The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a carbon dioxide (CO{sub 2}) project for the south Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. The second objective is to demonstrate the performance and economic viability of the project in the field. All work this quarter falls within Task V field demonstration. Short progress reports are presented for field demonstration involving: drill horizontal injection wells 6C-25H and 7C-11H; and drill two vertical WAG injectors along South Cowden Unit boundary.

Work includes studies of interface and grain boundary chemistry and structure in silicon nitride matrix/silicon carbide whisker composites, and in monolithic silicon nitride and silicon carbide synthesized by several different methods. Off-stoichiometric, impurity, and sintering aid elemental distributions in these materials (and other ceramics) have been of great interest because of expected effects on properties but these distributions have proven very difficult to measure because the spatial resolution required is high. The authors made a number of these measurements for the first time, using techniques and instrumentation developed here. Interfaces between metals and SiC are the basis for important metal matrix composites and contacts for high temperature SiC-based solid state electronic devices. The authors have investigated ultrapure interfaces between Ti, Hf, Ti-Hf alloys, Pt, and Co and Si-terminated (0001) 6H SiC single crystals for the first time.

Soil waste is generated from Tank Farms and associated Tank Farms facilities operations. The soil is a mixed waste because it is an environmental media which contains tank waste, a listed mixed waste. The soil is designated with the listed waste codes (FOO1 through F005) which have been applied to all tank wastes. The scope of this report includes Tank Farms soil managed under the Backlog program. The Backlog Tank Farm soil in storage consists of drums and 5 boxes (originally 828 drums). The Backlog Waste Program dealt with 2276 containers of solid waste generated by Tank Farms operations during the time period from 1989 through early 1993. The containers were mismanaged by being left in the field for an extended period of time without being placed into permitted storage. As a corrective action for this situation, these containers were placed in interim storage at the Central Waste Complex (CWC) pending additional characterization. The Backlog Waste Analysis Plan (BWAP) (RL 1993) was written to define how Backlog wastes would be evaluated for proper designation and storage. The BWAP was approved in August 1993 and all work required by the BWAP was completed by July 1994. This document presents results of …

The purpose of this report is to present test data recorded during acceptance testing of the Mobile Color Camera System (MCCS).

This work plan defines the manner in which the Waste Receiving and Processing Facility, Module I Process Area will be maintained under development control status. This status permits resolution of identified design discrepancies, control system changes, as-building of equipment, and perform modifications to increase process operability and maintainability as parallel efforts. This work plan maintains configuration control as these efforts are undertaken. This task will end with system testing and reissue of field verified design drawings.

During fiscal year 1997, the level of success achieved by the Tank Waste Remediation System (TWRS) shall be determined by specific performance measures. These measures take the form of significant deliverables, one of which is the completion of Tank Characterization Reports (TCRs). In order to achieve success regarding the TCR performance deliverable, multiple organizations across TWRS must work together. Therefore, the requirements and expectations needed from each of these TWRS organizations were examined in order to gain an understanding of the performance necessary from each organization to achieve the end deliverable. This memorandum of understanding (MOU) documents the results of this review and establishes the performance criteria by which TWRS will assess its progress and success. These criteria have been determined based upon a TWRS Characterization Project budget of $56.8 million for fiscal year 1997; if this budget is changed or the currently identified workscope is modified, this MOU will need to be revised accordingly. This MOU is subdivided into six sections, where sections three through six each identify individual interfaces between TWRS organizations. The specific performance criteria related to each TWRS organizational interface are then delineated in the section, along with any additional goals or issues pertaining to that …

This Design Review Report (DRR) documents the closure of all Review Cormnent Record sheets associated with the design reviews conducted for the Project W-314 Phase 1 Project Development Specification (PDS) Requirements Analysis. The DRR includes the documented comments and their respective dispositions for the W-314 PDS Requirements Analysis documents associated with Transfer Piping, Valve Pit Manifolds, Pit Leak Detection, Master Pump Shutdown, and Special Protective Coating. Acceptance of the comment dispositions and closure of the review comments is indicated by the Signatures of the participating reviewers.

This safety evaluation for packaging (SEP) document was developed to provide safety evaluations necessary to approve the transfer of the 222-S Cargo Tank from the 222-S Lab to the 204-AR Transfer Station. The SEP demonstrates that the onsite transfer will provide an equivalent degree of safety as would be provided by a package meeting the U.S. Department of Transportation requirements. This fulfills the onsite transportation safety requirements implemented in WHC-CM-2-14, Hazardous Material Packaging and Shipping.

The goal of this task is to demonstrate a bonding technique to produce a dual-alloy turbine disk concept which will satisfy the diverse property requirements of the rim and hub areas of the disk. The program examines methods of attaching a cast superalloy rim with sufficient rupture strength to a fine grain hub materials with the required LCF properties. The goals of the program were established in the context of a preliminary turbine design by Solar Turbines, Inc. designated ATS 5. The initial target for the ATS 5 application was to allow rim operating temperatures in the 1350-1400 {degrees} F range. The life goal of the Dual-Alloy Disk was envisioned to maintain Solar`s standard turbine disk philosophy of 1000,000 hours.

In the fourth quarter of calendar year 1996, 15 days of combust boiler tests were performed, including 10 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of December in the task 5 effort to 57, increased to 65 as of the date of this Report, 1/27/97. This compares with a total of 63 test days needed to complete the task 5 test effort, and it completes the number of tests days required to meet the task 5 project plan. The key project objectives of the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Work in the next quarter will focus on even greater reductions in environmental emissions. Also tests are planned with coals other than the Eastern U.S. bituminous coals tested in this project. For example, it is planned to tests Indian coals …

The Ferrocyanide Safety Issue at the Hanford Site was officially resolved in December 1996. This paper summarizes the key activities that led to final resolution of this safety hazard, a process that began in 1990 after it and other safety concerns were identified for the underground high-level waste storage tanks at the Hanford Site. At the time little was known about ferrocyanide-nitrate/nitrite reactions and their potential to cause offsite releases of radioactivity. The ferrocyanide hazard was a perceived problem, but it took six years of intense studies and analyses of tank samples to prove that the problem no longer exists. The issue revolved around the fact that ferrocyanide and nitrate mixtures can be made to explode violently if concentrated, dry, and heated to temperatures of at least 250 {degrees}C. The studies conducted over the last six years have shown that the combined effects of temperature, radiation, and pH during 40 or more years of storage have destroyed almost all of the ferrocyanide originally added to tanks. This was shown in laboratory experiments using simulant wastes and confirmed by actual samples taken from the ferrocyanide tanks. The tank waste sludges are now too dilute to support a sustained exothermic reaction, even …

Radiological and toxicological consequences of spray leak accidents in Hanford liquid waste tank farm pits were previously estimated and reported in WHC-SD- WM-CN-048 Rev 1, Calculation Notes in Support of TWRS FSAR Spray Leak Accident Analysis (Hall 1996a) in support of the Tank Waste Remediation System (TWRS) Final Safety Analysis Report (FSAR). The present document contains revised analyses incorporating more realistic assumptions and accident models than the previous document. In addition, several refinements in the analysis models suggested during the review of WHC-SD-CN-048 were investigated. Refinements which proved to have a significant effect on the results were included in the present analysis.

The characteristics of seismic- derived porosity maps have been further qualified by geologic and production relationships not previously explained nor their significance recognized. Patterns of seismic- derived porosity in the upper Grayburg compare accurately to geologic well data and to historic oil production in section 36. Areas of economic reservoir seem to be separated hydrodynamically, based on the porosity distribution and related differences of gas- to- oil ratio values. Porosity values east of the current limit of the seismic inversion model (where the current seismic data quality is poor) have been estimated for the Grayburg zones, to be used in the next production model run. Production data for that area are being requested from offset operators. When those data become available, they will be included in a revised engineering model will be made to match the production history and to simulate the effect of waterflood efforts. The mapping of porosity of the upper Grayburg zones from the seismic data was completed during the third quarter of 1997, with further qualification of the results done during the fourth quarter. The cross- plots of well log- determined porosity versus seismic velocity have shown a strong linear relationship useful for calibrating the conversion …

In the fourth quarter of calendar year 1996, 15 days of combust-boiler tests were performed, including 10 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of December in the task 5 effort to 57, increased to 65 as of the date of this Report, 1/27/97. This compares with a total of 63 test days needed to complete the task 5 test effort, and it completes the number of tests days required to meet the task 5 project plan. The key project objectives of the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NOX emissions as low as 0.07 lb/MMBtu and S02 emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Work in the next quarter will focus on even greater reductions in environmental emissions. Also tests are planned with coals other than the Eastern US bituminous coals tested in this project. For example, it is planned to tests Indian coals whose ash concentration …

The Waste Encapsulation and Storage Facility (WESF) was constructed in 1974 to encapsulate and store cesium and strontium which were isolated at B Plant from underground storage tank waste. The WESF, Building 225-B, is attached physically to the west end of B Plant, Building 221-B, 200 East area. The WESF currently utilizes B Plant facilities for disposing liquid and solid waste streams. With the deactivation of B Plant, the WESF Decoupling Project will provide replacement systems allowing WESF to continue operations independently from B Plant. Four major systems have been identified to be replaced by the WESF Decoupling Project, including the following: Low Level Liquid Waste System, Solid Waste Handling System, Liquid Effluent Control System, and Deionized Water System.