A detailed study of four reactor and shield configurations was made. Two basic reactor types, the boiling water and pressurized water reactors were considered. Shield materials of lead-water and iron-water were used with varying thicknesses for determining the optimum shield configuration for the PL-3 reactor. Also presented is a survey of available shielding codes. (auth)

We consider the negative ion concentrations in hydrogen discharges caused by electron excitation and dissociative attachment processes. The principal formation and destruction processes are discussed for electron densities in the range 10/sup 8/ to 10/sup 13/ electrons cm/sup -3/. Expressions are developed for calculating the high energy portion of the electron energy distribution in the discharge; using these energy distributions the electron excitation rates are evaluated. At low densities, the vibrational distribution arises from singlet electronic excitations and triplet excitations through the /sup 3/..pi../sub u/ state, in equilibrium with wall de-excitation processes. At high densities singlet excitations predominate in equilibrium with atom-molecule de-excitation processes. Possibilities for negative ion generation in a two-chamber tandem system are discussed in which the vibrational excitation occurs in a high power, high electron temperature discharge, kT/sub e/ = 5 eV, and dissociative attachment occurs in a low temperature kT/sub e/ = 1 eV, plasma chamber.

This report discusses the following topics on the effect radiation has on thermonuclear reactor materials: Atomic Displacements; Microstructure Evolution; Materials Engineering, Mechanics, and Design; Research on Low-Activation Steels; and Research Motivated by Grant Support.

Mainstream projects which have adult fish passage facilities are inspected by project operators, fishway attendants, and state and federal fishery agencies. The overall movement of upstream migrants in 1984 appeared to be satisfactory with few delays. Special efforts were made by fishery agencies and Corps personnel to check on potential problems which appeared to exist at The Dalles and John Day Dams this year. However, adult passage facilities were operating ''in criteria'' and fish may have been delayed by temperature or other factors. Inspections were generally made once a month. Some projects were operating at less than full criteria as seen during inspections by fishery agencies this year. It appears that during periods of low tailwater, certain projects have difficulty maintaining proper head at main fishway entrances. Some main entrance gates bottom-out and water depth over these weirs are not up to desired criteria. Also it was noted that auxiliary water pumps were not being run at a rate to achieve the desired amount of water for attracting fish to the fish ladders and maintaining proper head at main fishway entrances.

This report summarizes the results of an economic evaluation of the MIT process for the manufacture of ethanol from cellulosic residues. Conceptual process designs were developed for two cases, Case A which is based on the experimental data obtained to date, and Case B which hypothesizes the suppression of acid byproducts. Manufacturing costs, including profit, were estimated at $12.20/million Btu for Case A and $9.40/million Btu for Case B. These are equivalent to about $1.05 and $0.80/gal ethanol respectively. These economic estimates may be slightly on the low side since they do not consider feedstock storage nor working capital requirements. Nevertheless, the manufacturing costs for Case A appear to be comparable to those of the manufacture of ethanol from corn. The plant size used for this analysis was 1500 ton/day corn stover. This is considered to be a realistic size. The conceptual plants make about 27 million gal/yr ethanol in Case A and 41 million gal/yr in Case B. The MIT process appears to be one of the more promising programs being developed under contract for DOE. It is recommended that the process research be continued. Three areas of concern were identified which must be investigated before the process can …

Construction progress is listed and photographs of the solar atrium are included. (MHR)

This Phase I SBIR project investigated the economic and technical feasibility of advanced amine scrubbing systems for post-combustion CO2 capture at coal-fired power plants. Numerous combinations of advanced solvent formulations and process configurations were screened for energy requirements, and three cases were selected for detailed analysis: a monoethanolamine (MEA) base case and two “advanced” cases: an MEA/Piperazine (PZ) case, and a methyldiethanolamine (MDEA) / PZ case. The MEA/PZ and MDEA/PZ cases employed an advanced “double matrix” stripper configuration. The basis for calculations was a model plant with a gross capacity of 500 MWe. Results indicated that CO2 capture increased the base cost of electricity from 5 cents/kWh to 10.7 c/kWh for the MEA base case, 10.1 c/kWh for the MEA / PZ double matrix, and 9.7 c/kWh for the MDEA / PZ double matrix. The corresponding cost per metric tonne CO2 avoided was 67.20 $/tonne CO2, 60.19 $/tonne CO2, and 55.05 $/tonne CO2, respectively. Derated capacities, including base plant auxiliary load of 29 MWe, were 339 MWe for the base case, 356 MWe for the MEA/PZ double matrix, and 378 MWe for the MDEA / PZ double matrix. When compared to the base case, systems employing advanced solvent formulations and …

Heats of formation of the lowest triplet state of ethylene and the ground triplet state of ethylidene have been predicted by high level electronic structure calculations. Total atomization energies obtained from coupled-cluster CCSD(T) energies extrapolated to the complete basis set limit using correlation consistent basis sets (CBS), plus additional corrections predict the following heats of formation in kcal/mol: Delta H0f(C2H4,3A1) = 80.1 at 0 K and 78.5 at 298 K, and Delta H0f(CH3CH,3A") = 86.8 at 0 K and 85.1 at 298 K, with an error of less than +-1.0 kcal/mol. The vertical and adiabatic singlet-triplet separation energies of ethylene were calculated as Delta ES-T,vert = 104.1 and Delta ES-T,adia = 65.8 kcal/mol. These results are in excellent agreement with recent quantum Monte Carlo (DMC) values of 103.5 +- 0.3 and 66.4 +- 0.3 kcal/mol. Both sets of computational values differ from the experimental estimate of 58 +- 3 kcal/mol for the adiabatic splitting. The computed singlet-triplet gap at 0 K for acetylene is Delta ES-T,adia(C2H2) = 90.5 kcal/mol, which is in notable disagreement with the experimental value of 82.6 kcal/mol. The heat of formation of the triplet is Delta H0f(C2H2,3B2) = 145.3 kcal/mol. There is a systematic underestimation of …

Understanding the aqueous chemistry of plutonium, in particular in environmental conditions, is often complicated by plutonium's complex redox chemistry. Because plutonium possesses four oxidation states, all of which can coexist in solution, a reliable method for the identification of these oxidation states is needed. The identification of plutonium oxidation states at low levels in aqueous solution is often accomplished through an indirect determination using series of liquid-liquid extraction procedures using oxidation state specific reagents such as HDEHP and TTA. While these methods, coupled with radioactive counting techniques provide superior limits of detection they may influence the plutonium redox equilibrium, are time consuming, waste intensive and costly. Other analytical methods such as mass spectrometry and radioactive counting as stand alone methods provide excellent detection limits but lack the ability to discriminate between the oxidation states of the plutonium ions in solution.

Ground state structures with side-on nitrosyl ({eta}{sup 2}-NO) and isonitrosyl (ON) ligands have been observed in a variety of transition-metal complexes. In contrast, excited state structures with bent-NO ligands have been proposed for years but never directly observed. Here we use picosecond time-resolved infrared spectroscopy and density functional theory (DFT) modeling to study the photochemistry of Co(CO){sub 3}(NO), a model transition-metal-NO compound. Surprisingly, we have observed no evidence for ON and {eta}{sup 2}-NO structural isomers, but have observed two bent-NO complexes. DFT modeling of the ground and excited state potentials indicates that the bent-NO complexes correspond to triplet excited states. Photolysis of Co(CO){sub 3}(NO) with a 400-nm pump pulse leads to population of a manifold of excited states which decay to form an excited state triplet bent-NO complex within 1 ps. This structure relaxes to the ground triplet state in ca. 350 ps to form a second bent-NO structure.

The purpose of this Strategic Plan Report is to provide an introduction and in-depth analysis of the issues and opportunities, resources, and technologies of energy efficiency and renewable energy that have potential beneficial application for the people of the Jicarilla Apache Nation and surrounding communities. The Report seeks to draw on the best available information that existed at the time of writing, and where necessary, draws on new research to assess this potential. This study provides a strategic assessment of opportunities for maximizing the potential for electrical energy efficiency and renewable energy development by the Jicarilla Apache Nation. The report analyzes electricity use on the Jicarilla Apache Reservation in buildings. The report also assesses particular resources and technologies in detail, including energy efficiency, solar, wind, geothermal, biomass, and small hydropower. The closing sections set out the elements of a multi-year, multi-phase strategy for development of resources to the maximum benefit of the Nation.

LLNL has been using the largest transparent laser ceramics for the last two years in the solid-state heat capacity laser (SSHCL). The lab is very interested in extending the use of transparent ceramics to other laser applications. In this talk we will discuss work at the laboratory aimed at better understanding the sintering and the criteria needed for good ceramic transparency, the application of transparent ceramics in the SSHCL laser and possible new applications of tailored ceramics.

The potential use of different iron phosphates as cathodematerials in lithium-ion batteries has recently been investigated.1 Oneof the promising candidates is LiFePO4. This compound has severaladvantages in comparison to the state-of-the-art cathode material incommercial rechargeable lithium batteries. Firstly, it has a hightheoretical capacity (170 mAh/g). Secondly, it occurs as mineraltriphylite in nature and is inexpensive, thermally stable, non-toxic andnon-hygroscopic. However, its low electronic conductivity (~;10-9 S/cm)results in low power capability. There has been intense worldwideresearch activity to find methods to increase the electronic conductivityof LiFePO4, including supervalent ion doping,2 introducingnon-carbonaceous network conduction3 and carbon coating, and theoptimization of the carbon coating on LiFePO4 particle surfaces.4Recently, the Li doped LiFePO4 (Li1+xFe1-xPO4) synthesized at ARL hasyield electronic conductivity increase up to 106.5 We studied electronicstructure of LiFePO4 and Li doped LiFePO4 by synchrotron based soft X-rayemission (XES) and X-ray absorption (XAS) spectroscopies. XAS probes theunoccupied partial density of states, while XES the occupied partialdensity of states. By combining XAS and XES measurements, we obtainedinformation on band gap and orbital character of both LiFePO4 and Lidoped LiFePO4. The occupied and unoccupied oxygen partial density ofstates (DOS) of LiFePO4 and 5 percent Li doped LiFePO4 are presented inFig. 1. Our experimental results clearly indicate …

Operations with the Geothermal Loop Experimental Facility are reviewed. Inspection of the separators, scrubbers, pumps, valves, and controls is described. (MHR)

The conclusions we have reached are that rainout of fresh radioactive debris occurred at Hiroshima and Nagasaki, that this precipitation was initiated either by the weapon itself or by the ensuing fires or by both, and that self-induced rainout can occur and deposit sufficient amounts of radioactivity on the ground to pose a significant collateral damage hazard.

At about 6:30 a.m. one of the two Process Operators regularly stationed at 233-S was performing routine work in the Control Room, heard a nearby Poppy alpha detector breaking down.'' He checked and found the instrument appeared to be in operating condition as it would respond to a high level source. Further checking indicated that he was contaminated and that nearby horizontal surfaces were contaminated. This information was phoned to the Shift Supervisor who told the Operator that he would be right out and to throw a pair of shoe covers out the door. On arriving, the Supervisor donned the shoe covers and then quickly checked the Poppy response and confirmed the report of the Operator. Both men then left the building. Just outside they met the other Process Operator assigned to 233-S, returning from the lunchroom. The second Operator was handed a smear, previously taken and checked by the Supervisor, and told to check it on a Poppy in the load-out-room, a room adjacent to where the contamination was originally found. When the Supervisor heard the load-out-room Poppy break down as the smear was checked he instructed both Operators to stand by just outside the building while he went …

Data tabulated for chemical composition of geothermal waters are presented for four areas of interest in Nevada: Beowawe steam well and Beowawe Hot Spring, Buffalo Valley Hot Springs, Kyle Hot Springs, and Leach Hot Springs. Material recommendations were prepared for the Nevada geothermal well. A detailed field corrosion test program planned for the Nevada test well is included. A progress report is presented for a laboratory research program on velocity effects in corrosion. (MHR)

Catalytic studies on a new method for methanol synthesis from CO and H{sub 2} in a slurry reactor are described. This reaction proceeds through the carbonylation of methanol to methyl formate in the liquid phase followed by hydrogenolysis of methyl formate to two molecules of methanol; the net result is the reaction of CO with H{sub 2} to give methanol. Moderate temperatures and pressures (100--160{degrees}C, 50--65 atm) are used. Reaction rates using mixed catalysts comprised of an alkali methoxide and Cu-chromite are presented. It seems likely that Cu-chromite maintains the activity of the alkali methoxide catalyst. A mixed catalyst comprised of potassium methoxide and Cu-chromite was found to be the most active under the reaction conditions used. Evidence is provided for an interaction between the alkali methoxide and Cu-chromite. 27 refs., 6 figs., 2 tabs.

The report covers the PC-2, C-beam chordal average density measurement made on the loss-of-fluid test (LOFT) primary coolant system hot leg during the L1-4 nonnuclear loss-of-coolant accident (LOCA) test conducted May 3, 1977. The P-2, C-beam, or LOFT advanced densitometer, used was of the pulse height analysis/energy discrimination, or nuclear hardened type to be used for LOFT nuclear tests. The L1-4 test verified the applicability of pulse height analysis/energy discrimination techniques of the nuclear hardened gamma densitometer. Test results show that the reactor coolant fluid chordal average density can be calculated from gamma radiation source signal measured count rate data.

Imaging techniques that can be used to translate seismic and electromagnetic wave signals into visual representation are briefly discussed. The application of these techniques is illustrated on the example of determining the subsurface structure of a proposed power plant. Imaging makes the wave signals intelligible to the non-geologists. R and D work needed in this area are tabulated. (JSR)

This disposal concept is based on the Tumulus design developed by the French at the La Manche facility. Waste units are stacked above-grade on a concrete pad. The facility currently under development at the Oak Ridge National Laboratory (ORNL) involves sealing waste in concrete vaults, placing the vaults on a grade level concrete pad, and covering the pad and vaults with a soil cover after vault emplacement is complete. Emplacement is expected to continue until the facility exhausts its approximate 800 m/sup 3/ (28,000 ft/sup 3/) capacity. The facility incorporates engineered barriers to radionuclide migration; a monitoring system to ensure barrier performance; and a newly developed set of Demonstration Waste Acceptance Criteria to reduce the likelihood of groundwater contamination.

Figure-of-merit equations for material selection and detailed design equations have been developed to aid in the design of a linear electrooptic deflector element for use in a 10-ps streak camera. The figure of merit indicates that BaTiO/sub 3/, KTN, and ammonium oxalate (AMO) are suitable materials. Possible deflector designs, including that of a current AMO prototype development program, are discussed. Quadratic (Kerr-effect) operation and materials are discussed along with the possibility for 10.6-..mu..m-wavelength use.

Siltec Corporation's contract with JPL is directed towards the design and development of equipment and processes, to demonstrate continuous growth of crystals by the Czochralski method, suitable for producing single silicon crystals for use in solar cells. Continuous growth is defined as the growth of 100 Kg of single silicon crystal, 10 cm in diameter, from one container. Siltec's approach to meeting this goal is to develop a furnace with continuous liquid replenishment of the growth crucible, accomplished by a meltdown system and a liquid transfer mechanism, with associated automatic feedback controls. The design of the furnace elements has been completed, and all parts are now in the fabrication stage. The electronic control console regulating the growth system and meltdown system, and the liquid transfer mechanism, has been assembled. An experiment was performed with a standard production furnace, to demonstrate controlled flow of molten silicon through a small I.D. tube by pressure differential. Sections of the transfer tube system were evaluated, power requirements to balance heat losses determined, axial temperature profile in the tube, and radial temperature gradients in the heat pack were measured. A mathematical model was made for the electromagnetic throttle valve to control flow of molten silicon …

A revised program plan is presented for developing an electric vehicle incorporating a flywheel regenerative power system with design considerations and goals for safety and for vehicle body construction using lightweight fiber-reinforced composite material. Schedules are included for each of the major steps in the program. (LCL)