Cation Exchange Separation of Divalent Metal Ions From Rare Earths (open access)

Cation Exchange Separation of Divalent Metal Ions From Rare Earths

From abstract: "The divalent metal ions of calcium, magnesium, nickel, and strontium are eluted from a cation exchange column with 1.5M nitric acid and separated from trivalent rare earths, aluminum and yttrium. Prior sequential elution of other metal ions with hydrochloric acid in acetone-water or with dilute hydrofluoric acid does not interfere with the present separation method."
Date: June 6, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Garralda, Barbara B.
System: The UNT Digital Library
Acid-Base Equilibria in Tertiary Butyl Alcohol (open access)

Acid-Base Equilibria in Tertiary Butyl Alcohol

From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric measurements at a glass electrode, and conductance values of dissociation constants. A method was developed for the evaluation of the over-all dissociation constant of weak acids using potentiometric data for hydrogen ion activities and conductance data for the corresponding anion activities. Over-all dissociation constants are reported for perchloric acid, picric acid, 2,4-dinitrophenol, and benzoic acid. Apparent dissociation constants from potentiometric measurements at a constant ionic strength were determined for hydrobromic, nitric, hydrochloric, picric, and p-toluenesulfonic acids."
Date: August 6, 1962
Creator: Marple, Leland & Fritz, James S. (James Sherwood), 1924-
System: The UNT Digital Library
Gas-Cooled Reactor Project Quarterly Progress Report: December 1961 (open access)

Gas-Cooled Reactor Project Quarterly Progress Report: December 1961

Report documenting ongoing research and developments at the Oak Ridge National Laboratory's Gas-Cooled Reactor Project.
Date: April 6, 1962
Creator: Oak Ridge National Laboratory
System: The UNT Digital Library
Diffusion of Iron, Cobalt, and Nickel in Gold, Report No. 5 (open access)

Diffusion of Iron, Cobalt, and Nickel in Gold, Report No. 5

"The diffusivities of Fe, Co, and Al in otherwise pure Au were determined by a residual activity technique. It was found that the frequency factors and activation energies of the transition elements into Au are normal relative to the values for Au self-diffusion, and suggest that lattice diffusion is operative, in contrast to the corresponding situation for the diffusion of these elements in Al. This difference in behavior is explained in terms of the marked difference in solid solubilities in the two series."
Date: June 6, 1962
Creator: Duhl, David N.; Hirano, Ken-ichi & Cohen, Morris
System: The UNT Digital Library
Diffusion in Cobalt-Nickel Alloys, Report No. 4 (open access)

Diffusion in Cobalt-Nickel Alloys, Report No. 4

The self-diffusivities of Co60 and Ni63 in cobalt--nickel solid solutions exhibit a greater activation energy below the Curie temperature (T/sub c/) than above. Values of DELTA Q = Q (ferromagnetic) -- Q (paramagnetic) are approximately equal to RT/sub c/. This observation is interpreted to indicate that the increment in activation energy arises from an increase in the formation energy of a vacancy in the ferromagnetic lattice, with the additional binding energy arising from the interaction of a spin with the Weiss field."
Date: June 6, 1962
Creator: Hirano, Ken-ichi; Agarwala, R. P.; Averbach, B. L. & Cohen, Morris
System: The UNT Digital Library