Quarterly technical report including reports on chemistry of source, fissionable, and structural elements, nuclear chemistry, radio-organic chemistry, chemistry of separations processes, chemical physics, radiation chemistry, and instrumentation of the Chemistry Division of the Oak Ridge National Laboratory (ORNL). [From Abstract]

The general solution to the basic differential equation d^4w/dy^4 +4w= -4f(y) is transformed from the primary form treated in most texts to an alternate form in which each integration constant corresponds to one edge condition at y=0. The relationships between the integration constants of the two forms are derived and the values for the transformed functions are tabulated. The particular solution is derived in general and given in unique form for various functional forms of f(y). Matrix notation is used throughout the derivations; however, a knowledge of matrix theory is not need for application of the results.

Equilibrium krypton and xenon adsorption isotherms were obtained for four varieties of charcoal and for Linde Molecular Sieves Types 4A and 5A, generally at 0, 25, and 60°c. Such data are of interest in connection with design and evaluation of adsorbers for radioactive noble gas fission products. The isotherms were fitted, by linear regression analysis, to straight-line forms of the Freundlich and Langmuir equations. The Freundlich linear equation gave the better fit and the parameters of this equation are presented for each of the isotherms. Also presented are the constants for an equation representing the temperature dependence of arbitrary adsorption coefficients, the coefficients having been calculated from the Freundlich isotherm parameters. Some aspects of the applicability and accuracy of these results are discussed.