Thesis. Lithium fluoride crystals, with TlF added to the charge, were prepared by the Bridgman- Stockbarger method. The scintillation response to photon energies between 25 and 1250 keV for these crystals and a commercially prepared LiF (Ti) crystal was studied. The response of the LiF (Ti) crystal was compared to the response of an NE109 scintillator at 1250 keV. The dose response of the LiF (Ti) crystal was evaluated over the energy range 25 to 1250 keV. The absorption and emission spectra of the LiF (Ti) crystal are discussed. A historical review precedes the discussion. (auth)