Critical Dimensions of Untamped Conical Vessels (open access)

Critical Dimensions of Untamped Conical Vessels

Abstract: "The need often arises for determining the critical chemical concentration of uranium solution in the conical bottom of a plant reactor or storage vessel, or the dimension if the concentration is known. This report describes the mathematical analysis of Poisson's equation for a spherical sector, which approximates a right circular cone. The ratio of the critical dimension of an equivalent sphere to the height of the sector for various sector angles is derived from a comparison of first eigenvalues. No description of further relations between composition and dimensions is discussed in the report."
Date: August 25, 1947
Creator: Murray, Raymond
System: The UNT Digital Library
Iodine Exchange Reaction (open access)

Iodine Exchange Reaction

This report discusses an analysis on the exchange reaction between iodine and unipositive iodine with pyridine.
Date: August 25, 1948
Creator: Kleinberg, Jacob & Sattizahn, James
System: The UNT Digital Library
Vapor Traps for Handling Liquid Sodium (open access)

Vapor Traps for Handling Liquid Sodium

An active program is a present underway to develop equipment to handle liquid metals. Among the metals being studied are sodium and sodium--potassium alloy (the latter commonly referred to as NaK). In many of the systems being studied this liquid metal is pressurized by inert gas in the lines. At times it is necessary to bleed off some of this gas from the system. Although the gas is allowed to escape at a temperature at which the vapor pressure of sodium is extremely small, it has been found that excessive amounts of sodium are present in this gas stream. Either this sodium collects in the lead-off pipes from the system as a solid, threatening to block the passage in which it is found, or it passes out into the atmosphere. In order to explain the presence of such a dangerous concentration of sodium in the exit gas stream, it has been proposed that the sodium vapor present in the the system at high temperatures condenses into a mist or aerosol on cooling. This aerosol is stable and will not readily de-entrain or condense onto the surfaces over which it passes. Another possibility is that the oxygen present with the inert …
Date: August 25, 1951
Creator: Erickson, A. J.; Gregory, C. L. & Lang, P. M.
System: The UNT Digital Library
A Precise Potentiometric Titration Method for the Determination of Uranium (open access)

A Precise Potentiometric Titration Method for the Determination of Uranium

Abstract: "A precise potentiometric method for the determination of uranium in essentially pure uranium oxides is described. Ten gram samples of oxides are reduced in a Jones reductor and titrated potentiometrically to U+4, using platinum and tungsten electrodes. A weighed amount of solid Bureau of Standards potassium dichromate is then used to oxidize at least 99 percent of the uranous ion, and the oxidation is completed by titration with 0.01 N potassium dichromate using calomel and platinum electrodes. This method, which is based on a primary chemical standard, has a precision of +/- 0.015% on a single determination at the 95 percent confidence interval."
Date: August 25, 1953
Creator: Voss, F. S. & Greene, R. E.
System: The UNT Digital Library