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Advanced, Soluble Hydroliquefaction and Hydrotreating Catalysts Annual Report: 1990-1991 (open access)

Advanced, Soluble Hydroliquefaction and Hydrotreating Catalysts Annual Report: 1990-1991

The purpose of the present program is to develop soluble analogs of surface confined catalysts that can be impregnated directly into the coal structure at low temperatures. This approach should avoid problems related to surface area dependence, a two phase (surface-liquid) reaction system and, mass transport limitations. Heteropolyanions (HPAs) offer the opportunity to develop soluble forms of surface confined catalysts. HPAs are multi-functional catalysts that could be used to promote both hydroliquefaction and hydrotreating. In theory, these functions could be employed sequentially or simultaneously and could permit exceptional control of liquefaction reactions and reaction conditions. Thus, the current research program involves efforts to evaluate HPAs as soluble liquefaction nd hydrotreating catalysts, with the goal of developing soluble analogs of surface confined catalysts.
Date: September 9, 1991
Creator: Laine, Richard M & Stoebe, Thomas
System: The UNT Digital Library
Advanced, soluble hydroliquefaction and hydrotreating catalysts. Annual report No. 1, August 7, 1990--August 6, 1991 (open access)

Advanced, soluble hydroliquefaction and hydrotreating catalysts. Annual report No. 1, August 7, 1990--August 6, 1991

The purpose of the present program is to develop soluble analogs of surface confined catalysts that can be impregnated directly into the coal structure at low temperatures. This approach should avoid problems related to surface area dependence, a two phase (surface-liquid) reaction system and, mass transport limitations. Heteropolyanions (HPAs) offer the opportunity to develop soluble forms of surface confined catalysts. HPAs are multi-functional catalysts that could be used to promote both hydroliquefaction and hydrotreating. In theory, these functions could be employed sequentially or simultaneously and could permit exceptional control of liquefaction reactions and reaction conditions. Thus, the current research program involves efforts to evaluate HPAs as soluble liquefaction nd hydrotreating catalysts, with the goal of developing soluble analogs of surface confined catalysts.
Date: September 9, 1991
Creator: Laine, R. M & Stoebe, T.
System: The UNT Digital Library
AISI direct steelmaking program (open access)

AISI direct steelmaking program

AISI with co-funding from DOE has initiated a research and development program aimed at the development of a new process for direct steelmaking, and the program is discussed in this document. The project is expected to cost about $30 million over a three-year period, with the government providing approximately 77 percent of the funds and AISI the balance. In contrast to current steelmaking processes which are largely open and batch, the direct steelmaking process would be closed and continuous. Further, it would use coal directly, thereby avoiding the need for coke ovens. The second year of the Direct Steelmaking Program (November 29, 1989, through November 28, 1990) was a year of significant accomplishment. The various research programs proceeded essentially on schedule and the pilot plant, the centerpiece of the program, was completed about three months behind schedule but began operation in almost a picture-perfect manner. This report presents the last years accomplishments.
Date: January 9, 1991
Creator: Aukrust, E.
System: The UNT Digital Library
Characterization of Rocket Propellant Combustion Products (open access)

Characterization of Rocket Propellant Combustion Products

The overall objective of the work described in this report is four-fold: to (a) develop a standardized and experimentally validated approach to the sampling and chemical and physical characterization of the exhaust products of scaled-down rocket launch motors fired under experimentally controlled conditions at the Army's Signature Characterization Facility (ASCF) at Redstone Arsenal in Huntsville, Alabama; (b) determine the composition of the exhaust produces; (c) assess the accuracy of a selected existing computer model for predicting the composition of major and minor chemical species; (d) recommended alternations to both the sampling and analysis strategy and the computer model in order to achieve greater congruence between chemical measurements and computer prediction. 34 refs., 2 figs., 35 tabs.
Date: December 9, 1991
Creator: Jenkins, R. A.; Nestor, C. W.; Thompson, C. V.; Gayle, T. M.; Ma, C. Y.; Tomkins, B. A. et al.
System: The UNT Digital Library
Characterization of rocket propellant combustion products. Chemical characterization and computer modeling of the exhaust products from four propellant formulations: Final report, September 23, 1987--April 1, 1990 (open access)

Characterization of rocket propellant combustion products. Chemical characterization and computer modeling of the exhaust products from four propellant formulations: Final report, September 23, 1987--April 1, 1990

The overall objective of the work described in this report is four-fold: to (a) develop a standardized and experimentally validated approach to the sampling and chemical and physical characterization of the exhaust products of scaled-down rocket launch motors fired under experimentally controlled conditions at the Army`s Signature Characterization Facility (ASCF) at Redstone Arsenal in Huntsville, Alabama; (b) determine the composition of the exhaust produces; (c) assess the accuracy of a selected existing computer model for predicting the composition of major and minor chemical species; (d) recommended alternations to both the sampling and analysis strategy and the computer model in order to achieve greater congruence between chemical measurements and computer prediction. 34 refs., 2 figs., 35 tabs.
Date: December 9, 1991
Creator: Jenkins, R. A.; Nestor, C. W.; Thompson, C. V.; Gayle, T. M.; Ma, C. Y.; Tomkins, B. A. et al.
System: The UNT Digital Library
D0 Cryogenic Controls I/O Base Power Distribution (open access)

D0 Cryogenic Controls I/O Base Power Distribution

The D0 cryogenic control system has 3 I/O bases and 1 25 amp 24vdc power supply. Each I/O base uses both 120 vac and 24 vdc. There are as many as 14 modules in each base, depending on what type of module it may require ac or dc. Then there are as many as 32 devices (instrumentation) per module. There is a power distribution network that provides power to this system. It was configured so that no conductors, devices, or components could carry or receive more current or voltage than they could safely handle. This is done to protect both personel and components from fire, heat, and electric shock.
Date: March 9, 1991
Creator: Markley, D.
System: The UNT Digital Library
D0 Cryogenic Controls Uninterruptible Power System Installatino and Operation Details (open access)

D0 Cryogenic Controls Uninterruptible Power System Installatino and Operation Details

None
Date: March 9, 1991
Creator: Markley, D.
System: The UNT Digital Library
Direct oxide reduction demonstration, small-scale studies (open access)

Direct oxide reduction demonstration, small-scale studies

This project was initiated to provide process design information to the Plutonium Recovery Project (PRP). Although direct oxide reduction (DOR) has been operated in a production mode both at the Rocky Flats Plant (now operated by EG&G, Inc.) and Los Alamos National Laboratory, many aspects of the process are ill-defined. Because the PRP plans include significant DOR capability, a well-defined process should minimize capital cost and maximize productivity. Reduced radiation exposure may also be realized. A detailed, statistically valid investigation of the direct oxide reduction process was carried out utilizing 100 grams or less of plutonium dioxide per experiment. Conditions were established for obtaining 95% + yields. Conclusions drawn from the results of the experimental work were utilized to make recommendations for future large-scale investigative and confirmative work as well large-scale production demonstration work. 4 refs., 5 figs., 14 tabs.
Date: December 9, 1991
Creator: Long, J. L.; Santi, D. J.; Fisher, D. C. & Humiston, T. J.
System: The UNT Digital Library
Direct oxide reduction demonstration, small-scale studies (open access)

Direct oxide reduction demonstration, small-scale studies

This project was initiated to provide process design information to the Plutonium Recovery Project (PRP). Although direct oxide reduction (DOR) has been operated in a production mode both at the Rocky Flats Plant (now operated by EG G, Inc.) and Los Alamos National Laboratory, many aspects of the process are ill-defined. Because the PRP plans include significant DOR capability, a well-defined process should minimize capital cost and maximize productivity. Reduced radiation exposure may also be realized. A detailed, statistically valid investigation of the direct oxide reduction process was carried out utilizing 100 grams or less of plutonium dioxide per experiment. Conditions were established for obtaining 95% + yields. Conclusions drawn from the results of the experimental work were utilized to make recommendations for future large-scale investigative and confirmative work as well large-scale production demonstration work. 4 refs., 5 figs., 14 tabs.
Date: December 9, 1991
Creator: Long, J. L.; Santi, D. J.; Fisher, D. C. & Humiston, T. J.
System: The UNT Digital Library
Evaluation of potential surface rupture and review of current seismic hazards program at the Los Alamos National Laboratory. Final report (open access)

Evaluation of potential surface rupture and review of current seismic hazards program at the Los Alamos National Laboratory. Final report

This report summarizes the authors review and evaluation of the existing seismic hazards program at Los Alamos National Laboratory (LANL). The report recommends that the original program be augmented with a probabilistic analysis of seismic hazards involving assignment of weighted probabilities of occurrence to all potential sources. This approach yields a more realistic evaluation of the likelihood of large earthquake occurrence particularly in regions where seismic sources may have recurrent intervals of several thousand years or more. The report reviews the locations and geomorphic expressions of identified fault lines along with the known displacements of these faults and last know occurrence of seismic activity. Faults are mapped and categorized into by their potential for actual movement. Based on geologic site characterization, recommendations are made for increased seismic monitoring; age-dating studies of faults and geomorphic features; increased use of remote sensing and aerial photography for surface mapping of faults; the development of a landslide susceptibility map; and to develop seismic design standards for all existing and proposed facilities at LANL.
Date: December 9, 1991
Creator: unknown
System: The UNT Digital Library
Full scale demonstration of low-NO sub x cell burner retrofit (open access)

Full scale demonstration of low-NO sub x cell burner retrofit

The overall objective of the Full-Scale Demonstration of Low-NO{sub x} Cell Burner Retrofit project is to demonstrate the cost-effective reduction of NO{sub x} generated by a large based-loaded (70% capacity factor or greater), coal-fired utility boiler. Specific objectives include: (1) At least 50% NO{sub x} reduction over standard two-nozzle cell burners, without degradation of boiler performance or life; (2) Acquire and evaluate emission and boiler performance data before and after the retrofit to determine NO{sub x} reduction and impact on overall boiler performance; (3) Demonstrate that the retrofit of Low-NO{sub x} Cell Burners in boilers currently equipped with cell burners, is a cost-effective alternative to any other emerging, or commercially-available, NO{sub x} control technology.
Date: August 9, 1991
Creator: unknown
System: The UNT Digital Library
Full scale demonstration of low-NO{sub x} cell burner retrofit. Public design report (open access)

Full scale demonstration of low-NO{sub x} cell burner retrofit. Public design report

The overall objective of the Full-Scale Demonstration of Low-NO{sub x} Cell Burner Retrofit project is to demonstrate the cost-effective reduction of NO{sub x} generated by a large based-loaded (70% capacity factor or greater), coal-fired utility boiler. Specific objectives include: (1) At least 50% NO{sub x} reduction over standard two-nozzle cell burners, without degradation of boiler performance or life; (2) Acquire and evaluate emission and boiler performance data before and after the retrofit to determine NO{sub x} reduction and impact on overall boiler performance; (3) Demonstrate that the retrofit of Low-NO{sub x} Cell Burners in boilers currently equipped with cell burners, is a cost-effective alternative to any other emerging, or commercially-available, NO{sub x} control technology.
Date: August 9, 1991
Creator: unknown
System: The UNT Digital Library
Herbert Easterly auxiliary truck heater (open access)

Herbert Easterly auxiliary truck heater

The objective of this work was to continue the development of the Herbert Easterly heater apparatus for vehicles, such as semi-trailer tractors in order to fully establish its technical feasibility and provide the basis for its commercialization. This heater is auxiliary to the vehicle's primary heating system. With the engine off it heats both the vehicle engine to a temperature at which it starts easily and the vehicle passenger compartment. Specifically, this heater is automatically ignitable, operates directly from the vehicle diesel fuel supply and preheats the vehicle engine fuel prior to combustion. During the course of this work nine different versions of prototype heaters were designed, constructed and tested. All designs were based on the ideas and principles outlined in the Easterly patent. Each successive version incorporated design and fabrication improvements relative to the previous version. The final version, Prototype 9, utilized a multiple water jacket design to capture additional heat from the combustion gases prior to exhausting to the atmosphere. This final prototype exceeded the performance of a commercially available Webasto DBW-2010 using the same commercial burner as the one used in the Webasto unit. The time required to raise the heater fluid temperature by 120{degree}F was 23% …
Date: December 9, 1991
Creator: unknown
System: The UNT Digital Library
Herbert Easterly auxiliary truck heater. Final technical report (open access)

Herbert Easterly auxiliary truck heater. Final technical report

The objective of this work was to continue the development of the Herbert Easterly heater apparatus for vehicles, such as semi-trailer tractors in order to fully establish its technical feasibility and provide the basis for its commercialization. This heater is auxiliary to the vehicle`s primary heating system. With the engine off it heats both the vehicle engine to a temperature at which it starts easily and the vehicle passenger compartment. Specifically, this heater is automatically ignitable, operates directly from the vehicle diesel fuel supply and preheats the vehicle engine fuel prior to combustion. During the course of this work nine different versions of prototype heaters were designed, constructed and tested. All designs were based on the ideas and principles outlined in the Easterly patent. Each successive version incorporated design and fabrication improvements relative to the previous version. The final version, Prototype 9, utilized a multiple water jacket design to capture additional heat from the combustion gases prior to exhausting to the atmosphere. This final prototype exceeded the performance of a commercially available Webasto DBW-2010 using the same commercial burner as the one used in the Webasto unit. The time required to raise the heater fluid temperature by 120{degree}F was 23% …
Date: December 9, 1991
Creator: unknown
System: The UNT Digital Library
Marketing research for EE G Mound Applied Technologies' heat treatment process of high strength materials (open access)

Marketing research for EE G Mound Applied Technologies' heat treatment process of high strength materials

This report summarizes research conducted by ITI to evaluate the commercialization potential of EG G Mound Applied Technologies' heat treatment process of high strength materials. The remainder of the report describes the nature of demand for maraging steel, extent of demand, competitors, environmental trends, technology life cycle, industry structure, and conclusion. (JL)
Date: October 9, 1991
Creator: Shackson, R.H.
System: The UNT Digital Library
Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae (open access)

Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae

This department of energy-sponsored mission-oriented research project currently has three emphases. They are: (1) determining the kinetics of monohydroxybiphenyl (OH-BP) production in batch culture by N1-36, an unidentified soil isolate, when the organism is presented with dibenzothiophene (DBT) or dibenzosulfone (DBTO{sub 2}); (2) establishing reliable methods for physically characterizing R68.45, a broad host range plasmid; and (3) attempting to elicit a physiologically consistent and genetically stable ability of some gram negative soil isolates to convert DBT to o,o{prime}-biphenol. Eachh of these goals has subsidiary components. For example, in addition to establishing kinetics of formation of OH-BP by N1-36, analyses have been or will be performed to determine whether the catalytic activity can be achieved with irradiated cells, spheroplasts, and cell extracts. This report presents information on progress towards fulfilling both the principal goals listed above and some relevant ancillary activities.
Date: November 9, 1991
Creator: Krawiec, S.
System: The UNT Digital Library
Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae. Ninth quarterly report, [July--October 1991] (open access)

Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae. Ninth quarterly report, [July--October 1991]

This department of energy-sponsored mission-oriented research project currently has three emphases. They are: (1) determining the kinetics of monohydroxybiphenyl (OH-BP) production in batch culture by N1-36, an unidentified soil isolate, when the organism is presented with dibenzothiophene (DBT) or dibenzosulfone (DBTO{sub 2}); (2) establishing reliable methods for physically characterizing R68.45, a broad host range plasmid; and (3) attempting to elicit a physiologically consistent and genetically stable ability of some gram negative soil isolates to convert DBT to o,o{prime}-biphenol. Eachh of these goals has subsidiary components. For example, in addition to establishing kinetics of formation of OH-BP by N1-36, analyses have been or will be performed to determine whether the catalytic activity can be achieved with irradiated cells, spheroplasts, and cell extracts. This report presents information on progress towards fulfilling both the principal goals listed above and some relevant ancillary activities.
Date: November 9, 1991
Creator: Krawiec, S.
System: The UNT Digital Library
Petroleum Marketing Monthly, January 1991. [Contains Glossary] (open access)

Petroleum Marketing Monthly, January 1991. [Contains Glossary]

The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 55 tabs.
Date: January 9, 1991
Creator: unknown
System: The UNT Digital Library
PHYSLIB: A C++ tensor class library (open access)

PHYSLIB: A C++ tensor class library

C++ is the first object-oriented programming language which produces sufficiently efficient code for consideration in computation-intensive physics and engineering applications. In addition, the increasing availability of massively parallel architectures requires novel programming techniques which may prove to be relatively easy to implement in C++. For these reasons, Division 1541 at Sandia National Laboratories is devoting considerable resources to the development of C++ libraries. This document describes the first of these libraries to be released, PHYSLIB, which defines classes representing Cartesian vectors and (second-order) tensors. This library consists of the header file physlib.h, the inline code file physlib.inl, and the source file physlib.C. The library is applicable to both three-dimensional and two-dimensional problems; the user selects the 2-D version of the library by defining the symbol TWO D in the header file physlib.h and recompiling physlib.C and his own code. Alternately, system managers may wish to provide duplicate header and object modules of each dimensionality. This code was produced under the auspices of Sandia National Laboratories, a federally-funded research center administered for the United States Department of Energy on a non-profit basis by AT T. This code is available to US citizens, and institutions under research, government use and/or commercial license …
Date: October 9, 1991
Creator: Budge, K.G.
System: The UNT Digital Library