Abstract: Technical report describing an evaluation of solvents for use in the extraction of uranium from Mallinckrodt type ore feeds.

Technical report evaluating solvents for use in the extraction of uranium from Mallinckrodt type ore feeds. Re-evaluates the Mallinckrodt process in the light of the more recent solvent extraction development that has been carried out at various AEC sites.

Technical report outlining the effect of strain rate on the tensile properties of thorium. It has been found that the yield strength increases slightly with increasing strain rate, and that tensile strength increases but to a less extent. Studies on the fabrication of thorium by extrusion and drawing have continued, as have studies on the extrusion cladding of thorium and uranium with zirconium. [From Summary}

This quarterly progress report details the ongoing research and experiments at the Oak Ridge National Laboratory as part of the Aircraft Nuclear Propulsion Project. The first part of this report discusses reactor theory and design. The second part of this report is not included. The third part of this report discusses materials research. The fourth part of this report includes appendixes

This quarterly progress details the ongoing work of the Protective Equipment Evaluation Program at the Oak Ridge National Laboratory. Topics discussed include aerosol generation, penetration studies, particle size measurement, and an appendix with analytical methods.

The reactor equipment cell is expected to be completed by February 15. While filled with water, the tank was inspected for leaks, and the few leaks found will have been repaired by February 15. All orders for construction materials placed prior to this quarter have been received. New requisitions issued during the quarter total $16,000. Work orders were issued, and fabrication of all low-pressure-system components was begun in the ORNL shops. The thermal shield around the reactor vessel was specified as a 2-ft-thick cylindrical concrete wall. With this shield, the fast-neutron flux in the equipment area will be reduced to 7 x 109 neutrons/cm2/sec, the slow flux to 4 x 107 neutrons/cm2/sec, and the gamma intensity to less than 105 r/hr. The possible blast effects from a rupture of the pressure vessel were studied and are judged to be sufficient to justify the inclusion of a 1.5. to 2-in.-thick blast shield around the pressure vessel. The blast shield eliminates the danger of damaging the leak tight equipment-cell liner. Pressures in the reactor equipment cell, as a result of vessel failure, were calculated in order to arrive at a safe design pressure for the reactor equipment cell. For the case of …

The development of ionic methods for the determination of corrosion products in the highly radioactive Homogeneous Reactor (HR) fuels has been of major interest in the work of the Ionic Analyses Laboratory. Methods for the spectrophotometric determination of aluminum and for the polarographic determination of iron in HR fuels have been developed. The polarographic determination of molybdenum in uranyl sulfate solutions was studied. A polarographic method for the determination of zinc was developed. A fluorometric method for the determination of microgram amounts of fluoride was studied. Three organic reagents were investigated as precipitants for microgram quantities of zirconium in HR fuel. The automatic photometric titration technique was applied to the determination of thorium and of sulfate. A method was developed for the ionexchange separation and potentiometric titration of cobalt. The ultraviolet absorption spectra of technetium and rhenium were studied.

In the HRP Welding program, a major part of the welding and fabrication, and some of the testing, is performed using an inert atmosphere. the use of the inert gas consumable arc welding process and dry box welding or other work in a dry box comes within this category. Since much of the work in the project make use of, or requires, inert atmospheres, a general discussion follows of the methods used, description of equipment, processes, quality of atmospheres, purity requirements, kinetics of metal-gas reactions, and the proper application of the equipment and methods use din obtaining the desired results.

A study was made of a method for the flame photometric determination of iron. In Part I of this report, the flame emission spectrum of iron, measured by means of a Beckman Model DU spectrophotometer with a flame attachment, is compated to that measured with an ORNL high-sensitivity, recording, single-beam instrument, in order to determine which instrument is best suited for this application. Although it was found that the Beckman product has the higher resolving power over the wavelength region of 360 to 400mu, it does no posses the sensitivity or ease of operation of the ORNL instrument. On this basis, the ORNL flame spectrophotometer is used in subsequent tests. After selecting the best-suited instrument for the flame photometric determination of iron, it was necessary to establish the optimum operating conditions for this particular method. These conditions are described in Part II.

Preliminary measurements of the corrosion of titanium were made in 13 M HNO3-0.05 M fluoride using 0.1 M H3BO3 as a liquid and vapor phase complexing agent. Titanium Ax-55 was attacked at average rates of 0.58 and 0.33 mils/month in the liquid and vapor. In dissolver solutions containing 0.5 and 1.0 M titanium, all rates were less than 0.1 mils/month.

The solution of the monoenergetic Boltzmann equation in an infinite homogeneous, nonmultiplying medium with linearly anisotropic scattering and an isotropic plane source is given and compared with the corresponding solution for isotropic scattering. The effective source strength for the asymptotic flux turns out to be the same as that for isotropic scattering to first order in Σa/Σ.

Programming research in the construction of a translator to Oracle language from ALGOL.

Report documenting ongoing research and developments at the Oak Ridge National Laboratory's Gas-Cooled Reactor Project.

Report describing the progress made in the Clinch River Study for the period May to October 1961. This report is based off of multiple reports of water sampling conducted across six stations in order to evaluate the safety and radioactive content of the Clinch River.

Report containing ongoing research and experiments of the Oak Ridge National Laboratory's Instrumentation and Controls Division.