Activation and micropore structure determination of activated carbon-fiber composites (open access)

Activation and micropore structure determination of activated carbon-fiber composites

Rigid, high surface area activated carbon fiber composites have been produced with high permeabilities for environmental applications in gas and water purification. These novel monolithic adsorbents can be produced in single pieces to a given size and shape. The project involves a collaboration between the Oak Ridge National Laboratory (ORNL) and the Center for Applied Energy Research (CAER), University of Kentucky. The carbon fiber composites are produced at the ORNL and activated at the CAER using different methods, with the aims of producing a uniform degree of activation, and of closely controlling pore structure and adsorptive properties. The main focus of the present work has been to find a satisfactory means to uniformly activate large samples of carbon fiber composites and produce controlled pore structures. Several environmental applications have been explored for the activated carbon fiber composites. One of these was to evaluate the activated composites for the separation of CH{sub 4}-CO{sub 2} mixtures, and an apparatus was constructed specifically for this purpose. The composites were further evaluated in the cyclic recovery of volatile organics. The activated carbon fiber composites have also been tested for possible water treatment applications by studying the adsorption of sodium pentachlorophenolate, PCP.
Date: September 5, 1997
Creator: Jagtoyen, M.; Derbyshire, F. & Kimber, G.
Object Type: Report
System: The UNT Digital Library
Adak Island, Alaska, Microearthquake survey: Preliminary Hypocenter Determinations (open access)

Adak Island, Alaska, Microearthquake survey: Preliminary Hypocenter Determinations

Microearthquakes, defined as shocks having magnitudes less than 4, are commonly recorded in the vicinity of geothermal manifestations and volcanism. They have been mapped from producing geothermal fields as well as those not yet developed, in such places as Iceland, El Salvador, Japan, Kenya and the US. Microearthquakes have been recorded at several geothermal sites in the Imperial Valley and Coso Hot Springs, California; Kilbourne Hole, New Mexico; Yellowstone National Park, Wyoming; and The Geysers, California, where there is debate over whether or not the seismicity is induced by steam production. Seismicity occurs around active volcanoes, but appears reduced directly over zones of high temperature or magma, where the depth of the brittle fracture zone is shallow, as over Yellowstone caldera. In areas of active hydrothermalism, regional stress is likely to be relieved by low-level seismicity rather than occasional large ruptures, owing to the high temperatures, presence of fluids, and crustal weakening due to alteration and fracturing. Active faulting maintains the permeability of the system, which in its absence, might otherwise seal. on the microscopic scale, pore-fluid pressures rise as a result of heating, resulting in the decrease of effective pressure at the pore-mineral boundary. When this effective pressure becomes …
Date: November 5, 1982
Creator: Lange, Arthur L. & Avramenko, Walter
Object Type: Report
System: The UNT Digital Library

Adaptation of subsurface microbial communities to mercury

This report gives information about the Adaptation of subsurface microbial communities to mercury.
Date: April 5, 2006
Creator: Sorensen, Soren J.
Object Type: Presentation
System: The UNT Digital Library
ADAPTING A CERTIFIED SHIPPING PACKAGE FOR STORAGE APPLICATIONS (open access)

ADAPTING A CERTIFIED SHIPPING PACKAGE FOR STORAGE APPLICATIONS

For years shipping packages have been used to store radioactive materials at many DOE sites. Recently, the K-Area Material Storage facility at the Savannah River Site became interested in and approved the Model 9977 Shipping Package for use as a storage package. In order to allow the 9977 to be stored in the facility, there were a number of evaluations and modifications that were required. There were additional suggested modifications to improve the performance of the package as a storage container that were discussed but not incorporated in the design that is currently in use. This paper will discuss the design being utilized for shipping and storage, suggested modifications that have improved the storage configuration but were not used, as well as modifications that have merit for future adaptations for both the 9977 and for other shipping packages to be used as storage packages.
Date: June 5, 2012
Creator: Loftin, B. & Abramczyk, G.
Object Type: Article
System: The UNT Digital Library
Adapting high-resolution speckle imaging to moving targets and platforms (open access)

Adapting high-resolution speckle imaging to moving targets and platforms

High-resolution surveillance imaging with apertures greater than a few inches over horizontal or slant paths at optical or infrared wavelengths will typically be limited by atmospheric aberrations. With static targets and static platforms, we have previously demonstrated near-diffraction limited imaging of various targets including personnel and vehicles over horizontal and slant paths ranging from less than a kilometer to many tens of kilometers using adaptations to bispectral speckle imaging techniques. Nominally, these image processing methods require the target to be static with respect to its background during the data acquisition since multiple frames are required. To obtain a sufficient number of frames and also to allow the atmosphere to decorrelate between frames, data acquisition times on the order of one second are needed. Modifications to the original imaging algorithm will be needed to deal with situations where there is relative target to background motion. In this paper, we present an extension of these imaging techniques to accommodate mobile platforms and moving targets.
Date: February 5, 2004
Creator: Carrano, C J & Brase, J M
Object Type: Article
System: The UNT Digital Library
Addendum 3 to CSAR 80-027, Use of calorimeter 109B for fissile material measurement (open access)

Addendum 3 to CSAR 80-027, Use of calorimeter 109B for fissile material measurement

This modification to the Plutonium Finishing Plant (PFP) calorimeter system involves removing current calorimeter No. 3 from the water bath and replacing it with a calorimeter that can accommodate larger diameter items (an oversize can). The inside diameters of both the sample and the reference cells will be increased to 5.835 inches at the top opening and to 5.22 inches at the bottom, the 8 inch high measurement zone. This Addendum 3 to Criticality Safety Analysis Report 80-027 examines criticality safety during the use of the modified calorimeter (Calorimeter 109B) with enlarged cell tube diameters to assure that an adequate margin of subcriticality is maintained for all normal and contingency conditions.
Date: December 5, 1994
Creator: Chiao, T.
Object Type: Report
System: The UNT Digital Library
Addressing Problems with Scene-Based Wave Front Sensing (open access)

Addressing Problems with Scene-Based Wave Front Sensing

Scene-Based Wave Front Sensing uses the correlation between successive subimages to determine phase aberrations which blur digital images. Adaptive Optics technology uses deformable mirrors to correct for these phase aberrations and make the images clearer. The correlation between temporal subimages gives tip-tilt information. If these images do not have identical image content, tip-tilt estimations may be incorrect. Motion detection is necessary to help avoid errors initiated by dynamic subimage content. In this document, I will discuss why edge detection fails as a motion detection method on low resolution images and how thresholding the normalized variance of individual pixels is successful for motion detection.
Date: August 5, 2003
Creator: Chan, C
Object Type: Report
System: The UNT Digital Library
Adjustable Shock Test Sled for Haversine Pulses at 250 fps (open access)

Adjustable Shock Test Sled for Haversine Pulses at 250 fps

New test requirements were developed by Sandia National Laboratory to simulate a regime of shock testing not previously performed at the Kansas City Plant operated by Honeywell Federal Manufacturing & Technologies. These environments were unique in that they involved amplitude of shock >1000g with relatively long pulse durations (greater 5 ms but less than 10 ms) and involved velocity changes up to 235 ft/sec. Ten months were available to develop, design, manufacture and prove-in this new capability. We designed a new shock sled to deliver this new family of shock environments in a laboratory test. The performance range of the new sled includes five specific shocks (1000 g – 8 ms, 1300 - 6 ms, 1500 g – 5.4 ms, 1950 g – 6 ms, 2250 g – 5.4 ms; all haversine shaped), and it also incorporates adjustability to accommodate new shocks within this range. These shock environments result in velocity changes ranging from 160 fps to 250 fps. The test sled accommodates test articles weighing up to 20 lbs and measuring up to 10” along any axis.
Date: May 5, 2008
Creator: Hartwig, Troy; Hower, Brent & Seaholm, Aaron
Object Type: Article
System: The UNT Digital Library
Adsorption and desorption of sulfur dioxide on novel adsorbents for flue gas desulfurization. Final report, September 1, 1994--February 29, 1996 (open access)

Adsorption and desorption of sulfur dioxide on novel adsorbents for flue gas desulfurization. Final report, September 1, 1994--February 29, 1996

A sol-gel granulation method was developed to prepare spherical {gamma}-alumina granular supports and supported CuO granular sorbents for flue gas desulfurization. The prepared {gamma}-alumina supported CuO sorbents exhibit desirable pore structure and excellent mechanical properties. The sorbents contain higher loading (30-40 wt. %) of CuO dispersed in the monolayer or sub-monolayer form, giving rise to a larger SO{sub 2} sorption capacity ({gt}20 wt.%) and a faster sorption rate as compared to similar sorbents reported in the literature. With these excellent sulfation and mechanical properties, the sol-gel derived {gamma}-alumina supported CuO granular sorbents offer great potential for use in the dry, regenerative flue gas desulfurization process. Research efforts were also made to prepare DAY zeolite supported sorbents with various CuO contents by the microwave and conventional thermal dispersion methods at different conditions. Monolayer or sub-monolayer coating of Cu(NO{sub 3})sub 2 or CuO was achieved on several DAY supported sorbents by the microwave heating method but not by the conventional thermal dispersion method. The DAY zeolite supported CuO sorbents prepared by the microwave heating method can adsorb up to 15 wt.% of SO{sub 2}. The results obtained have demonstrated the feasibility of effective preparation of zeolite supported CuO sorbents by the microwave …
Date: August 5, 1996
Creator: Lin, Y.S. & Deng, S.G.
Object Type: Report
System: The UNT Digital Library
The Advanced Chemistry Basins Project: Final Report (open access)

The Advanced Chemistry Basins Project: Final Report

In the next decades, oil exploration by majors and independents will increasingly be in remote, inaccessible areas, or in areas where there has been extensive shallow exploration but deeper exploration potential may remain; areas where the collection of data is expensive, difficult, or even impossible, and where the most efficient use of existing data can drive the economics of the target. The ability to read hydrocarbon chemistry in terms of subsurface migration processes by relating it to the evolution of the basin and fluid migration is perhaps the single technological capability that could most improve our ability to explore effectively because it would allow us to use a vast store of existing or easily collected chemical data to determine the major migration pathways in a basin and to determine if there is deep exploration potential. To this end a the DOE funded a joint effort between California Institute of Technology, Cornell University, and GeoGroup Inc. to assemble a representative set of maturity and maturation kinetic models and develop an advanced basin model able to predict the chemistry of hydrocarbons in a basin from this input data. The four year project is now completed and has produced set of public domain …
Date: April 5, 2004
Creator: Goddard, William; Meulbroek, Peter; Tang, Yongchun & Cathles, Lawrence, III
Object Type: Report
System: The UNT Digital Library
Advanced Combustion (open access)

Advanced Combustion

Topics covered in this presentation include: the continued importance of coal; related materials challenges; combining oxy-combustion & A-USC steam; and casting large superalloy turbine components.
Date: March 5, 2013
Creator: Holcomb, Gordon R.
Object Type: Article
System: The UNT Digital Library
Advanced Electric and Magnetic Material Models for FDTD Electromagnetic Codes (open access)

Advanced Electric and Magnetic Material Models for FDTD Electromagnetic Codes

The modeling of dielectric and magnetic materials in the time domain is required for pulse power applications, pulsed induction accelerators, and advanced transmission lines. For example, most induction accelerator modules require the use of magnetic materials to provide adequate Volt-sec during the acceleration pulse. These models require hysteresis and saturation to simulate the saturation wavefront in a multipulse environment. In high voltage transmission line applications such as shock or soliton lines the dielectric is operating in a highly nonlinear regime, which require nonlinear models. Simple 1-D models are developed for fast parameterization of transmission line structures. In the case of nonlinear dielectrics, a simple analytic model describing the permittivity in terms of electric field is used in a 3-D finite difference time domain code (FDTD). In the case of magnetic materials, both rate independent and rate dependent Hodgdon magnetic material models have been implemented into 3-D FDTD codes and 1-D codes.
Date: May 5, 2005
Creator: Poole, B. R.; Nelson, S. D. & Langdon, S.
Object Type: Article
System: The UNT Digital Library
Advanced Gasification Mercury/Trace Metal Control with Monolith Traps (open access)

Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-μg/m{sup 3} (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-μg/m{sup 3} (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic …
Date: October 5, 2010
Creator: Musich, Mark; Swanson, Michael; Dunham, Grant & Stanislowski, Joshua
Object Type: Report
System: The UNT Digital Library
Advanced hardware and software methods for thread and gear dimensional metrology. CRADA final report (open access)

Advanced hardware and software methods for thread and gear dimensional metrology. CRADA final report

The Oak Ridge Centers for Manufacturing Technology (ORCMT) and Apeiron Incorporated have collaborated on an effort to develop a frequency modulated continuous wave (FMCW) fiber lidar system for dimensional metrology of internal threads, gears, and splines. The purpose of this effort was to assist a small company in developing an instrument that would exceed the performance of competing foreign instruments and provide measurement capabilities necessary to assure compliance for NASA facilities and other industrial facilities. The two parties collaborated on design, assembly, and bench testing of the prototype instrument. The prototype system was targeted to have the capability of profiling internally machined gears and threads to an accuracy of less than a micron.
Date: March 5, 1997
Creator: Miller, A. C., Jr. & Grann, E. B.
Object Type: Report
System: The UNT Digital Library
Advanced Large Area Plastic Scintillator Project (ALPS): Final Report (open access)

Advanced Large Area Plastic Scintillator Project (ALPS): Final Report

The advanced Large-Area Plastic Scintillator (ALPS) Project at Pacific Northwest National Laboratory investigated possible technological avenues for substantially advancing the state-of-the-art in gamma-ray detection via large-area plastic scintillators. The three predominant themes of these investigations comprised the following: * Maximizing light collection efficiency from a single large-area sheet of plastic scintillator, and optimizing hardware event trigger definition to retain detection efficiency while exploiting the power of coincidence to suppress single-PMT "dark current" background; * Utilizing anti-Compton vetoing and supplementary spectral information from a co-located secondary, or "Back" detector, to both (1) minimize Compton background in the low-energy portion of the "Front" scintillator's pulse-height spectrum, and (2) sharpen the statistical accuracy of the front detector's low-energy response prediction as impelmented in suitable energy-windowing algorithms; and * Investigating alternative materials to enhance the intrinsic gamma-ray detection efficiency of plastic-based sensors.
Date: February 5, 2008
Creator: Jordan, David V.; Reeder, Paul L.; Todd, Lindsay C.; Warren, Glen A.; McCormick, Kathleen R.; Stephens, Daniel L. et al.
Object Type: Report
System: The UNT Digital Library
Advanced power conversion based on the Aerocapacitor{trademark}. Final report (open access)

Advanced power conversion based on the Aerocapacitor{trademark}. Final report

This report summarizes work performed under contract No. DE-FC07-94ID13283, {open_quotes}Advanced Power Conversion Based on the Aerocapacitors{trademark}.{close_quotes} Under this contract high power density, high energy density, organic electrolyte Aerocapacitors{trademark} were developed and characterized for power conversion applications. Pilot facilities for manufacturing prototype AA-size Aerocapacitors{trademark} were put in place. The low ESR and good frequency response of these devices show that they are ideal components for high discharge rate and low to moderate frequency (< 10 kHz) applications such as power conversion.
Date: March 5, 1997
Creator: Roark, D.
Object Type: Report
System: The UNT Digital Library
Advanced process research and development to enhance metals and materials recycling. (open access)

Advanced process research and development to enhance metals and materials recycling.

Innovative, cost-effective technologies that have a positive life-cycle environmental impact and yield marketable products are needed to meet the challenges of the recycling industry. Four materials-recovery technologies that are being developed at Argonne National Laboratory in cooperation with industrial partners are described in this paper: (1) dezincing of galvanized steel scrap; (2) material recovery from auto-shredder residue; (3) high-value-plastics recovery from obsolete appliances; and (4) aluminum salt cake recycling. These technologies are expected to be applicable to the production of low-cost, high-quality raw materials from a wide range of waste streams.
Date: December 5, 1997
Creator: Daniels, E. J.
Object Type: Article
System: The UNT Digital Library
Advanced Processing of CdTe- and CuIn{sub x}Ga{sub 1{minus}x}Se{sub 2}-Based Solar Cells; Phase I Report (open access)

Advanced Processing of CdTe- and CuIn{sub x}Ga{sub 1{minus}x}Se{sub 2}-Based Solar Cells; Phase I Report

The main tasks of the cadmium telluride portion of this project include the development of simplified processing for fabricating high-efficiency CdTe solar cells, studies on the long-term stability of CdTe devices, and the development of alternative transparent conducting oxides, window layers, and back contacts. The second portion of this project focused on CIGS solar cells. The main tasks include the development of a manufacturable process for CIGS devices and the development of high-band-gap alloys for use in tandem cell structures. Additional objectives include development of improved junction formation processing and contributing to the overall understanding of these materials and devices. Because the processing is manufacturing-driven, the authors use an all solid-state, simplified two-step process that relaxes the level of deposition control required.
Date: September 5, 2000
Creator: Morel, D. L. & Ferekides, C. S.
Object Type: Report
System: The UNT Digital Library
Advanced Resources for Catalysis Science; Recommendations for a National Catalysis Research Institute (open access)

Advanced Resources for Catalysis Science; Recommendations for a National Catalysis Research Institute

Catalysis is one of the most valuable contributors to our economy and historically an area where the United States has enjoyed, but is now losing, international leadership. While other countries are stepping up their work in this area, support for advanced catalysis research and development in the U.S. has diminished. Yet, more than ever, innovative and improved catalyst technologies are imperative for new energy production processes to ease our dependence on imported resources, for new energy-efficient and environmentally benign chemical production processes, and for new emission reduction technologies to minimize the environmental impact of an active and growing economy. Addressing growing concerns about the future direction of U.S. catalysis science, experts from the catalysis community met at a workshop to determine and recommend advanced resources needed to address the grand challenges for catalysis research and development. The workshop's primary conclusion: To recapture our position as the leader in catalysis innovation and practice, and promote crucial breakthroughs, the U.S. must establish one or more well-funded and well-equipped National Catalysis Research Institutes competitively selected, centered in the national laboratories and, by charter, networked to other national laboratories, universities, and industry. The Institute(s) will be the center of a national collaboratory that gives …
Date: October 5, 2005
Creator: Peden, Charles HF. & Ray, Douglas
Object Type: Report
System: The UNT Digital Library
Advanced Simulation and Computing FY12-13 Implementation Plan Volume 2, Rev 0 (open access)

Advanced Simulation and Computing FY12-13 Implementation Plan Volume 2, Rev 0

None
Date: May 5, 2011
Creator: Meisner, R.
Object Type: Report
System: The UNT Digital Library
Advanced Techniques for Fourier Transform Wavefront Reconstruction (open access)

Advanced Techniques for Fourier Transform Wavefront Reconstruction

The performance of Fourier transform (FT) reconstructors in large adaptive optics systems with Shack-Hartmann sensors and a deformable mirror is analyzed. FT methods, which are derived for point-based geometries, are adapted for use on the continuous systems. Analysis and simulation show how to compensate for effects such as misalignment of the deformable mirror and wavefront sensor gain. Further filtering methods to reduce noise and improve performance are presented. All these modifications can be implemented at the filtering stage, preserving the speed of FT reconstruction. Simulation of a large system shows how compensated FT methods can have equivalent or better performance to slower vector-matrix-multiply reconstructions.
Date: August 5, 2002
Creator: Poyneer, L A
Object Type: Article
System: The UNT Digital Library
Advanced Techniques for In-Situ Monitoring of Phase Transformations During Welding Using Synchrotron-Based X-Ray Diffraction (open access)

Advanced Techniques for In-Situ Monitoring of Phase Transformations During Welding Using Synchrotron-Based X-Ray Diffraction

Understanding the evolution of microstructure in welds is an important goal of welding research because of the strong correlation between weld microstructure and weld properties. To achieve this goal it is important to develop a quantitative measure of phase transformations encountered during welding in order to ultimately develop methods for predicting weld microstructures from the characteristics of the welding process. To aid in this effort, synchrotron radiation methods have been developed at Lawrence Livermore National Laboratory (LLNL) for direct observation of microstructure evolution during welding. Using intense, highly collimated synchrotron radiation, the atomic structure of the weld heat affected and fusion zones can be probed in real time. Two synchrotron-based techniques, known as spatially resolved (SRXRD) and time resolved (TRXRD) x-ray diffraction, have been developed for these investigations. These techniques have now been used to investigate welding induced phase transformations in titanium alloys, low alloy steels, and stainless steel alloys. This paper will provide a brief overview of these methods and will discuss microstructural evolution during the welding of low carbon (AISI 1005) and medium carbon (AISI 1045) steels where the different levels of carbon influence the evolution of microstructures during welding.
Date: June 5, 2005
Creator: Elmer, J. W.; Palmer, T. A.; Zhang, W. & DebRoy, T.
Object Type: Article
System: The UNT Digital Library
Advanced waste forms research and development. First quarterly report (open access)

Advanced waste forms research and development. First quarterly report

Activities during the last two months are described. A significant portion of time was spent reviewing the literature on the Cs/sub 2/O-Al/sub 2/O/sub 3/-SiO/sub 2/ system, on the use of clays and zeolites for Cs-fixation of aqueous wastes, and on silicate-phosphate apatite structure crystal chemistry. The results from the latest group of compatibility studies (CS-runs) were used to modify the first demonstration supercalcine formulation so that it is more in line with the actual crystalline phase formation. Supercalcine formuation 75-2 is described.
Date: August 5, 1975
Creator: McCarthy, G. J.
Object Type: Report
System: The UNT Digital Library