Work during this report period includes a continuation of the study of the effect of krypton 85 on the polymerization of styrene; an attempt at evaluation of the polymers produced; and the effect of krypton radiation on the electrical properties of gases, such as the rare gases, and nitrogen, and oxygen. the results obtained are summarized in the report.

The liquid metal level instrument will operate at tank temperatures up to 1000 F. Overall system accuracy depends on operating conditions, as described in the report. Test accuracies from 2 to 8% have been obtained from full to empty tank. The primary detector unit successfully passed navy HI shock test.

Equipoise-2, a two-dimensional, two-group neutron-diffusion code in R-Z geometry, has been programmed for the IBM-7090 computer. This code was designed to permit the running of large numbers of cases without requiring excessive machine time. Typical running times are of the order of one to three minutes per case for a 1000-point problems. The maximum number of mesh points that can be used is 1444.

The ORNL analog computer was used to simulate four widely different experiment conditions in the small EGCR in-pile loops. Various control and safety systems were evaluated in each case. Curves are included which show the response to postulated accidents and component failures. The results indicate that one standard control and safety system will probably be adequate for a wide variety of test conditions.

Departures from the usual precipitation method produced crystalline uranium peroxide in several forms. Three types of segregated needles were used in the preparation of three pellets for pellet-type elements. Densities of the pellets ranged from 93 to 97% of theoretical, depending on conditions of precipitation.

Tests were conducted to determine methods of removing scale deposits from the HRT heat exchangers. A mockup of the heat exchanger header was cleared of a deposit of iron rust by reverse flushing at a flow rate below 75 gpm. A tube bundle consisting of 109 1/4in. O.D. x 0.049 in. wall tubes was plugged with rust. Approximately 80% of these tubes were unplugged by using a 70 psi water pressure differential in combination with vibration from a pneumatic rivet gun. No mechanical method was employed in the tests which could clear the remaining tubes.

In connection with the program of the measurement of eta for U233, several critical experiments have been performed by R. Gwin and D. W. Magnuson of ORML with light water solutions of uranyl nitrate (highly enriched in either U233 or U35) in an essentially bare sphere 27 inches in diameter. This report presents the results of two multigroup-diffusion-theory calculations for the above experiments performed by C. B. Mills and associated at Los Alamos. Assumer cross sections, material concentrations detailed neutron balances and a comparison with elementary theory are included. The agreement between the calculated and experimental multiplication constants is excellent for the multigroup calculation but only fair for the elementary calculation. The latter method overestimates the fast leakage so that the computed multiplication constant is less than that found experimentally.

In an elastic collision the neutron loses part of its kinetic energy to the nucleus with both the kinetic and momentum of the system being conserved. However, for many elements the scattering is not isotropic in the center-of-mass system at the higher neutron energies. Many of the present reactor multigroup codes include anisotropic scattering at the high neutron energies, while many others assume isotropic scattering at all energies. In order to consider some of the effects of including anisotropic scatting, reference is made t the multigroup equation generally assumed for the slowing-down density.

The information concerning beryllium assembled herein has been selected primarily to provide information that might be pertinent to the design of the ART. The creep-rupture data in the literature have been obtained from vacuum cast and extruded beryllium, rather than from the hot-pressed beryllium which will be used in the ART. A research program is being conducted by the Brush Beryllium Company, under contract to the Oak Ridge National Laboratory, which will eventually provide the design engineers with data on the high temperature strength properties of hot-pressed beryllium. In the interim, it will be necessary for the metallurgists and design engineers to make judicious estimates and extrapolations from the data available.

This report is presented in order to provide a satisfactory system of symbols and identifications for process-instrumentation equipment and to promote a uniformity of practice that will simplify and expedite instrumentation work. It is intended that the systems presented here should be capable of designating and identifying the multitude of instrumentation items which are used for control and operation of conventional processes, as well as for specialized work peculiar to ORNL. Instrument Society of America standards have been adhered to whenever practical.

Short reports to the members of the Nuclear Cross Section Advisory Group from three groups: (1) High voltage group; (2) Fast chopper time-of flight spectrometer; and (3) Electronuclear research division.

In order to test the operation of a freeze jacket in air with the process fluid closely following the conditions found in the high pressure circulation loop of a homogeneous reactor, or, 2000 psi and 300C, a test loop was built and used in conjunction with existing refrigeration equipment. The freeze jacket was made of 5/16-in. type 346 stainless steel tubing wrapped around and welded to a 1/2-in. stainless steel process line. It was concluded that for these reactor operating conditions, only a small leak rate, 11 cc/min, could be frozen off. It is recommended that, at the beginning of the the freezing operation, the temperature of the secondary refrigerant entering the freeze jacket be at least -40C and that the freeze jacket be made as long as practical.

It is the purpose of this memo to clarify and revise burnup calculations for the APPR irradiation program and to present a proposed irradiation schedule. the report will also be in the nature of a review of the program.

This report covers the S-I-5-B-M fuel irradiation in the GETR Maritime Loop during the first quarter of fiscal year 1962. The data are summarized in Section II.

Experiments were carried out to determine the erosion, oxidation and dimensional characteristics of purposely defected fuel elements containing unsintered UO2 powder prepared by the swaging technique. The experiments were conducted in an out-of-reactor loop under superheat conditions of pressure, temperature, flow velocity and steam chemical composition.

A method for calculating the frequency response of weighted voids (proportional to reactivity of steam voids) as a function of reactor power is presented.

A partial bibliography of reports on the Fluorox moving-bed for producing UO3, UF4, and UF6 is given.

A fifth in-pile loop experiment, L-4-8, was completed. The loop operated in-pile for a total of 1637 hr, during which time the LITR energy output was 4377 Mwhr. The average fission power in the loop based o cesium analyses was 622 w when the LITR was at full power (3 Mw). Based on oxygen data, the generalized corrosion rate for the first 300 hr was 4.0 mpy; the rate for the remaining 1357 hr was 0.7 mpy. The nickel data gave parallel results. The corrosion of the type 347 stainless steel, Zircaloy-2, and Ti-55AX [unintelligible] exposed in the core and in in-line holders was generally consistent with that observed in previous in-pile loop experiments. Some differences with steel were attributed to the fact that this was the first loop containing steel specimens operated with 0.04 m H2SO4 present in the uranyl sulfate charge solution (0.17 m UO2SO4, 0.03 m CuSO4). Stress specimens, made from the alloys Zircaloy-2, type 17-4 PH stainless steel, and Ti-C-130-AM, were exposed in care, in-line, and pressurizer locations. Microscopic examination and average weight loss gave no indication of effects attributable to the stressed condition of the specimens.

Observations of the effects of neutron damage to zirconium oxides led to the conclusion that the cubic form of ZrO2 is more stable to such damage than the monoclinic form. It has been reported that zirconium corrodes more rapidly in certain liquids when exposure is made under radiation (neutrons and fission products). It is well known that on heating monoclinic ZrO2 a transformation, monoclinic to tetragonal (very similar to cubic), occurs at about 1500°C. The transformation involves sufficient atomic rearrangement that pieces of ZrO2 normally crack and crumble. It is suggested that the effects of neutrons on monoclinic ZrO2 may be similar so that a protective oxide film on the metal would be destroyed soon after its formation. It might be possible, therefore, that the protective oxide film on zirconium metal which is normally monoclinic might be less resistant to corrosion under radiation damage than a similar film which was cubic.

Consideration has been given to various forms of fissionable material for use in atomic reactors, including the pure metals, their alloys and compounds. Of particular interest is the dioxide of uranium which is refractory and corrosion resistant in some environments.The oxide is useful in both granular and bulk forms. Small grains of uranium oxide can be mixed with other materials to form matrix type elements where they serve either as a convenient or necessary form of fuel or fertile material. For other applications the oxide may be fabricated in bulk form such as pellets, rods, plates, or blocks.There is a need for knowledge of the properties of the properties of this oxide, particularly as it affects fabrication in the various forms required. This knowledge is also required by reactor designers and engineers. There is in addition a challenging field for basic studies of sintering rates, oxidation behavior and other phenomena. Fabrication techniques have been developed to produce uranium oxide in various forms with consideration given to the economy of production. The continued application of basic knowledge of these materials has led to simpler. more practical means of fabrication and has thus widened the scope of their use in atomic reactors.

A uniform intensity flat top spill-out cannot be obtained by manual control for two reasons: 1. The horizontal density of the internal beam of the Cosmotron is far from uniform. As a result, a manually controlled linear motion of the internal beam into a target will result in a non-uniform spill-out intensity. 2. Stability requirements of the Cosmotron magnet voltage are not easily met without feedback because of inherent component stability. The proposed servo system will sense the external beam intensity, and correct the magnet voltage to keep this intensity constant. This servo must operate through the transfer function of the main ignitron system and the flat top filter. Both of those transfer functions impose special problems.

The Hanford water treatment plants were operated for a number of years with alum as a coagulant and activated silica as a coagulant and a polyacrylamide as a filter conditioning agent. (other polyelectrolytes may be used.) Sufficient time has elapsed to make a comparison of the two methods of operation valid and useful. Such a comparison is the purpose of this paper.

The need for criticality control in the proposed reprocessing of slightly enriched non-production fuels at Hanford has led to the development of a geometrically "safe", vertical tube, recirculating dissolver. A study of the nitric acid dissolution of uranium dioxide in a pilot plant dissolver of this type is reported here. The study was pointed toward the comparison of uranium dioxide dissolution rates in a batch and a recirculating dissolver and the definition of hydraulic problems associated with the recirculation of nitric acid, by air lift, technique through beds of reacting uranium dioxide.

Summary of miscellaneous updates related to the project. This includes information on the following. Simplified equations for modeling reactor conditions. Solubility tests involving thorium, bismuth, and protactinium. various other measurements and tests involving thorium, uranium, protactinium, bismuth, aluminum, and various other salts.