A preliminary assessment was conducted to evaluate factors that may have been responsible for the vegetation damage that has occurred in groundwater seeps downslope from the F- and H-area seepage basins. The factors that were considered included altered hydrology, toxicity from hazardous chemical constituents associated with seepage basin operation, and toxicity from non-hazardous constituents associated with basin operation. It was concluded that the observed damage was not likely to have resulted from altered hydrologic conditions or hazardous constituents associated with basin operation. Insufficient information is currently available to determine definitively which of the non-hazardous constituents, alone or in concert, were responsible for the observed vegetation damage. The most likely explanation, however, is that elevated Na, pH, and conductivity is outcropping seep water are responsible for tree mortality. All three of these factors will return to ambient levels over a period of several years when basin operation ceases. Faster remediation can be achieved using lime at the seep line.

In April 1987, Air Products started the third and final contract with the US Department of Energy to develop the Liquid Phase Methanol (LPMEOH) process. One of the objectives was to identify alternative commercial catalyst(s) for the process. This objective was strategically important as we want to demonstrate that the LPMEOH process is flexible and not catalyst selection limited. Among three commercially available catalysts evaluated in the lab, the catalyst with a designation of F21/0E75-43 was the most promising candidate. The initial judging criteria included not only the intrinsic catalyst activity but also the ability to be used effectively in a slurry reactor. The catalyst was then advanced for a 40-day life test in a laboratory 300 cc autoclave. The life test result also revealed superior stability when compared with that of a standard catalyst. Consequently, the new catalyst was recommended for demonstration in the Process Development Unit (PDU) at LaPorte, Texas. This report details the methodology of testing and selecting the catalyst.

The proceedings of six work groups that discussed techniques to prevent and abate noise, hydrogen sulfide emissions, and accidental spills of chemicals and geothermal wastes at The Geysers-Calistoga KGRA are reported. Problems associated with well completion and production, and with systems, components, and materials, and their effects on emissions were also discussed. The comments and recommendations of the work groups are included in the proceedings. (MHR)

The objective of this study was to investigate the feasibility of using the cementitious properties and agglomeration characteristics of coal conversion byproducts to encapsulate and immobilize hazardous waste materials. The intention was to establish an economical way of co-utilization and co-disposal of wastes. In addition, it may aid in the eradication of air pollution problems associated with the fine-powdery nature of fly ash. Encapsulation into agglomerates is a novel approach of treating toxic waste. Although encapsulation itself is not a new concept, existing methods employ high-cost resins that render them economically unfeasible. In this investigation, the toxic waste was contained in a concrete-like matrix whereby fly ash and other cementitious waste materials were utilized. The method incorporates the principles of solidification, stabilization and agglomeration. Another aspect of the study is the evaluation of the agglomeration as possible lightweight aggregates. Since fly ash is commercially used as an aggregate, it would be interesting to study the effect of incorporating toxic wastes in the strength development of the granules. In the investigation, the fly ash self-cementation process was applied to electroplating sludges as the toxic waste. The process hoped to provide a basis for delisting of the waste as hazardous and, thereby …

Work in the Carpenter laboratory under the aegis of grant DE-FG02-98ER14857 concerned the formation, properties, and reactions of organic free radicals known or believed to be important in hydrocarbon combustion. Both computational and experimental methods were employed in these studies.

Electron bunches with the unparalleled combination of high charge, low emittances, and short time duration, as first produced at the SLAC Final Focus Test Beam (FFTB), are foreseen to be produced at the SABER facility. These types of bunches have enabled wakefield driven accelerating schemes of multi-GV/m in plasmas. In the context of the Dielectric Wakefield Accelerators (DWA) such beams, having rms bunch length as short as 20 um, have been used to drive 100 um and 200 um ID hollow tubes above 20 GV/m surface fields. These FFTB tests enabled the measurement of a breakdown threshold in fused silica (with full data analysis still ongoing) [1]. With the construction and commissioning of the SABER facility at SLAC, new experiments would be made possible to test further aspects of DWAs including materials, tube geometrical variations, direct measurements of the Cerenkov fields, and proof of acceleration in tubes >10 cm in length. This collaboration will investigate breakdown thresholds and accelerating fields in new materials including CVD diamond. Here we describe the experimental plans, beam parameters, simulations, and progress to date as well as future prospects for machines based of DWA structures.

Innovation Partners proposed and successfully demonstrated in this SBIR Phase I grant a software/hardware co-design approach to reduce both the difficulty and time to implement Field Programmable Gate Array (FPGA) solutions to data acquisition and specialized computational applications. FPGAs can require excessive time for programming and require specialized knowledge that will be greatly reduced by the company's solution. Not only are FPGAs ideal for DAQ and embedded solutions, they can also be the best solution to specialized signal processing to replace Digital Signal Processors (DSPs). By allowing FPGA programming to be done in C with the equivalent of a simple compilation, algorithm changes and improvements can be implemented decreasing the life-cycle costs and allow subsitution of new FPGA designs staying above the technological details.

The DOE supported research is a theoretical statistical-mechanical based study of the thermophysical properties of fluids and fluid mixtures. It focuses upon thermodynamic and transport properties in particular. In addition the study covers the development of new ways for predicting the microscopic structure of fluids in a wide range of thermodynamic state parameters, including the critical point.

An ab-initio calculation of the optical potential for neutron-nucleus scattering has been performed by explicitly coupling the elastic channel to all the particle-hole (p-h) excitation states in the target. These p-h states may be regarded as doorway states through which the flux flows to more complicated configurations, and (in the end) to long-lived compound nucleus resonances. The random-phase approximation (RPA) provides the linear combinations of p-h states that include the residual interactions within the target, and we show preliminary results for elastic flux loss using both p-h and RPA descriptions of target excitations.

We report on the development and prototyping efforts undertaken with the goal of producing a micro-vertex detector for the STAR experiment at the RHIC accelerator at BNL. We present the basic detector requirements and show a sensor development path, conceptual mechanical design candidates and readout architecture. Prototyping and beam test results with current generation MimoSTAR-2 sensors and a readout system featuring FPGA based on-the-fly hit finding and data sparsification are also presented.

Several hybridization-based methods used to delineate single copy or repeated DNA sequences in larger genomic intervals take advantage of the increased resolution and sensitivity of free chromatin, i.e., chromatin released from interphase cell nuclei. Quantitative DNA fiber mapping (QDFM) differs from the majority of these methods in that it applies FISH to purified, clonal DNA molecules which have been bound with at least one end to a solid substrate. The DNA molecules are then stretched by the action of a receding meniscus at the water-air interface resulting in DNA molecules stretched homogeneously to about 2.3 kb/{micro}m. When non-isotopically, multicolor-labeled probes are hybridized to these stretched DNA fibers, their respective binding sites are visualized in the fluorescence microscope, their relative distance can be measured and converted into kilobase pairs (kb). The QDFM technique has found useful applications ranging from the detection and delineation of deletions or overlap between linked clones to the construction of high-resolution physical maps to studies of stalled DNA replication and transcription.

On December 17, 2008, the reference-case projections from Annual Energy Outlook 2009 (AEO 2009) were posted on the Energy Information Administration's (EIA) web site. We at LBNL have, in the past, compared the EIA's reference-case long-term natural gas price forecasts from the AEO series to contemporaneous natural gas prices that can be locked in through the forward market, with the goal of better understanding fuel price risk and the role that renewables can play in mitigating such risk. As such, we were curious to see how the latest AEO reference-case gas price forecast compares to the NYMEX natural gas futures strip. This brief memo presents our findings. Note that this memo pertains only to natural gas fuel price risk (i.e., the risk that natural gas prices might differ over the life of a gas-fired generation asset from what was expected when the decision to build the gas-fired unit was made). We do not take into consideration any of the other distinct attributes of gas-fired and renewable generation, such as dispatchability (or lack thereof), differences in capital costs and O&M expenses, or environmental externalities. A comprehensive comparison of different resource types--which is well beyond the scope of this memo--would need to …

A phase-space discontinuous Galerkin (PSDG) method is presented for the solution of stellar radiative transfer problems. It allows for greater adaptivity than competing methods without sacrificing generality. The method is extensively tested on a spherically symmetric, static, inverse-power-law scattering atmosphere. Results for different sizes of atmospheres and intensities of scattering agreed with asymptotic values. The exponentially decaying behavior of the radiative field in the diffusive-transparent transition region and the forward peaking behavior at the surface of extended atmospheres were accurately captured. The integrodifferential equation of radiation transfer is solved iteratively by alternating between the radiative pressure equation and the original equation with the integral term treated as an energy density source term. In each iteration, the equations are solved via an explicit, flux-conserving, discontinuous Galerkin method. Finite elements are ordered in wave fronts perpendicularly to the characteristic curves so that elemental linear algebraic systems are solved quickly by sweeping the phase space element by element. Two implementations of a diffusive boundary condition at the origin are demonstrated wherein the finite discontinuity in the radiative intensity is accurately captured by the proposed method. This allows for a consistent mechanism to preserve photon luminosity. The method was proved to be robust and …

A molten hydroxide trapping process has been considered for removing radioiodine species from off-gas streams whereby iodine is reacted directly with molten hydroxides such as NaOH or KOH. The resulting product is the corresponding iodide, which can be separated by simple cooling of the molten mixture to grow the iodide primary phase once the mixture reaches 70-80 mol% in the iodide component. Thermodynamic analysis indicates that such a chemical process is highly favorable. Experimental testing of the trapping process using molecular iodine showed trapping of up to 96% of the volatile iodine. The trapping efficiency was dependent on operational parameters such as temperature and gas-melt contact efficiency, and higher efficiencies are expected as the process is further developed. While an iodide phase could be effectively isolated by slow cooling of a molten iodide-hydroxide mixture, the persistent appearance of hydroxide indicated that an appreciable solubility of hydroxide occurred in the iodide phase.

The objective of this systems study is to produce a waste removability strategy document that contains sufficient details, recommended design alternatives, and the technical rationale (a) to support Licensing in the development of the License Application Plan, and (b) to provide input in the form of design requirements, for the FY 97 Retrieval Design & Operation activity in support of viability assessment. The intent of this systems study is to support a decision on how to proceed with design with respect to retrievability, regarding the extent to which the repository/waste package designs should accommodate the retrieval option.

Evaporitic environments are found in a variety of depositional environments as early as the Archean. The depositional settings, microbial community and mineralogical composition vary significantly as no two settings are identical. The common thread linking all of the settings is that evaporation exceeds precipitation resulting in elevated concentrations of cations and anions that are higher than in oceanic systems. The Dead Sea and Storrs Lake are examples of two diverse modern evaporitic settings as the former is below sea level and the latter is a coastal lake on an island in the Caribbean. Each system varies in water chemistry as the Dead Sea dissolved ions originate from surface weathered materials, springs, and aquifers while Storrs Lake dissolved ion concentration is primarily derived from sea water. Consequently some of the ions, i.e., Sr, Ba are found at significantly lower concentrations in Storrs Lake than in the Dead Sea. The origin of the dissolved ions are ultimately responsible for the pH of each system, alkaline versus mildly acidic. Each system exhibits unique biogeochemical properties as the extreme environments select certain microorganisms. Storrs Lake possesses significant biofilms and stromatolitic deposits and the alkalinity varies depending on rainfall and storm activity. The microbial community …

Little Pend Oreille National Wildlife Refuge is proposing to acquire a 706-acre property located in Stevens County, Washington. The new acquisition would be called the Kaniksu Unit. A habitat evaluation was conducted on the property using the Habitat Evaluation Procedures (HEP) methodology (U.S. Fish and Wildlife Service 1980). Evaluation species were black-capped chickadee, mallard, ruffed grouse and white-tailed deer. Life requisites evaluated were food and reproduction for black-capped chickadee, food, cover, and reproduction for mallard, available winter browse for white-tailed deer and fall-to-spring cover for ruffed grouse.

A good method for solving the nonlinear Vlasov equation is the semi-Lagrangian algorithm, in which the phase space density is represented by its values on a fixed Cartesian grid with interpolation to off-grid points. At each time step, orbits are followed backward from grid points. Since this method is expensive with phase space dimension D > 2, we seek a more efficient discretization of the density. Taking a cue from the theory of numerical quadrature in high dimensions, we explore the idea of replacing the grid by scattered data sites from a low-discrepancy (quasirandom) sequence. We hope to see a reduction in the required number of sites, especially for D > 2. In our first implementation we follow forward orbits rather than backward, and work only with D = 2. We are able to reduce the number of sites by a factor of 8, at least for a limited time of integration. A much bigger reduction is expected in higher dimensions.

Foot and mouth disease (FMD) is a highly infectious and contagious viral disease affecting bovidae (cattle, zebus, domestic buffaloes, yaks), sheep, goats, swine, all wild ruminants and suidae. Camelidae (camels, dromedaries, llamas, vicunas) have low susceptibility. Foot and mouth disease is caused by a RNS virus of the family Picornaviridae, genus Aphthovirus. There are seven immunologically distinct serotypes: A, O, C, SAT1, SAT2, SAT3, Asia 1. Foot and mouth disease causes significant economic loss both to countries who manage it as an endemic disease (with or without vaccination), as well as those FMD free countries which may become infected. The mortality rate is low in adult animals, but often higher in young due to myocarditis. Foot and mouth disease is endemic in parts of Asia, Africa, the Middle East and South America (sporadic outbreaks in free areas). The Office of International Epizootics (OIE), also referred to the World Organization for Animal Health maintains an official list of free countries and zones.1 The OIE Terrestrial Code (Chapter 2.2.10) provides detailed information on the categories of freedom that can be allocated to a country as well as guidelines for the surveillance for foot and mouth disease (Appendix 3.8.7). In short, countries may …

The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

A new approach for positron acceleration in non-linear plasma wakefields driven by electron beams is presented. Positrons can be produced by colliding an electron beam with a thin foil target embedded in the plasma. Integration of positron production and acceleration in one stage is realized by a single relativistic, intense electron beam. Simulations with the parameters of the proposed SABER facility [1] at SLAC suggest that this concept could be tested there.

The E163 laser acceleration experiments conducted at SLAC have stringent requirements on the temporal properties of two regeneratively amplified, 800nm, Spitfire laser systems. To determine the magnitude and cause of timing instabilities between the two Ti:Sapphire amplifiers, we pass the two beams through a cross-correlator and focus the combined beam onto a Hamamatsu G1117 photodiode. The photodiode has a bandgap such that single photon processes are suppressed and only the second order, two-photon process produces an observable response. The response is proportional to the square of the intensity. The diode is also useful as a diagnostic to determine the optimal configuration of the compression cavity.

Many of the important challenges facing humanity, including developing alternative sources of energy and improving health, are being addressed by advances that demand the improved understanding and control of matter. While the visualization, exploration, and manipulation of macroscopic matter have long been technological goals, scientific developments in the twentieth century have focused attention on understanding matter on the atomic scale through the underlying framework of quantum mechanics. Of special interest is matter that consists of natural or artificial nanoscale building blocks defined either by atomic structural arrangements or by electron or spin formations created by collective correlation effects The essence of the challenge to the scientific community has been expressed in five grand challenges for directing matter and energy recently formulated by the Basic Energy Sciences Advisory Committee [1]. These challenges focus on increasing our understanding of, and ultimately control of, matter at the level of atoms, electrons. and spins, as illustrated in Figure 1.1, and serve the entire range of science from advanced materials to life sciences. Meeting these challenges will require new tools that extend our reach into regions of higher spatial, temporal, and energy resolution. X-rays with energies above 10 keV offer capabilities extending beyond the nanoworld …

This project consisted of three major research areas: (1) development of a solid Pu ceramic target for the MASHA separator, (2) chemical separation of nuclear decay products, and (3) production of new isotopes and elements through nuclear reactions. There have been 16 publications as a result of this project, and this collection of papers summarizes our accomplishments in each of the three areas of research listed above. The MASHA (Mass Analyzer for Super-Heavy Atoms) separator is being constructed at the U400 Cyclotron at the Flerov Laboratory of Nuclear Reactions in Dubna, Russia. The purpose of the separator is to physically separate the products from nuclear reactions based on their isotopic masses rather than their decay characteristics. The separator was designed to have a separation between isotopic masses of {+-}0.25 amu, which would enable the mass of element 114 isotopes to be measured with outstanding resolution, thereby confirming their discovery. In order to increase the production rate of element 114 nuclides produced via the {sup 244}Pu+{sup 48}Ca reaction, a new target technology was required. Instead of a traditional thin actinide target, the MASHA separator required a thick, ceramic-based Pu target that was thick enough to increase element 114 production while still …