization of pathways involving H₂SO, HOSH, and H₂OS (open access)

Computational studies of the potential energy surface for O(¹D) + H₂S: Characterization of pathways involving H₂SO, HOSH, and H₂OS

Article on computational studies of the potential energy surface for O(¹D) + H₂S and the characterization of pathways involving H₂SO, HOSH, and H₂OS.
Date: December 1, 1994
Creator: Goumri, Abdellatif; Rocha, John-David Ray; Laakso, Dianna; Smith, C. E. & Marshall, Paul
Object Type: Article
System: The UNT Digital Library