A study was conducted on the elution behavior of curium (III), americium (III), plutonium (III), actinium (III), plutonium (IV), neptunium (IV), uranium (IV), thorium (IV), neptunium (V), plutonium (VI), uranium (VI), lanthanum (III), cerium (III), europium (III), ytterbium (III), ytterium (III), strontium (II), barium (II), radium (II), cesium (I) with 3.2 M, 6.2 M, and 12.2 M HCI solutions from Dower-50 cation exchange resin columns. These elutions show that in high concentrations of hydrochloric acid the actinides form complex ions with chloride ion to a much greater extent than the lanthanides. In order to explain these results, a partial covalent character may be ascribed to the bonding in the transuranium complex ions. It is shown that a reasonable structure for such covalent bonding involves hybridization of the 5g-ortibals in the actinide elements.

The fission and spallation reactions caused in uranium by bombardment with high energy protons (340 to 350 Mev) were investigated. The reaction products were separated from the target by chemical processes and identified by their radioactive properties. The relative yields of the observed fission products were measured, and the results plotted as a function of mass number. Several of the spallation products were identified and their yields estimated.