The following report covers the construction materials selected for laboratory corrosion studies and the determination of their corrosion rates in process solutions.

From abstract: "This project was a study of electrostatic classification of submicron aerosols. Classification of particles as small as 0.006-[mu]-diameter was shown to be feasible, and good classification of atmospheric dust was achieved. However, a practical solution to the problem of overlapping between particles larger and smaller than 0.1 [mu], the point of minimum electric mobility, was not found."

Abstract: "X-ray and microscopic examination of slags from uranium metal production bombs which gave good and bad yields in the plant at St. Louis have indicated the significance of uranium oxide formation. Apparently the oxide (UO2) results from reaction of the UF4 with linear material, particularly with moisture in the liner."

From introduction: This report presents the results of the two phases of the work: study of the compatibility of beryllia bodies with a coating material, molybdenum; and studies of beryllia-beryllium body fabrication.

This report follows an investigation made to determine creep-rupture data for three sheet materials. Fourteen of sixteen tests were made in an atmosphere of carbon dioxide within hermetically sealed capsules, analyzing the reaction of the three sheet metals: 347 stainless steel, iron-aluminum-chromium alloy designated 261C, and a zirconium-base alloy, AE1H. Minimum creep rate, per cent elongation, and rupture life were determined and reported.

The following report examines the most suitable enamels recommended for protection of aluminum slug cans.

Introduction: "During the early planning of the multicurie cells at Hanford it was decided that a slave type manipulator would be necessary to perform the experiments for which the cells were being designed. The design required steel roofs for installation through a port hole in the face. Technical Services Equipment Development began developing the proposed manipulator in January 1951 by making a study of those existing at that tune. None met the requirements which had been established; therefore, the design of a special manipulator was started immediately."

This report analyzes a linear, hard-core pinch tube built to examine tubes afflicted by small-scale instabilities evident from many observations.

This report describes a toroidal version of the hard-core pinch and the additional information it can obtain to what the analogous linear pinch can get.

Abstract. Experimental work was carried out to improve material conversion efficiency and to reduce handling costs inherent in the present process for production of high purity calcium. Charges up to 54 pounds were handled successfully in the equipment available. Material losses were reduced and more complete removal of alkali and alkaline earth metals was effected by controlled pressures of inert gas and by melting under positive pressure of Argon.

A good determination of the resonance absorption of uranium when admixed with various substances is necessary so that calculations can be made on the efficiency of homogeneous piles. The original experiments along these lines were undertaken by Creutz, Jupnik, and Snyder (C-116) and consisted of experiments on the resonance capture in pure U, UO2, U3O8, and one experiment on capture in a mixture of U3O8 and graphite. These experiments were done at the cyclotron in Princeton and consisted of determining the ratio of the twenty-three minute activity of uranium to an iodine monitor placed in some position with respect to the sample. By using spheres of different radii both the volume and the surface absorptions were measured. It was considered very desirable to extend these measurements to mixtures containing large amounts of graphite to uranium and also to investigate other substances containing hydrogen and deuterium. In addition it was decided to use both iodine and gallium monitors in the experiments. While the experiments were in progress, an absorption curve for uranium metal was made by Marshall using iodine and gallium detectors, which showed that there was a certain amount of overlapping of resonance levels of uranium and iodine.

It was desired to determine a method of evaporating boron to form a rather pure uniform tenacious coat of specified thickness. These coats are needed as monitoring films for neutron intensities, particularly in steel ionization cylinders. The most satisfactory method of evaporating boron employed a graphite filament. A mixture of amorphous boron and Carbenoid A was painted onto the filament which was then heated by electrical resistance method to 2300 degree C at which temperature the boron evaporated. Opaque films with purities up to 98% boron or better could be deposited by this method. Much heat was liberated by the filament, and it was found necessary to cool the steel cylinders during evaporation to prevent alloying of boron with the steel. Cathodic deposition also proved satisfactory for producing high purity films; this method has the advantage that little or no heat is produced during the process, but requires much time. Other less efficacious methods of depositing lighter films of born were developed; these are included in the following discussion.

The following report presents neutron-flux measurements with the Mark I element, which include neutron-flux distribution and flux depression within the element.

The following report describes a chemical procedure to analyze fission products and long-lived rare earths in both untreated urine samples and the supernates from the precipitation steps in the TTA procedure for plutonium.

"A series of glass compositions containing uranium oxide was investigated to determine fiberizability and physical properties of resultant fibers. The basic properties to be determined were the maximum U/sub 3/O/sub 8/ content in a fiberizable glass and the maximum service temperature of the fibers. Glasses containing 60 wt% U/sub 3/O/sib 8/ were fiberizable; the fibers had strengths of 100,000 psi at 1600 deg F. Fiber-forming equipment was installed at Moun Laboratory to produce glass fibers containing PuO/sub 2/. Fibers were successfully formed in the first trials. For additional work a series of base glasses were provided affording a wider range of both PuO/sub 2/ solubility and physical properties."

This report covers the S-I-5-B-M fuel irradiation in the GETR Maritime Loop during the second quarter of fiscal year 1962. The data are summarized in Section II. Discussions on fuel performance, fuel environment (water chemistry), problems with loop operations, and the crud deposition program are included.

"lsotope dilution techniques are described for the assay of chlorinated hydrocarbon pesticides and organic phosphorus pesticides in foods. Results are given for the determination of tetranitro-DDT-dianilide, dianilide of tetranitro- DDE, dieldrin, systox, and derivatives of these compounds. "

"As presented in the original proposal the project consisted essentially of three parts: Phase I, Development and refinement of a radiochemical flow counting technique for the study of kinetics of reactions in solution ; Phase II, The application of this technique to the detailed study of the mechanism of solvolysis of sulfonium salts in mixed solvents ; Phase II, The further application of this kinetic technique, as a longer term aim, to other reacting systems of biochemical or other interest. This report covers the work of the contractual period 1 Sept. 1959 to 31 Aug. 1960."

The compatibility of zirconium diboride, boron carbide, and boron nitride with type 304 stainless steel was evaluated as a function of temperature (1000-1200°C), time (1-3 hr). Appropriate loadings of the boron compounds and stainless steel powder were blended and fashioned into a compact powder metallurgically. Each compact was roll clad into a plate and subsequently heat treated at a temperature equal to the initial sintering temperature. Metallographic examination of the fabricated and heat-treated plates demonstrated that none of the systems were metallurgically stable. The instability was generally manifested by the (1) interaction of the discrete boron compounds with the matrix and (2) precipitation of a hypothetically boron-rich phase throughout the stainless steel matrix material.

This is the thirty-seventh progress report of the Laboratory for Nuclear Science at the Massachusetts Institute of Technology. Progress during the period of June 1, 1955 through August 31, 1955 is reported on: (1) Chemistry of the fission elements group, (2) Nuclear chemistry (inorganic) group, (3) Nuclear chemistry (organic) group, (4) Cosmic ray group, (5) Elementary particle scattering group, (6) neutron physics group, (7) ONR generator group, (8) Radioactivity group, (9) Cyclotron group, (10) Synchrotron group, (11) Theoretical group, (12) Personnel listing.

Abstract: "A magnetically operated pump has been constructed and used successfully to pump a mixture of uranium hexafluoride and hydrogen fluoride gases at pressures up to 175 psia. and temperatures up to 100 C."

Abstract. The region where exact thermodynamic description of the state of matter at high pressure and high temperature is possible is located. In the remaining region various approximate theories and empirical relations are discussed. These considerations are applied to hydrogen to locate the density and pressure at which the diatomic bond collapses. Also the approximate conditions are determined at which no bound electron states exist.

The following report describe the effect of plasma oscillations using a table-top model and the probable magnitude of the quantities needed to reach complete ionization.

Abstract: High Velocity disturbance are observed to propagate in advance of the plane shock front along the walls of a high-explosive-operated shock tube. Experiments were performed which indicate that the disturbance proceeds at a constant velocity relative to the shock front, and carries a considerable amount of energy as evidenced by its ability to penetrate metal plates. The velocity of a similar disturbance observed along a rod placed on the axis of the shock tube normal to the plane shock front was essentially independent of the rod material and diameter. This phenomenon was observed when shock tubes were filled with argon or chlorine but was absent when air or helium was used.