Abstract. The rate constants for the reaction of the hydrated electron eaq with a number of solutes and with radicals formed in water radiolysis are reported. Hydrated electrons were formed in the electron pulse irradiated solutions at concentrations in the range from 1 to 10 pM. Their reaction was followed by the decay of the optical absorption of eaq at 5780 A. Generally a 04 psec pulse of 15 MeV electrons was used. In the absence of eaq scavengers, second-order kinetics prevailed owing to the dominance of the reactions,eaq+eaq, eaq+H, and eaq+H202 when OH radical scavengers were present in alkaline solution. An analysis of the decay curves leads to values for keaq+eaq and keaq+H of 0.9~ 1010 and 3 x 1010 M-1 sec-1, respectively. With scavenger present in excess over [eaq], pseudo first-order kinetics were found and rate constants for a number of inorganic and organic compounds are reported. The agreement of these and other rate constants with diffusion-controlled reaction theory is discussed.

Report issued by the U.S. National Bureau of Standards discussing piston gage pressure and reducing errors of measurement. Sources of error are described and evaluated in order to "reduce the magnitude of overall error of measurement" (p. 1). This report includes tables, and illustrations.

Report discussing pressure measurements made with piston gages that are affected by gravity, temperature, pressure, and several other variables. For accurate determinations of pressure the calculations must take these variables into account. A general equation is developed and simplified procedures for calculating pressure are illustrated.