The successful separation of pyrite from coal by flotation is dependent to a large extent upon the selectivity of the process, and the use of a pyrite depressant is one of the most important and cost-effective techniques for achieving this. This report evaluates the effects of three factors on the floatability of pyrite. These are (1) the superficial oxidation of pyrite, (2) the contamination of pyrite surfaces by carbonaceous matter, and (3) pulp redox potentials. XPS (x-ray photoelectron spectroscopy) and IR spectrometry have been used to identify surface reaction products. Microflotation, laboratory-scale conventional flotation and microbubble column flotation were used to quantify the effects of these factors. It was found that low (reducing) pulp potentials are effective depressants of pyrite (more so for fresh, unoxidized samples than for oxidized samples), whilst at the same time do not materially affect coal flotation.

Solid friction is considered by some to be a fundamental property of two contacting materials, while others consider it to be a property of the larger tribosystem in which the materials are contained. A set of sliding friction experiments were designed to investigate the hypothesis that the unlubricated sliding friction between two materials is indeed a tribosystems-related property and that the relative influence of the materials properties or those of the machine on friction varies from one situation to another. Three tribometers were used: a friction microprobe (FMP), a typical laboratory-scale reciprocating pin-on-flat device, and a heavy-duty commercial wear tester. The slider material was stainless steel (AISI 440C) and the flat specimen material was an ordered alloy of Ni{sub 3}Al (IC-50). Sphere-on-flat geometry was used at ambient conditions and at normal forces ranging from 0.01 N to 100 N and average sliding velocities of 0.01 to 100.0 mm/s. The nominal, steady-state sliding friction coefficient tended to decrease with increases in normal force for each of the three tribometers, and the steady state value of sliding friction tended to increase as the mass of the machine increased. The variation of the friction force during sliding was also a characteristic of the …

The Filter Compartment (FC) in this analysis is a generic reactor airborne activity confinement filter compartment which possesses all the essential physical and mechanical properties of the Savannah River Site (SRS) confinement filters of Reactor Buildings K, L, and P. The filters belong to the Airborne Activity Confinement System (AACS). These filters absorb a significant amount of radioactive effluents from the exhausting air. The seismic excitation is input indirectly from the output of the seismic analysis of the 105 exhaust stack building in the form of floor response spectra. However, the 105 exhaust stack building was analyzed for seismic motions defined by free-field ground response spectra with a ZPA (Zero Period Acceleration) of 0.2G for all three orthogonal components of ground motion and a shape consistent with USNRC Regulatory Guide 1.60. Based upon equivalent dynamic analysis of the FC, DuPont engineers suggested modifications on the existing FC with heavy I-section beams (1). The scope of this phase I'' analysis, as requested by Seismic Engineering (2), is to carry out a scoping analysis'' of Frequency Analysis and Response Spectrum Analysis of the FC with DuPont suggested conceptual modifications. Our suggestion was that the existing FC without conceptual modifications be analyzed first. …

To better understand the surface chemical properties of coal and mineral pyrite, studies on the effect of flotation surfactants (frother and kerosene) on the degree of hydrophobicity have been conducted. The presence of either frother or kerosene enhanced the flotability of coal and mineral pyrite with a corresponding decrease in induction time over the pH range examined. Scanning electron microscopy (SEM) results indicate a correlation exists between the sample surface morphology and crystal structure and the observed hydrophobicity. As a result of the data obtained from the surface characterization studies, controlled surface oxidation was investigated as a possible pyrite rejection scheme in microbubble column flotation.

We have made a first study of the calorimetric response to 10 GeV/c charged pions in the transition region between barrel and endcap for the scintillator-tile design pursued at Argonne National Laboratory using the simulation program ANLSIM. For (very nearly) projective tower orientations in the barrel, the crack appears deep within a narrow angular range, causing a loss of the response in that region up to 40%. Pointing the towers onto the beam axis 35 cm or more away from the nominal-interaction point leads to a shortened depth of the barrel-endcap crack as seen by particles incident from the interaction region, cutting the maximum loss down by almost one half. The worsening of the resolution follows the same trend. Introduction of a solenoidal coil in front of the calorimeter causes an overall degradation of the response by an amount nearly comparable to the effect of the crack. Electrons of the same incident momentum are more strongly affected by the coil than pions but see only a much narrower region of degradation by the crack. 15 refs., 6 figs., 2 tabs.

In the project status report for 4/9/90--7/8/90, Table 2 presented update results of a comparative study of coal sample deterioration in several container types including foil laminate bags. This table contained an erroneous entry (foil laminate bag {minus}20 mesh, alkali extraction 65.4% transmittance). The alkali extraction test on {minus}20 mesh coal stored in foil laminate bags for 52 weeks was repeated in duplicate on another bag (after 64 weeks total storage) resulting in a measurement of 96.2% transmittance. This value has been substituted for the erroneous 65.4% value in the corrected copy of Table 2 enclosed with this report. All values of the alkali extraction and Gieseler fluidity tests indicate that the state of preservation of sample in foil laminate bags is excellent. The samples stored by other methods for comparison purposes all showed significant loss in fluid characteristics. One new whole-seam channel sample of the hvAb Pittsburgh seam coal, DECS-12, was collected July 25, 1990 in Greene County, PA. This sample was placed in 30-gallon steel barrels with high-density lid gaskets and purged with argon at the mine. Upon return to Penn State it was promptly processed so that Gieseler fluidity and other routine analyses could be performed.

The holographic stressmeter is an instrument which has been developed at Caltech to allow determination of the complete stress tensor from in situ borehole measurements. The stressmeter uses double-exposure holographic interferometry to record the displacements induced by the drilling of a small sidehole into the borehole wall. The local stresses, which are the result of the far-field stresses, concentrated at the borehole, cause deformation of the surface of the borehole wall in the vicinity of the sidehole. The first part of this study uses a thin infinite elastic plate subjected to plane stress at infinity to model the displacements at the borehole wall. However, the existence of some holograms which were difficult to model closely led us to examine the validity of this model. In order to investigate the problem further, we performed a two-dimensional finite element analysis for an elastic box with a terminated hole. We varied the dimensions of the hole to see what effect the radius and depth of the hole might have on the displacements. The plate model predicts that the depth of the hole should have no effect on the horizontal components of displacement, but the finite element results show that the magnitude of both …

The overall objective of the Full-Scale Low-NOx Cell (LNC) Burner Retrofit project is to demonstrate the cost-effective reduction of NOx generated by a large, base-loaded (70% capacity factor or greater), coal-fired utility boiler. Specific objectives include: at least 50% NOx reduction over standard two-nozzle cell burners, without degradation of boiler performance or life; acquire and evaluate emission and boiler performance data before and after the retrofit to determine NOx reduction and impact on overall boiler performance; and demonstrate that the LNC burner retrofits are the most cost-effective alternative to emerging, or commercially- available NOx control technology for units equipped with cell burners. The focus of this demonstration is to determine maximum NOx reduction capabilities without adversely impacting plant performance, operation and maintenance.

This research project proposes to develop novel new approaches of improving the radioimmunodetection and radioimmunotherapy of malignancies by augmenting retention of radioimmunoconjugates by tumor cells. The approaches shown to be effective in these laboratory experiments will subsequently be incorporated into out ongoing clinical trials in patients. Specific project objectives include: to study the rates of endocytosis, intracellular routing, and metabolic degradation of radiolabeled monoclonal antibodies targeting tumor-associated antigens on human leukemia and lymphoma cells; To examine the effects of lysosomotropic amines (e.g. chloroquine, amantadine), carboxylic ionophores (monensin, nigericin), and thioamides (propylthiouracil), on the retention of radiolabeled MoAbs by tumor cells; to examine the impact of newer radioiodination techniques (tyramine cellobiose, paraiodobenzoyl) on the metabolic degradation of radioiodinated antibodies; to compare the endocytosis, intracellular routing, and degradation of radioimmunoconjugates prepared with different radionuclides ({sup 131}Iodine, {sup 111}Indium, {sup 90}Yttrium, {sup 99m}Technetium, {sup 186}Rhenium); and to examine the utility of radioimmunoconjugates targeting oncogene products for the radioimmunotherapy and radioimmunoscintigraphy of cancer.

One of the most difficult separations in minerals processing involves the differential flotation of pyrite and coal. Under practical flotation conditions, they are both hydrophobic and no cost-effective method has been developed to efficiently reject the pyrite. The problem arises from inherent floatability of coal and pyrite. Coal is naturally hydrophobic and remains so under practical flotation. Although pyrite is believed to be naturally hydrophilic under practical flotation conditions it undergoes a relatively rapid incipient oxidation reaction that causes self-induced'' flotation. The oxidation product responsible for self-induced'' flotation is believed to be a metal polysulfide, excess sulfur in the lattice, or in some cases elemental sulfur. It is believed that if incipient oxidation of pyrite could be prevented, good pyrite rejection could be obtained. In order to gain a better understanding of how pyrite oxidizes, a new method of preparing fresh, unoxidized pyrite surfaces and a new method of studying pyrite oxidation have been developed this reporting period.

The temperature profiles from a selection of TFTR L-mode discharges are simulated with the 1-1/2-D BALDUR transport code using a combination of theoretically derived transport models, called the Multi-Mode Model. The present version of the Multi-Mode Model consists of effective thermal diffusivities resulting from trapped electron modes and ion temperature gradient ({eta}{sub i}) modes, which dominate in the core of the plasma, together with resistive ballooning modes, which dominate in the periphery. Within the context of this transport model and the TFTR simulations reported here, the scaling of confinement with heating power comes from the temperature dependence of the {eta}{sub i} and trapped electron modes, while the scaling with current comes mostly from resistive ballooning modes. 24 refs., 16 figs., 3 tabs.

This report summarizes the International Conference on Fusion Reactor Materials (ICFRM-4) which was held December 4--9, 1989, in Kyoto, Japan, as well as the results of several workshops, planning meetings, and laboratory visits made by the travelers. The ICFRM-4 is the major forum to present and exchange information on materials research and development in support of the world's fusion development efforts. About 360 papers were presented by the 347 conference attendees. Highlights of the conference are presented. A proposal by the United States to host ICFRM-5 was accepted by the International Advisory Committee. ORNL will be the host laboratory. A meeting of the DOE/JAERI Annex I Steering Committee to review the US/Japan Collaborative Testing of First Wall and Blanket Structural Materials with Mixed Spectrum Fission Reactors was held at JAERI Headquarters on December 1. The Japanese emphasized the critical importance of a resumption of HFIR operation. Even though the HFIR outage has lasted three plus years this program has continued to provide new and important data on materials behavior which has particular relevance to ITER.

During the course of 9{degree} tapered side-bonding resistance upset weld development at Mound, various studies have been conducted to evaluate the effect of yield strength on welds in 304L stainless steel. The results of these studies have concluded that at high yield strengths there may be a minor reduction in the length of Class 2 or better bond. Satisfactory welds have been produced with materials having yield strengths ranging from 36.0 to 141.0 ksi. However, when body yield strengths exceed 80.0 ksi a minor decrease in bond lengths begins. A significant inverse relationship between stem yield strength and bond length was shown to exist. 8 refs., 9 figs., 10 tabs.

The long-range objective of this research program is the development of more efficacious technetium-99m radiopharmaceuticals for use as imaging agents in diagnostic nuclear medicine. We seek to isolate and develop distinct site imaging agents, each of which has properties optimized to provide diagnostic information concerning a given pathological condition. The specific objectives during the period (9/1/89 to 8/31/92) include: (1) Development of strategies for improving yields of specific Tc-diphosphonate complexes with optimum imaging properties; (2) Development of electrodes for rapid in situ electrochemical generation of skeletal imaging agents; (3) Development of electrochemical sensors for {Tc} and Re imaging agents; (4) Characterization of stable {Tc}- and Re-diphosphonate complexes obtainable in high yield by structural studies with techniques such as NMR, EXAFS, and Raman spectroscopy; (5) Development of improved separation techniques for the characterization of diphosphonate skeletal imaging agents; (6) Evaluation of the effect of the biological milieu on {Tc}-diphosphonate complexes; and (7) Electrochemical studies of technetium and rhenium complexes synthesized by Professor Deutsch's research group for heart and brain imaging.

Results from modeling of transformation toughening in brittle materials using a discrete micromechanical model are presented. The material is represented as a two-dimensional triangular array of nodes connected by elastic springs. Microstructural effects are included by varying the spring parameters for the bulk, grain boundaries, and transforming particles. Using the width of the damage zone and the effective compliance (after the initial creation of the damage zone) as measures of fracture toughness, we find that there is a strong dependence of toughness on the amount, size, and shape of the transforming particles, with the maximum toughness achieved with the higher amounts of the larger particles.

The two-hit resolution of a silicon drift chamber is measured using a pulsed Nd:Yag laser and a time digitizer readout. The data is analyzed by forming the covariance matrix in time samples, and transforming to a matrix in amplitude and time variation of each of the two hits. The resolution of the two-hit separation is found to be better than 25 microns with a drift field of 530 V/cm and a separation of more than 500 microns, with the resolution increasing to 50 microns as the separation nears 500 microns. Results are also presented for multiply ionizing tracks, showing a great improvement over single minimum ionizing. 8 refs.

I have investigated the effect of scattering in the rock overburden on the position and direction of atmospheric muons as observed at the Soudan 2 detector relative to the surface. The dominant contributions to the fluctuations in those observables arise from multiple Coulomb scattering and delta ray production. The contribution of the other energy loss mechanisms, bremsstrahlung, pair production and nuclear interactions, is small, with slowly increasing importance at very large deviations from the means of the distributions.

The purpose of this report is to evaluate the effect of near-field rock treatment by injection of reactive material (calcite) above the drift for the purpose of decreasing postclosure drift seepage. The method used for the calculation was a coupled reaction-transport numerical model for gas-water-rock interaction. This includes the mass conservation of heat, liquid and gas for thermohydrological calculations, of aqueous and gaseous species for advective and diffusive transport, and the kinetics of mineral-water reactions.

The experimental study of the water-rock interaction shows that the secondary mineral assemblage depends on the water composition. For example, granite-pure water interaction produces zeolites (relatively low-dense, Mg-poor minerals), whereas seawater yields chlorites (high-dense, Mg-rich minerals). The reactions have volumetric effects from several % to 20 % in magnitude. Volume deformations in the heterogeneous matrix cause uneven mechanical strains. Reactions with the effect of about 0,1 vol.% may cause strains of the order of 100-1000 bars being enough for destruction of rocks. Signs and magnitudes of local volume changes depend on the mineral composition of the secondary assemblage. Hence, one can provide either healing or cracking of primary fractures, as desired, by changing the composition of water in the water-felsic rock system where some elements (Mg, Fe) are in lack. The techniques of "chemical hydrofracturing" looks promising as applied to a granite HDR massif. One can regulate the permeability of fractured flow paths by changing in concord the composition and pressure of the injected water. This approach should promote efficient extraction of the petrothermal energy.

High surface electric fields have been obtained in the first tests of a superconducting rf quadrupole device. The rf quadrupole fields were generated between niobium vanes 6.5 cm in length, with an edge radius of 2 mm, and with a beam aperture of 6 mm diameter. In tests at 4.2 K, the 64 MHz device operated cw at peak surface electric fields of 128 MV/m. Virtually no electron loading was observed at fields below 100 MV/m. It was possible to operate at surface fields of 210 MV/m in pulses of 1 msec duration using a 2.5 kW rf source. For the vane geometry tested, more than 10 square centimeters of surface support a field greater than 90% of the peak field. The present result indicates that electric fields greater than 100 MV/m can be obtained over an appreciable area, sufficient for some accelerator applications. It also shows that superconducting rf technology may provide an extended range of options for rf quadrupole design. 7 refs., 4 figs.

Differential geometry provides a natural family of coordinate systems, the Frenet frame, in which to specify the geometric properties of magnet winding. By a modification of the Euler-Bernoulli thin rod model, the strain energy is defined with respect to this frame. Then it is minimized by a direct method from the calculus of variations. The mathematics, its implementation in a computer program, and some analysis of an SSC dipole by the program will be described. 16 refs.

The Nuclear Test and Experimental Science Program (NTES) has requested that the Laser Program design and price an upgrade to the Janus laser system (JANUS UPGRADE) capable of reliably delivering in excess of 200 joules per beamline in a range of pulse forms to three experiment areas. The facility is to have the following characteristics: three experiment areas, two high energy beams, each with 200--400 joule/1 ns at a wavelength of 1.053 or 1.064 microns, and 125--250 J/1 ns when frequency doubled, one probe beam (0.1 J rated at 30 ps) to be used for interferometry, and reliable operation. The proposed facility would occupy approximately 5600 ft{sup 2} and be located in the Bldg. 174 complex. A block diagram of the entire facility is shown in Fig. 1. The facility is further defined by the Work Breakdown Structure (also shown in Fig. 1). The main elements of the WBS are the conventional facility and modifications thereof (WBS 1), special equipment (WBS 2), the laser (WBS 3), the experiment areas (WBS 4), the controls and data acquisition system (WBS 5), and the project integration (WBS 6). The experiment area has three target chambers and uses diagnostic hardware now in Janus. 12 …

Recent studies of nuclear mass models show that it is essential to account for the Coulomb redistribution energy when calculating the nuclear potential energy in the heavy-element region. Results obtained by use of a mass model that includes Coulomb redistribution effects on analyzed. Q values of {alpha} and {beta} decay are calculated. Half-lives for {alpha} decay are estimated by use of the Viola-Seaborg systematics. For EC, {beta}{sup +} decay and {beta}{sup {minus}} decay, half-lives are calculated in a microscopic QRPA model. Calculated single-particle level structures in the heavy-element regions are presented. These indicate possible regions of isomers that would be unusually stable with respect to spontaneous fission and {alpha} decay. Finally, we discuss the implications of earlier extensive work on fission properties of nuclei in this region.

'With the increased sensitivity of waste-level measurements in the H-Area Tanks and with periods of isolation, when no mass transfer occurred for certain tanks, waste-level changes have been recorded with are unexplained.'