Serial/Series Title

Hydrocarbon and nonhydrocarbon derivatives of cyclopropane (open access)

Hydrocarbon and nonhydrocarbon derivatives of cyclopropane

The methods used to prepare and purify 19 hydrocarbon derivatives of cyclopropane are discussed. Of these hydrocarbons, 13 were synthesized for the first time. In addition to the hydrocarbons, six cyclopropylcarbinols, five alkyl cyclopropyl ketones, three cyclopropyl chlorides, and one cyclopropanedicarboxylate were prepared as synthesis intermediates. The melting points, boiling points, refractive indices, densities, and, in some instances, heats of combustion of both the hydrocarbon and nonhydrocarbon derivatives of cyclopropane were determined. These data and the infrared spectrum of each of the 34 cyclopropane compounds are presented in this report. The infrared absorption bands characteristic of the cyclopropyl ring are discussed, and some observations are made on the contribution of the cyclopropyl ring to the molecular refractions of cyclopropane compounds.
Date: August 15, 1952
Creator: Slabey, Vernon A.; Wise, Paul H. & Gibbons, Louis C.
System: The UNT Digital Library
A unified two-dimensional approach to the calculation of three-dimensional hypersonic flows, with application to bodies of revolution (open access)

A unified two-dimensional approach to the calculation of three-dimensional hypersonic flows, with application to bodies of revolution

A procedure for calculating three-dimensional steady and nonsteady supersonic flows with the method of characteristics is developed and discussed. An approximate method is deduced from the characteristics method and shown to be of practical value at high supersonic speeds.
Date: August 15, 1952
Creator: Eggers, A. J., Jr. & Savin, Raymond C.
System: The UNT Digital Library