Abstract: "A method has been established for the estimation of volatile organic acids in aqueous process solutions containing UNH, nitric acid, ANN, sodium dichromate and small amounts of hexone. The practice is to distill a 400 ul or 500 ul sample in the presence of an excess of phosphoric acid and ferrous sulfate under a high vacuum; a special apparatus utilizing a receiver cooled with a dry ice-isopropanol mixture is employed. The distillate is taken up in isopropanol and then titrated potentiometrically with standard potassium hydroxide solution. Since nitric acid and organic acids are present, two end points are observed. The potassium hydroxide added between these end points is equivalent to the organic acids. In the titration, CO2 from the atmosphere or in the potassium hydroxide is a source of error. The former was avoided and correction was made for the latter."

The following report provides information conducted with the purpose of ascertaining the effect of oxygen on activated charcoal at approximately one atmosphere by measuring the amount of CO2 formed over a known length of time.

Either system appears to be fairly satisfactory from a containment standpoint. Current results indicate probable over-all rates of about 0.2mils/mo for titanium vs. 1.5-3.0 mils/mo for Ni-o-nel. Tests are not 100% comparable due to changes made in flowsheet conditions, but have been of sufficient variation and length as to allow good predictions to be made. Both metals show some tendency toward local attack in Thorex solutions. These tendencies are increased by poor welding techniques.

Equilibrium loading of uranium on Dowex 21K has been studied in a sulfate system for uranium concentrations from 0.0005 M to 0.0005 M, total sulfate concentrations of 0.45 M to 0.6M, and sulfuric acid concentration of 0.020 M. Loading data have been fitted to Langmuir adsorption isotherms and Langmuir constants have been evaluated. Resin was equilibrated with uranium feed solutions by flowing the feed through a shallow fixed bed of resin.

Reactivity measurements conducted in the Hanford Test Pile are interpreted to yield resonance integrals for uranium, uranium oxide, thorium and thorium oxide. The experiments were made using cadmium filters and are discussed in terms of the multiplication factor of the Hanford Test Pile.

Statistical methods were employed to measure relative values of electron loading and spark-over voltage for a large number of unoutgassed electrode materials. Test voltages up to 110 KV were employed in vacuum of the order of 10<sup>-7 mm Hg. All metals showed a square root dependence between spark-over voltage and spacing.