Techniques for conditioning of Ta filaments for improved bonding and emission with a Ta metal powder-Ta/sub 2/O/sub 5/ mixture are described. A porous Ta metal layer is deposited which restricts sample to the filament. Metal- oxide ion emission is enhanced with additional Ta/sub 2/O/sub 5/ to the porous layer. Reduction of fractionation through action of liquid Ta/sub 2/O/sub 5/ is discussed in particular for Sr+ emission. Use of conditioned filaments for rapid U concentration analysis with a single-filament mass spectrometer is emphasized. (auth)

This report outlines the detailed design and system analysis of a solar industrial process steam system for the Lone Star Brewery. The industrial plant has an average natural gas usage of 12.7 MMcf per month. The majority of this energy goes to producing process steam of 125 psi and 353/sup 0/F at about 50,000 lb/h, with this load dropping to about 6000 lb/h on the weekends. The maximum steam production of the solar energy system is about 1700 lb/h. The climatic conditions at the industrial site give 50% of the possible amount of sunshine during the winter months and more than 70% during the summer months. The long-term yearly average daily total radiation on a horizontal surface is 1574 Btu/day-ft/sup 2/, the long-term yearly average daytime ambient temperature is 72/sup 0/F, and the percentage of clear day insolation received on the average day of the year is 62%. The solar steam system will consist of 9450 ft/sup 2/ of Solar Kinetics T-700 collectors arranged in fifteen 90-ft long rows through which 67.5 gpm of Therminol T-55 is pumped. This hot Therminol then transfers the heat collected to a Patterson-Kelley Series 380 unfired steam boiler. The solar-produced steam is then metered …

The processing of Al fuel, principally of the MTR-ETR type, is reported. Processing rate averaged 90% of flow sheet values for the entire operating period, and a U recovery of 99.85% was achieved. Aqueous Zr fuel processing studles continued with the objective of adapting the HF process to continuous dissolution-complexing in order to increase the capacity of the ICPP process while using as much existing equipment as possible to minimize costs. Good results were indicated in a 190-hr run dissolving 2% U-Zr fuel in a Monel dissolver using 4.8M HF-0.03M HNO/sub 3/ dissolvent at 200 deg F; insoluble material did not accumulate in the dissolver, although a U-containing film was formed, apparently in small, equilibrium quantity. Shorter term continuous laboratory dissolutions indicated that 4.8M acid was preferable to 10M acid for the acid feed rate/fuel surface ratios proposed, resulting in dissolver products of greater stability and higher uranium content. Additional laboratory data are presented on UF/sub 4/ hydrate form and solubility, together with maximum dissolvable U compositions with Zircaloy under various flowsheet condltions. Processing of Al alloys containing high Si was found to present no unusual problems in laboratory studies. Siliceous residues resulting from dissolution of Al-U alloys containing 2% …

The possible effects of a hydrogen atmosphere in reducing film deposition were studied in the large circulating loop and in rocking cell and pyrolytic capsule tests. At H/sub 2/ pressures of 200 to 400 psig no reduction in film weight deposited was observed in the loop tests, and in the pyrolytic tests film deposits were doubled. Heat conductivity of the films was much higher however. ln these high ash films the inorganic constituent was found to be alpha -Fe rather than the usual magnetite, which seems to account for the heat conductivity. Separation of benzene-insoluble material from high boiler and coolant was accomplished by centrifugation and by deposition on glass. The material was closely related to film formation. The nature of the inorganic and organic constituents of this material was examined in several analytical studies. Advances in the techniques of nuclear magnetic resonance, O/sub 2/ analysis, measurement of chromatograms, application of computers, and other methods were made. It was demonstrated by use of Fe5/sup 59/ that irradiated terphenyl under air attacks Fe rapidly and possibly the Fe is in solution as a chelate or other complex. It also was indicated by some tests that such a soluble form of Fe …

Under sponsorship from the US Department of Energy, technical personnel from the Savannah River Laboratory (SRL) and other DOE laboratories, universities and private industry have completed a full scale demonstration of environmental remediation using horizontal wells. This demonstration was performed as Phase I of an Integrated Demonstration Project designed to evaluate innovative remediation technologies for environmental restoration of sites contaminated with organic contaminants. The demonstration utilized two directionally drilled horizontal wells to deliver gases and extract contaminants from the subsurface. The resulting in situ air stripping process was designed to remediate soils and sediments above and below the water table as well as groundwater contaminated with volatile organic contaminants. The 139 day long test successfully removed volatile chlorinated solvents from the subsurface using the two horizontal wells. One well, approximately 300 ft (90m) long and 165 ft (50m) deep drilled below a contaminant plume in the groundwater, was used to inject air and strip the contaminants from the groundwater. A second horizontal well, approximately 175 ft (53m) long and 75 ft (23m) deep in the vadose zone, was used to extract residual contamination in the vadose zone along with the material purged from the groundwater. Pretest and posttest characterization data …

The Hanford metal wastes were divided into four categories: supernate - the liquid waste; hard sludge - dense agglomerates of poorly defined crystalline carbonates approximating the hardness of soft blackboard chalk; soft sludge - an easily slurried semi-solid consisting chiefly of needle-like phosphates; and recombined sludge - a representative sample of the solid wastes as received from Hanford, shown to be a mixture of hard and soft sludges in the ratio 2/3 by weight. The density of supernate, in the temperature range 24 to 74/sup 0/C, varied from 1.130 to 1.103 g/ml. Hard sludge density averaged 3.0 g/ml and that of soft sludge averaged 1.84 g/ml. The consistency, or apparent viscosity, as a function of temperature, shear rate, and solids content was measured individually on slurries of recombined, soft, and hard sludges using supernate as the suspending medium. Settling rates were also run on these 3 slurries as a function of solids content.

This cleanup verification package documents completion of removal actions for the 105-H Reactor Ancillary Support Areas, Below-Grade Structures, and Underlying Soils (subsite 118-H-6:2); 105-H Reactor Fuel Storage Basin and Underlying Soils (118-H-6:3); and Fuel Storage Basin Deep Zone Side Slope Soils. This CVP also documents remedial actions for the following seven additional waste sties: French Drain C (100-H-9), French Drain D (100-H-10), Expansion Box French Drain E (100-H-11), Expansion Box French Drain F (100-H-12), French Drain G (100-H-13), Surface Contamination Zone H (100-H-14), and the Polychlorinated Biphenyl Surface Contamination Zone (100-H-31).

The study of meteorite Murray has been reported in previous Quarterly Reports. This report gives further results with Murray, and information on another meteorite, Orgueil. A sample of Orgueil was sent from the Museum National d Histoire Naturelle, Paris. It fell in several pieces over an area of 2 square miles near Orgueil, France, in 1864. The elemental analysis of this meteorite is shown in Table 1. They extracted a 10.07-g sample of this meteorite with water, using the same procedure as that for Murray. The water extracted 1.32 g, which is at least twice as much material as was water-extracted from Murray. The elemental analysis of the water extract is given in Table II and its uv spectrum is shown in Figure 1. From an x-ray diffraction pattern it was determined that the water extract contained mostly MgSO{sub 4} {center_dot} 6H{sub 2}O with some calcium sulfate. Their spectrum (Figure 2) shows a strong SO{sub 4} band at 1100 cm{sup -1}, = strong H{sub 2}O bands at 1650 cm{sup -1} and 3200-3600 cm{sup -1}, and some unidentified peaks at 2300, 1400, and 980 cm{sup -1}. The approximately 8 g of Orgueil left after the water extraction was then extracted with …

Use of a one-dimensional model of longitudinal space-charge(SC) impedance has been proposed for studying the microbunchinginstability in single-pass delivery systems relevant for the nextgeneration of FELs. For beams with uniform transverse density andcircular cross-section of radius r_b the SC impedance can be expressed ina handy analytical form, making this model particularly convenient. Inthis report we show how with an appropriate choice of r_b one can usethis as an effective-beam model to approximate beams with non-axissymmetric and non-uniform transverse densities.

This thesis studies Monte Carlo simulations of QCD heavy flavor production processes (p{bar p} {yields} Q({anti Q})X) at hadron colliders. ISAJET bottom quark cross-sections are compared to the O({alpha} {sub s}{sup 3}) perturbative calculation of Nason, Dawson, and Ellis. These Monte Carlo cross-sections are computed from data samples which use different parton distribution functions and physics parameters. Distributions are presented in the heavy quark's transverse momentum and rapidity. Correlations in rapidity and azimuthal angle are computed for the heavy flavor pair. Theory issues which arise are the behavior of the cross-section at low and high values of transverse momentum and the treatment of double counting problems in the flavor excitation samples. An important result is that ISAJET overestimates bottom quark production cross-sections and K factors. These findings are relevant for estimates of rates and backgrounds of heavy floor events.

During the first year of the grant, we participated in three WOCE expeditions (a total of 152 days at sea) in the South Pacific Ocean, and the field phase of the proposed investigation has been successfully completed. The total CO[sub 2] concentration and pCO[sub 2] were determined at sea in 4419 water samples collected at 422 stations. On the basis of the shipboard analyses of SIO Reference Solutions for CO, and a comparison with the results of previous expeditions, the overall precision of our total CO[sub 2] determinations is estimated to be about [plus minus]2 uM/kg. The deep water data indicate that there is a CO[sub 2] maximum centered about 2600 meters deep. This appears to represent a southward return flow from the North Pacific. The magnitude and distribution of the CO, maximum observed along the 135.0[degrees]W meridian differ from those observed along the 150.5[degrees]W meridian due to Tuamotu Archipelago, a topographic high which interferes with the southward return flow. The surface water pCO[sub 2] data indicate that the South Pacific sub-tropical gyre water located between about 15[degrees]S and 50[degrees]S is a sink for atmospheric CO[sub 2].

Proposals to amend Appendix A of Part 440 of Weatherization Assistance for Low-Income Persons are described. The proposals establish new specifications for the materials purchased for utilization in the weatherization of dwellings which qualify for assistance under Part 440. These proposed regulations prescribe the minimum requirements which must be met or exceeded by each type of material and the Federal standards to which they must conform. In addition, these regulations include installation requirements for each class of material installed at the request of the enduser. (MCW)

Engineering and construction activities associated with the Dresden Unit 1 chemical cleaning facility are described for January to June 1979.

This report documents the technical evaluation of the station and instrument ground grid systems at the Davis Besse Nuclear Power Station, Unit 1. The evaluation is to determine that there are no inadvertent ties between the instrument and station ground grid systems, that any identified inadvertent ties are corrected, and to assure that the installation meets design criteria. The information submitted by the licensee indicates that there are no inadvertent ties between the station and instrument ground grid systems and that the installation meets design criteria.

The KIPS Ground Demonstration System (GDS) was designed to simulate, as closely as possible, a Flight System Conceptual Design (FSCD). No radiator was incorporated and electric heat sources were used in place of isotope heat sources. To minimize air in-leakage and to simulate heat losses associated with space operation, the system was operated in a vacuum chamber. Initial testing was performed on the development system which did not incorporate a high performance turbine or non-condensing configuration of the cold liquid passages in certain regenerator vapor regions. After testing of the development system and retrofit to the GDS configuration, which included improvements in the above two items, the GDS was installed in the test chamber. Testing to date showed the GDS configuration has demonstrated a system efficiency of greater than 15%. Satisfactory heat balances have been calculated on most system components, permitting evaluation of component performance. Certain performance deficiencies currently exist which prevented the 18% efficiency goal being attained. These can be corrected with further development.

This report summarizes the results of a safety analysis that was done on Building 151. The report outlines the methodology, the analysis, and the findings that led to the low hazard classification. No further safety evaluation is indicated at this time. 5 tables.

The Oak Ridge Research Reactor (ORR) was constructed in the mid 1950s. Since it is an older facility, the issue of life-limiting conditions or material deterioration resulting from prolonged exposure to the normal operating environment is an item that should be addressed in the safety analysis for the ORR. Life-limiting conditions were considered in the original design of ORR; but due to the limited data that were available at that time on material performance in research reactors, various studies were completed during the first 10 years of operation at ORR to verify the applicable life-limiting parameters. Based on today's knowledge of life limiting conditions and the previous 30 years of operating experience at the ORR facility, the three specific areas of concern are addressed in this supplement: (1) embrittlement of the structures due to radiation damage, which is described in Section 2; (2) fatigue due to the effects of both thermal cycling and vibration, which is addressed in Section 3; and (3) the effects of corrosion on the integrity of the primary system, which is described in Section 4. The purpose of this document is to provide a review of the applicable safety studies which have been performed, and to …

Pile Engineering Sub-Section has been investigating the causes and effects of cocked slugs in process tubes for the past year because they are suspected to be the cause for some slug ruptures. In Project CG-642 - Continuous Charge-Discharge Equipment - C Reactor it is proposed that slugs be flush charged into the process tubes. This document reports the effect of flush charging slugs on their tendency to cock as discovered in laboratory tests.

A new technique is describe for the direct detection of volatile organic compounds in aqueous solutions at levels in the parts per trillion range. The sample is enriched in analyte in two consecutive stages, one utilizes a semi-permeable membrane interface and the other a jet separator. The analyte solution is sampled as it flows coaxially over a semi-permeable capillary membrane, the interior of which is continuously purged by helium. The permeate is pneumatically transported to the mass spectrometer via a jet separator, which is used to remove excess helium and water from the analyte vapor stream. Data are reported for an ion trap mass spectrometer used in conjunction with a conventional fixed-gap quartz jet separator. Typical analyte response times are 2-5 minutes and flow injection methods are used for sample delivery. Detection limits in the range 30 to parts per billion are observed for selected volatile organic compounds and the response is linear over 3 orders of magnitude. Details of the construction of the interface are provided.

Under sponsorship from the US Department of Energy, technical personnel from the Savannah River Laboratory (SRL) and other DOE laboratories, universities and private industry have completed a full scale demonstration of environmental remediation using horizontal wells. This demonstration was performed as Phase I of an Integrated Demonstration Project designed to evaluate innovative remediation technologies for environmental restoration of sites contaminated with organic contaminants. The demonstration utilized two directionally drilled horizontal wells to deliver gases and extract contaminants from the subsurface. The resulting in situ air stripping process was designed to remediate soils and sediments above and below the water table as well as groundwater contaminated with volatile organic contaminants. The 139 day long test successfully removed volatile chlorinated solvents from the subsurface using the two horizontal wells. One well, approximately 300 ft (90m) long and 165 ft (50m) deep drilled below a contaminant plume in the groundwater, was used to inject air and strip the contaminants from the groundwater. A second horizontal well, approximately 175 ft (53m) long and 75 ft (23m) deep in the vadose zone, was used to extract residual contamination in the vadose zone along with the material purged from the groundwater. Pretest and posttest characterization data …

During the first year of the grant, we participated in three WOCE expeditions (a total of 152 days at sea) in the South Pacific Ocean, and the field phase of the proposed investigation has been successfully completed. The total CO{sub 2} concentration and pCO{sub 2} were determined at sea in 4419 water samples collected at 422 stations. On the basis of the shipboard analyses of SIO Reference Solutions for CO, and a comparison with the results of previous expeditions, the overall precision of our total CO{sub 2} determinations is estimated to be about {plus_minus}2 uM/kg. The deep water data indicate that there is a CO{sub 2} maximum centered about 2600 meters deep. This appears to represent a southward return flow from the North Pacific. The magnitude and distribution of the CO, maximum observed along the 135.0{degrees}W meridian differ from those observed along the 150.5{degrees}W meridian due to Tuamotu Archipelago, a topographic high which interferes with the southward return flow. The surface water pCO{sub 2} data indicate that the South Pacific sub-tropical gyre water located between about 15{degrees}S and 50{degrees}S is a sink for atmospheric CO{sub 2}.

Although Lawrence Livermore National Laboratory has been involved in weapons disassembly since its involvement in weapons design, the Lab was recently requested by the Department of Energy to extend its responsibility for LLNL-designed weapons to include dismantlement of some systems in the cold war arsenal. Dissolution of LX-10-1 and PBX-9404 explosive from two artillery fired atomic projectiles (AFAPs) can be accomplished using dimethyl sulfoxide. The composition of LX-10-1 and PBX-9404 are given. The authors have evaluated the detonability of solutions of these two plastic bonded explosives in dimethyl sulfoxide (DMSO) under shock and thermal scenarios based on the UN ``Recommendations on the Transport of Dangerous Goods - Tests and Criteria`` (ST/SG/AC.10/11) and US Army Technical Bulletin 700-2. Prior to the relatively large scale shock and thermal sensitivity testing, small scale safety tests and thermochemical code calculations were used as a preliminary estimate of the detonability and hazards associated with up to 33% of these explosives in DMSO. Thermochemical calculations, small scale safety testing, and gap testing all indicate that these solutions are not detonable. They are currently in the process of evaluating these solutions using the small scale cookoff bomb (SCB) test.

The historical approach to the separation of radon from water is liberation of the radon from the sample by boiling under vacuum in the presence of a strong acid; flushing the liberated radon, with an inert gas, into an ionization chamber or an alpha proportional counters and measuring the collected activity. Such an analysis requires a manipulation time of approximately one hour, a waiting period of two to three hours before measurement to allow transitory equilibrium to be reached, and finally a measurement time, resulting in 4 to 6 hours for one analysis. In addition, specialized equipment including a vacuum train is required. If it is desired to count the alpha particles from radon and its daughters in a proportional counter, absorption trains to remove all oxygen, a poor counting gas, are required. The method presented herein requires only 20--25 minutes for a complete analysis and except for the beta counter utilizes standard laboratory equipment.

This report discusses the following topics relating to inertial confinement with spin polarized hydrogen targets: low temperature implementation of mating a target to omega; dilution-refrigerator cold-entry and retrieval system; target shell tensile strength characterization at low temperatures; and proton and deuteron spin-lattice relaxation measurements in HD in the millikelvin temperature range. (LSP)