"An account is given of an extensive study of the A-2 Compiler System for the Remington Rand Univac digital computer. In particular, the following topics are discussed: application and performance of subroutines, segmenting, and introduction of subroutines to the library."

A sequential method is described for the determination of strontium- 89, strontium-90, barium-140, and tungsten185 in rain water samples. A comparison is made of data on radioactivity in individual rain samples and in monthly pot samples. Data are included on the total strontiuro-90 fall-out collected in steep walled stainless steel pots during the period. Results are compared with cumulative data for 1958 end 1959. (C.H.)

Sixty-two references, some annotated, were taken from foreign literature to determine the status of work done in this area of metallurgy during 1958 and 1959. The references are grouped into two categories: references pertinent to the subject and general metallurgical references on metallic fuels.

The potential to kinetic energy conversion process in the lower stratosphere is evaluated using adiabatically derived vertical velocities for the North American region for a five-day period. Preliminary results suggest the possibility that on the average the kinetic energy of stratospheric motions may not result from a conversion of potential energy within the stratosphere. The further implication is that stratospheric motions are mechanically driven by the motions in the adjacent layers of the atmosphere.

The progress report covers the work carried out during the first year 1958-59 in the department of metallurgy at M.I.T. under the supervision of Professors John T. Norton and Robert E. Ogilvie. A brief summary of the work that has been completed and in some cases still continuing is given. The work has been listed under the following general headings: (1) Diffusion studies in the uranium-niobium system, (2) X-ray detection of cladding defects, (3) Precision X-ray stress analysis of uranium and zirconium, (4) Magnetic studies of Fe3O3 single crystals, (5) Crystal structure studies of yttrium compounds, (6) Structural relationships in ZrFe2-ZrCr2 system.

The kinetics of transformation of zirconium binary alloys is being pursued. Mechanical property variation as a function of transformation if also being investigated. Zirconium-tin and zirconium-titanium alloys transform very rapidly when quenched from the beta field. These alloys have, generally speaking, been demonstrated to be not amenable to heat treatment in the normal sense of the word. Eutectoid alloys, principally zirconium-molybdenum alloys, have shown a definite response to heat treatment in terms of mechanical property variation. An embrittling agent, probably "omega" phase, is suspect at this time for the brittleness observed in certain molybdenum alloys and the very high hardness levels reached in other alloys such as zirconium-niobium and zirconium-thorium. Work to establish the existence of omega phase is in progress and, it is hoped, suggestions for avoiding the brittle condition associated with it will be forthcoming.

This technical report represents a brief survey of work by this project on the effects of ultraviolet radiation (UV) on certain of the photochemical and metabolic properties of rhubarb chard and sugar beet (Beta vulgaris). These plants were selected for this work because for some years they have been used as sources of chloroplasts for Hill reaction studies in this laboratory. Some of this work has appeared as a brief paper.

This is the seventeenth quarterly report on our echelle project, as numbered above. Our work this quarter has to some extent been directed towards the Spectroscopy Symposium held at Argonne National Laboratory on February 15, 16, and 17. This report consists principally of brief abstracts of the two papers given at this meeting. Progress since the last quarterly report included completion of the echelle comparator calibration, and the successful production and photographing of the desired spectra of praseodymium and erbium in strong magnetic fields. Considerable interest was aroused by these papers, not only because rare earth spectra are being analyzed, but because of the general applicability of our experimental techniques in producing the spectra.

The problem of a blast wave propagating through an inhomogeneous atmosphere is set up for computation by the CRC LORA. Previous treatments of this problem have used various simplifying assumptions such as that of purely radial flow. Since, however, pressure gradients in this situation will not in general be in the direction of rays from the blast center, non-radial flow will exist, and there is reason to believe that for large distances this effect will play a prominent role. Therefore, a program was set up for the numerical calculation (on the CRCLORA) of the propagation of a blast wave from a ground burse with altitude effects and possible tangential flow taken into account. With initial conditions known, the program is designed to give the pressure, density, radial and tangential flow velocities after successive time intervals at 16 equally spaced positions on each of 16 straight rays emanating from the point of burst. These positions are shifted with time to keep up with the shock front. Rehmeyer's and Van Neumann's method is used to handle the discontinuous shock front. In this method an artificial viscosity term is introduced in the the equations of motion in order to smooth out the discontinuity, …

A membrane demineralizer has been tested in a pressurized loop. The loop water resistivity was maintained in the 1-2 megohm range by ionized solid transfer in the demineralizer. The size and power requirement of the unit tested per gpm flow through the unit, were 2.3 cu ft and 100 watts. In view of the fact that present designed could reduce the size and required maintenance, further studies may be warranted.

Preliminary experiments have been conducted to evaluate the use of the nuclear reactions Li6 (n,α)H3 and O16(H13,n)F18 to determine the thickness of oxide films on metals. Sheets of thin paper and of aluminum, imbedded in powdered LiF, were irradiated with pile neutrons at a flux of 6 x 10^11 n/cm^2/sec and counted with an end-window proportional counter. A saturation activity of 1.87 hr F18 of 150 dis/min per microgram of oxygen was observed in the paper, but radioactivity due to impurities masked F18 in the aluminum. It is concluded that a 1 A (0.01 μgm/cm^2) oxide film thickness may be measured by a neutron irradiation at a flux of 10^14 n/cm^2/sec but chemical separation of induced radioactivity from the bulk metal is essential.

The "absolute" containment of ions in the DCX magnetic mirror field resulting from the cylindrical symmetry of the field is discussed. The regions of confinement in space and momentum are plotted for 300 Kev deuterons.

Experiments in the controlled melting of irradiated fuel specimens, particularly of the APPR, STR, and MTR types have confirmed that prolonged heating in air at temperatures in excess of the melting point results in the release of a large portion of the radioactivity. On the other hand, a moderate amount of heating in air or steam sufficient only to melt a specimen results mainly in the partial volatilization of the rare gases; the halogens, iodine and bromine; and the alkali metals, cesium and rubidium. In the presence of air or water vapor, strontium and other fission products are not released. At trace concentration of fission products, slow melting of the APPR plate at 1525 C in air or steam effected the release of 50 percent of the rare gases, 33 percent of the iodine, 9 percent of the cesium and traces of strontium. After 25% burn-up, the cesium value increased to about 60 percent. Aluminum alloy of the MTR type, also at trace concentration, upon melting at 700 C released up to 2 percent of the iodine, 10 percent of the rare gases, and negligible portions of other fission products. Zirconium alloy of the STR type after 15 percent burn …

It has been reported in the literature that prolonged soaking of 16 wt & uranium-aluminum alloys at elevated temperatures induces a microstructural changed termed "conglobulation". this process is essentially a spheroidization of the UAl4 eutectic. Conclusions of the tests: (1) Extended soaking of 48 wt $ uranium-aluminum alloy billets at 600 C does not improve their hot-rolling characteristics. (2) Soaking periods of 50 hours and greater reduce the tensile and yield strengths of these alloys. (3) Soaking for 50 hours results in complete spheroidization of the eutectic in 48 wt % uranium-aluminum alloys.

A six-inch diameter "O" ring from the HRT Mockup was examined metallographically after 2452 hours exposure to uranyl sulfate solution at 300C. surface defects, except for cold work defects were found only in areas exposed to uranyl sulfates. Defects found were pits, transgranular cracks, surface cracks, and grain attacks.

A design and economic analysis is presented for a 44,000 DWT tanker utilizing a 27,300 shp direct cycle boiling water reactor propulsion system. Included are design descriptions and drawings, estimates of operating and capitol costs for the reference ship, estimates of long range potential, descriptions of required research and development programs, a preliminary safeguards analysis, an analysis of ship's motion on boiling water reactor performance, a summary reactor physics analysis, and a discussion of direct cycle accessibility considerations. Also included are summary descriptions for various design alternatives which were considered.

Methods for analyzing chemical impurities in sodium metal samples are presented. Chemical analysis was used to determine the following impurities: Calcium, Carbon, Chromium, Iron, Lithium, Nickel, Oxygen, Potassium, and Zirconium. Spectrographic analysis was used to determine many other impurities. Sodium samples obtained from experimental apparatus operated as part of the work being conducted for Atomics International were analyzed by these methods.

Three edge loaded thoria-urania nuclear fuel samples were assembled into a capsule, irradiated and examined. This irradiation was the first of a series to develop thoria-urania fuel for high heat flux, specific power and burn-up operation in a sodium graphite reactor.

Experimental test loops have been used to study the problem of hydraulic stability. The oscillatory behavior of a single-phase and two-phase natural circulation loop has been examined at atmospheric pressures and oscillating modes of operation were studied in terms of heat input.

An ion exchange testing program was completed on Gunnar acid leach liquors and pulps. A standard column system and a resin-in-pulp system, both using anion exchange resins, were investigated. The Gunnar leach liquors are readily amenable to the recovery of uranium by ion exchange.

A series of leaching, thickening, and filtration tests was undertaken to determine minimum conditions for high uranium extractions and to obtain thickening and filtration data.

In the course of recovering uranium from Rand cyanide residues, large volumes of barren acid liquors are produced. With the flowsheets now under consideration it is not advisable to recycle such liquors and they are to be discarded. Consideration was given to the removal of manganese under conditions that would permit its recovery as MnO2.

A new method to procure RaLa sources was proposed by Group CMR-10, Los Alamos Scientific Laboratory. This method depended upon irradiation of small-diameter U235 wire in the Materials Testing Reactor, Arco, Idaho. A procedure for cladding and sealing U235 wire in stainless steel tubing, by drawing, plugging the tube ends, and welding, was developed, tested, and proved to be satisfactory.

In some recent experiments the ion density in a plasma was measured as a function of radial distance from a d-c arc source of ions for the magnetic field intensities from 2500 to 14000 oersted. The diffusion coefficient appeared to very inversely as the square of the magnetic field strength, D~1/H2. The absolute value of D was shown to be approximately that which would be predicted by the collision diffusion theory when account is taken of the shorting effect of the end walls. The purpose of this report is to continue the examination of ion diffusion in a plasma and field experimentally the relation between the diffusion coefficient and the neutral gas pressure for a constant magnetic field.