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A new synthetic route for the preparation of [Os3(CO)10(μ-OH)(μ-H)] and its reaction with bis(diphenylphosphino)methane (dppm): syntheses and X-ray structures of two isomers of [Os3(CO)8(μ-OH)(μ-H)(μ-dppm)] and [Os3(CO)7(μ3-CO)(μ3-O)(μ-dppm)]
Article describes a convenient synthetic method for the preparation of the hydroxy-bridged triosmium cluster [Os₃(CO)₁₀(μ-OH)(μ-H)] along with the re-evaluation of the reaction of this cluster with dppm that has led to the isolation of a new isomer for [Os₃(CO)₈(μ-OH)(μ-H)(μ-dppm)].
Date:
December 17, 2020
Creator:
Richmond, Michael G.; Joy, Tuhinur R.; Bhoumik, Nikhil C.; Ghosh, Shishir & Kabir, Shariff E.
System:
The UNT Digital Library
Covalency in Fe2O3 and FeO: Consequences for XPS satellite intensity
Article examines the covalent character of the interaction between the metal cation and the oxygen ligands for two Fe oxides with different nominal oxidation states, Fe(II)O, and Fe(III)₂O₃.
Date:
November 17, 2020
Creator:
Bagus, Paul S.; Nelin, Connie J.; Brundle, C. R.; Crist, B. Vincent; Lahiri, N. & Rosso, Kevin M.
System:
The UNT Digital Library
Electrochemical sensor for selective tyramine determination, amplified by a molecularly imprinted polymer film
This article devised, fabricated, and tested a molecularly imprinted polymer (MIP) film based electrochemical sensor for selective determination of tyramine.
Date:
November 17, 2020
Creator:
Ayerdurai, Viknasvarri; Cieplak, Maciej; Noworyta, Krzysztof R.; Gajda, Marianna; Ziminska, Agnieszka; Sosnowska, Marta et al.
System:
The UNT Digital Library
Hole-punching for enhancing electrocatalytic activities of 2D graphene electrodes: Less is more
Article develops 2D carbon electrocatalysts based on graphene with and without punched holes and/or N-doping and performs a comprehensive combined experimental and theoretical study on the edge and surface electrocatalytic activities of single-layer 2D graphene sheets.
Date:
August 17, 2020
Creator:
Xia, Zhenhai; Gao, Yunxiang; Zhang, Lipeng; Li, Chang Ming & Dai, Liming
System:
The UNT Digital Library
Computational Study of Methane C–H Activation by Main Group and Mixed Main Group–Transition Metal Complexes
This article presents density functional theory (DFT) research where nine different molecules, each with different combinations of A (triel) and E (divalent metal) elements, were reacted to effect methane C–H activation.
Date:
May 26, 2020
Creator:
Carter, Carly C. & Cundari, Thomas R., 1964-
System:
The UNT Digital Library