Complex Systems of the Rare Earth Metals With Glycolate, Lactate, and α-Hydroxyisobutyrate Ligands (open access)

Complex Systems of the Rare Earth Metals With Glycolate, Lactate, and α-Hydroxyisobutyrate Ligands

From Abstract : "The solubilities of the individual rare earth lactates and α-hysroxyisobutyrates in water at 20 and 60° were determined for comparison with the rare earth glycolate solubilities determined earlier."
Date: February 21, 1963
Creator: Powell, J. E.; Karraker, R. H.; Kolat, R. S. & Farrell, J. L.
System: The UNT Digital Library
Transport Reactions of Some Vanadium (III) Halides (open access)

Transport Reactions of Some Vanadium (III) Halides

Technical report. From Abstract : "The reactions of VCl2. VCl3, and VCl3-VBr3 mixtures with bromine vapor at 350 to 450°C led to vaporization of the halides and deposition of mixed halides of vanadium (III) at lower temperatures."
Date: August 21, 1962
Creator: McCarley, Robert E.; Roddy, James W. & Berry, Keith O.
System: The UNT Digital Library
The Thallium-Indium Phase Diagram as a Function of Composition, Temperature, and Pressure (open access)

The Thallium-Indium Phase Diagram as a Function of Composition, Temperature, and Pressure

Technical report. From Abstract : "The thallium-rich region of the thallium-indium phase diagram was determined from atmospheric pressure to 5.5 kbars primary from electrical resistivity data obtained as a function of composition, temperature, and pressure."
Date: August 21, 1962
Creator: Meyerhoff, Robert Wagner & Smith, J. F.
System: The UNT Digital Library
Separation of Iron by Liquid-Liquid Column Extraction (open access)

Separation of Iron by Liquid-Liquid Column Extraction

From abstract: "Iron(III) can be separated from many elements by extraction from 6 to ͟8M hydrochloric acid. The extraction is carried out by passing the aqueous hydrochloric acid solution through a column packed with 2-octanone adsorbed onto a poly-fluorocarbon resin. Fluoride, phosphate, sulfate or citrate cause no interference. Traces if iron(III) can be separated quantitatively from large amounts of copper(II) or zinc(II); traces of titanium(IV) can be separated from large amounts of iron(III)."
Date: March 21, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Hedrick, C. E.
System: The UNT Digital Library
Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane (open access)

Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane

From abstract: "A study has been made of the yields of gaseous products labeled with C11 from the C12(γ, n) reaction in liquid cyclohexane. The effects of variations in the radiation dose and in the concentration of dissolved iodine during irradiation on the yields of these products were studied in order to elucidate the reaction mechanisms. A reaction model was developed as a method of assessing the relative importance of radical and molecular processes. The data suggest (1) that the formation of C11 labeled CH4, C2H4 + C2H6, and C3H6 involves a hot radical process while (2) the formation of C2H2 is by a molecular reaction with cyclohexane."
Date: March 21, 1962
Creator: Rack, Edward P. & Voigt, Adolf F.
System: The UNT Digital Library
αZ Correction to the Bethe-Maximon Pair Production Cross Section (open access)

αZ Correction to the Bethe-Maximon Pair Production Cross Section

From abstract: "The first order correction in αZ to the Bethe-Maximon pair production cross section is calculated for the case where the incident photon and one of the electrons has an energy much greater than mc2. Comparison of these calculations to the experimental data of Plimpton and Hammer shows an improvement ina greement between theory and experiment of approximately a factor of 1+(αZ4π/15) for low positron kinetic energies. However, for positron kinetic energies of the order of 1 Mev no improvement is obtained."
Date: March 21, 1962
Creator: Moroi, David S. & Hammer, C. L.
System: The UNT Digital Library
Electrical Properties of the Tungsten Bronzes (open access)

Electrical Properties of the Tungsten Bronzes

From abstract: "The electrical resistivity of NaxWO3, LixWO3, and KxWO3 has been measured at 300°K. The range of x-values was 0.25 < x < 0.9. All resistivities were characteristic of a metal and lie on a single curve. An extrapolation of the conductivity curve to zero conductivity indicated that the tungsten bronzes should be semiconductors for x < 0.25. The resistivities that have been measured for tungsten bronzes with x < 0.25 showed semiconducting behavior. The resistivity of LixWO3 exhibited an anomalous peak in the ρ vs Τ cuve. The Hall coefficient of Li0.37WO3 indicated one free electron per alkali atom as was previously found for NaxWO3. The Seebeck coefficient of NaxWO3 depended linearly on x[superscript]-2/3 as expected from free electron theory. The implications of these and some other data are discussed."
Date: March 21, 1962
Creator: Shanks, H. R.; Sidles, Paul Howard & Danielson, G. C.
System: The UNT Digital Library
Electronic Spectra of Catacondensed and Pericondensed Aromatic Hydrocarbons (open access)

Electronic Spectra of Catacondensed and Pericondensed Aromatic Hydrocarbons

From abstract: "The electronic spectra arising from the excitations of pi-electrons in homo-nuclear conjugated bond systems are calculated for 37 aromatic hydrocarbons. The theoretical approach used takes into account overlap effects between different a atoms, correlation between different electrons, variations in internuclear distances, and the influence of non-conjugated neighbors, hydrogen and carbon. Four types of approximations are carried trough for the molecules in order to obtain an estimate of the inadequacies of the theory. From the calculated transition energies and oscillator strengths, theoretical spectra are synthesized and compared with observed spectra. In order to help the interpretation, a decomposition of the transition dipoles into atomic contributions is introduced. The spectra of alternant molecules are succesfully predicted, but the limits of the underlying assumptions appear to be exceeded in the applications to non-alternant systems. The calculations are markedly successful for the peri-condensed systems, which had presented an obstacle to previous treatments. It is found that the calculated spectra are fairly sensitive to small variations in interatomic distances. calculations with exact atomic positions, where available, give considerably better agreement with experimental spectra. The calculations lead to an understanding of the general spectral pattern found in all aromatic hydrocarbons. On this basis the …
Date: June 21, 1962
Creator: Hummel, Richard L. & Ruedenberg, Klaus, 1920-
System: The UNT Digital Library
Vaporization reactions of vanadium(III) bromide : Dissociation and Disproportionation Equilibria, and the Formation of Vanadium (IV) Bromide (open access)

Vaporization reactions of vanadium(III) bromide : Dissociation and Disproportionation Equilibria, and the Formation of Vanadium (IV) Bromide

Technical report. From Abstract : "The equilibria (1) VBr3(s) = VBr2(s) + 1/2Br2(g) and (2) 2VBr3(s) = VBr2(s) + VBr4(g) were studied over the range 644 to 805°K by transpiration in helium."
Date: August 21, 1962
Creator: McCarley, Robert E. & Roddy, James W.
System: The UNT Digital Library
The Vapor Pressures of VCl2, VCl3, VBr2, and VBr3 by Knudsen Effusion (open access)

The Vapor Pressures of VCl2, VCl3, VBr2, and VBr3 by Knudsen Effusion

Technical report. From Abstract : "The vapor pressures of crystalline VCl2, VBr2, VCl3 and VBr3 have been measured by the Knudsen effusion method using pyrex and Vycor effusion cells. ... During the measurements on VCl3 and VBr3 dissociation and disproportionation of the samples occurred simultaneously with the simple vaporization. However, because the product of each of these processes was collected separately during an experiment, the vapor pressure due to sublimation was obtained without difficulty."
Date: August 21, 1962
Creator: McCarley, R. E. & Roddy, J. W.
System: The UNT Digital Library