Equilibrium loading of uranium on Dowex 21K has been studied in a sulfate system for uranium concentrations from 0.0005 M to 0.0005 M, total sulfate concentrations of 0.45 M to 0.6M, and sulfuric acid concentration of 0.020 M. Loading data have been fitted to Langmuir adsorption isotherms and Langmuir constants have been evaluated. Resin was equilibrated with uranium feed solutions by flowing the feed through a shallow fixed bed of resin.

"An experiment to determine the effect of reactor irradiation on the thermal conductivity of uranium-impregnated graphite at elevated temperatures as described. The results show a decrease in the thermal conductivity saturating at [approximately] 60 percent at a temperature of 700 degrees C; at [approximately] 50 percent at a temperature of 1000 degrees C; and at [approximately] 25 percent at a temperature of 1300 degrees C. It was found that after irradiation at a given temperature, exposure at a higher temperature resulted in an increase in the thermal conductivity. The converse was also observed. Within the precision of measurement there was no difference in effed between temperature changes produced by varying the fission rate in the samples and changes produced by varying the power in an external heater."

A promising scheme for the chemical processing of a thorium breeder reactor of the two-region aqueous homogeneous type consists of the following operations: concentration of insoluble fission and corrosion products from the core system into a small volume of fuel solution, combining this slurry with irradiated thorium oxide slurry taken from the blanket, recovery of D2O by evaporation, dissolution of the thorium and uranium in HNO3, and, after a suitable cooling period, recovery of the uranium and thorium by solvent extraction for return to the reactor. The use of a hydroclone and underflow container arrangement for concentrating insoluble fission and corrosion products under simulated reactor conditions has been successfully demonstrated on dynamic loops. Solids concentration factors greater than 103 were demonstrated, and equilibrium solids concentration in the circulating solution less than 1 ppm was attained in these tests. Present data indicate that proper design and operation will minimize solids deposition in the reactor system and that the insoluble impurities can be effectively removed by the hydroclone. An alternate method of processing the slurry removed from the core system by the hydroclone consists of removing the room temperature insolubles by centrifugation, recovering the uranium from the supernatant by peroxide precipitation, thermal …

It is concluded that an excess of O2 must be added to the HRT fuel circulating stream in amounts sufficient to recombine the D2 in dead-end lines and serve as corrosion protection.

In the preliminary stages of getting up a time-of-flight system for measuring neutron spectra from proton reactions, a study of the time dependence of the beam in the 86Inch Cyclotron was made. This study revealed the expected bunching of the protons to produce a short burst of beam on each cycle of the 13.4 Mc/s accelerating voltage. In addition to the 13.4 Mc/s structure, however, there was a 360 c/sec modulation of the beam pulses and a complicated pattern built upon that.

When it was discovered that two HRT flange bolts of a lot of 16 spares contained serious cracks, a program was launched to (1) determine the cause for the cracking, and (2) find methods for non-destructive testing the remainder of the 672 bolts shipment, a large portion of which had been installed in the HRT. Concurrently, inspection of 8 ferrules removed from an HRT flange revealed hairline cracking in 4 of them. Magnaglo, a magnetic particle inspection method using a fluorescent dye, proved to be the only definitive method for inspecting the bolts. The evidence gathered on the bolts pointed to quench cracking as the cause for the defects. Nothing abnormal was disclosed in regard to the bolt material. The alloy and heat treatment at present prescribed for the HRT bolts and ferrules are considered suitable. However, recommendations are made for plating with zinc, instead of formerly prescribed cadmium, to a thickness of 0.0002 inch, followed by a hydrogen relief treatment and a final bichromate chemical dip.

The following report presents a discussion of the method for hydrodynamic problems, together with some new considerations that have arisen concerning the method.

Abstract: "Variations in receiver slot design produce changes in quantity and quality of product and recycle, not only instantaneously, but also as a function of time in approaching equilibrium. The case of fixed feed concentration and fixed inventory of Uranium is described here for standard and Dip-Lip wider R slot receivers. The effects of the two types of receivers on recycle and product X and W concentrations, X production rate, plant X utilization efficiency, integrated X production and effective mass output are shown graphically."

Statistical methods were employed to measure relative values of electron loading and spark-over voltage for a large number of unoutgassed electrode materials. Test voltages up to 110 KV were employed in vacuum of the order of 10<sup>-7 mm Hg. All metals showed a square root dependence between spark-over voltage and spacing.

This technical report analyzes an experiment designed to test the theory of seismic decoupling of underground explosives proposed by Latter, LeLevier, Martinelli, and McMillan [1959]. The theory calculated the amplitude of a 1.7-kiloton nuclear explosive in a hole in salt and compares it to the measured value of the 1.7-kt Rainier shot in tuff at the same distance. A decoupling factor of about 300 resulted. The experiment, called Cowboy, was designed to test the decoupling principle by carrying out a series of eight high-explosive shots in two spheres made in a salt dome and nine tamped shots for comparison purposes. The seismic data reported here was obtained primarily at 14,000 and 22,000 feet from the shot at frequencies of 10 to 30 cps. A salt-to-salt decoupling factor of 100 was obtained which is consistent wit the predicted 300 tuff-to-salt factor. When the sphere was over-driven so that the walls did not move elastically (a condition which violates the theory), decoupling factors of 10 and 30 were measured. The report interprets the seismic data to give the dependence of decoupling on the various parameters of the experiment. The decoupling deduced from measurements made 80 feet from the shot points is found …

The apparatus and procedures that are to be used to fill the liquid metal system of the Pratt and Whitney Forced Convection Liquid Metal Inpile Loop are described. The liquid metal to be used is a mixture containing 56% Na and 44% K, which is a liquid at room temperature. In order to simplify the filling procedure at the reactor site, two containers, each of which contains exactly enough liquid metal to fill the experiment to the prescribed level, a fill dolly incorporating a purified helium system, and an evacuation system will be provided at the reactor site. After completion of the liquid metal transfer, the liquid metal fill tube will be crimped, cut, and seal welded. The liquid metal and helium systems will then be pressurized through the helium fill tubes, which will also be crimped, cut, and seal welded. Each tube seal weld will be inspected after completion of the weld by mass spectrometry leak check and dye penetrant fault detection

"The influence of compressive creep on the self-diffusivity of α-iron has been measured in the temperature range of 742-885°C. the diffusivity is enchanced in proportion to the strain rate, but this dependence decreases with increasing temperature. The magnitude of the strain is relatively unimportant in this connection. Strain rates from 0 to -2 x 10¯³ sec¯¹ were investigated with a corresponding increase in diffusivity up to 3 x 10³ times. The results are analyzed in terms of vacancy diffusion and the excess vacancies introduced during deformation. It is concluded that grain boundaries are the main vacancy sinks in polycrystalline iron and that the vacancy lifetime is therefore dependent on the grain size."

Recently, there has been some evidence to point to possible ordering in the α-brasses. Masumoto et al. have concluded from their specific heat measurements that there is a possibility of ordering in the α-brasses. In particular they observed an anomaly in the specific heat curves for the α-brasses for the temperature range from 200 to 260°C and explained these results upon the basis of a change in local or short range order in α-brasses at these temperatures. In connection with the study of radiation damage effects in α-brass ordering has been suspected. Rosenblatt has annealed 70-30 α-brass previously annealed at 350°C and cooled to room temperature at 190°C for six weeks. He observed a decrease of .90 ± .03% in the electrical resistivity of α-brass measured at -196°C after the anneal at 190°C.

"The purposes of the program being conducted under the present contract are: 1) To determine the feasibility of cladding zirconium on uranium by a direct casting process. 2) To investigate the diffusion of liquid metals in the fusion zone."

Technical report. Quite pure anhydrous ThCl4 in small quantity (8-10 g charge) has been prepared by the action of a mixture of Cl2 and CCl4 vapor on ThO2 at 675 degrees to 725 degrees C.

This report describes the results of evaluation tests made on several glass-coated bayonet heaters supplied to Separations Equipment Development by the Pfaudler Company. The glass-coated heaters were found to be resistant to thermal shock, mild mechanical shock, and chemical attack by boiling 60% nitric acid.

Thorium and thorium-uranium oxide slurries were irradiation in the Low Intensity Test Reactor (LITR) at temperatures up to 300C in small stirred autoclaves. Stirring was accomplished by means of an electromagnetically operated lunger. Stirrer operations was monitored suing an oscilloscope. Relative slurry viscosities were determined both in and out-of-pile using calibration curves of apparent viscosity versus stirrer rise time. Post-irradiation examination of selected slurries indicated no gross changes occurred in the particulate properties.

"This bibliography lists selected articles on beryllium which have appeared in journals received in the library of the Lawrence Radiation Laboratory, Livermore, California and articles, reports, and books which have appeared in the following abstracting services between January, 1958 and August 1959."

The following quarterly report covers the period between April, May and June of 1954. The reports presented in this document discusses subjects of medical health and physics such as: biological studies of radiation effects, the metabolic properties of various tracer materials, radiation chemistry, health chemistry, and health physics.

Abstract. An inexpensive method for detection of dust-loaded high efficiency filters is described. Air flow is continuously indicated by elementary pitot tubes and plastic rotameters. Accuracy obtained is within +- 15%. Information as to construction, installation, and use is presented.

A preliminary study of molten salt power reactors was made. The most promising fuel carrier salts were the fluorides and chlorides of the alkali metals, zirconium, and beryllium. The chlorides were found to have lower melting points but were less stable and more corrosive than the fluorides. A Li/sup 7/ F- - BeF/sub 2/ mixture with ThF/sub 4/ and UF/sub 4/appeared to perform best. Of the numerous alloys tested as container material, Inconel and a nickel-- molybdenum alloy INOR-8 appeared to be the most resistant to corrosion. To study the performance, safety, economics, and construction costs of a typical molten salt reactor, a reactor of specific type and size was chosen for study. The reference design reactor was a two-region homogeneous converter with a core salt of 70 mole% Li/sup 7/F and 30% BeF/sub 2. ThF/sub 4/ and enough VF/sub 4/ for criticality were added. Study indicated that a molten salt reactor would produce economical power, but the problem of developing a salt core and a container metal which would last for many years of operation needed further study. (M.C.G.)

"These notes are intended to serve as a summary of the current knowledge of properties of materials. In the future some need may exist for related information of methods of testing, design and fabrication. This issue presents information on low tin-zirconium alloys with subdivision..."

"The magnetic properties of color centers were studied to obtain information regarding electron traps in insulators. Experiments designed to determine the equation governing the recovery of resonance after saturation were carried out. Relatively large samples were prepared by the method of additive coloration. KCl and RbCl crystals were used. Resonance saturation as a function of concentration was investigated and no significant dependence found. Measurements of the unsaturated susceptibility were made at liquid nitrogen and liquid helium temperatures. The bleaching of the F-center to form the B-band produced a different resonance. The equipment for observing the saturation and recovery of a portion of the resonance at 4 deg K is described. A theoretical examination was made of the interaction between the vibration of the ions around a negative-ion vacancy in an alkali halide and an electron trapped at that site. (M.C.G.)."

The leak detector system consists of one gas pressurized reservoir containing heavy water, a tubing manifold connecting the pressurizer to six separate lines each connected to one of the flanges, tubing lines leading from the second hole on each of three flange pairs (dome and heat exchanger flanges) back into the instrument room, plus required valves and fittings. A schematic diagram of the system in included.