Semivolatile organic (GC-MS) and inorganic analyses of groundwater samples during the hydrous pyrolysis/oxidation (HPO) field test in Visalia, CA, 1997 (open access)

Semivolatile organic (GC-MS) and inorganic analyses of groundwater samples during the hydrous pyrolysis/oxidation (HPO) field test in Visalia, CA, 1997

Hydrous pyrolysis/oxidation (HPO) is a novel, in situ, thermal-remediation technology that uses hot, oxygenated groundwater to completely oxidize a wide range of organic pollutants. A field demonstration of HPO was performed during the summer of 1997 at the Southern California Edison Pole Yard in Visalia, California, a site contaminated with creosote. The goal of the field experiment was to confirm the success of HPO under field remediation conditions. The groundwater was heated by steam injections, and oxygen was added by co-injection of compressed air. The progress of the HPO remediation process was evaluated by monitoring groundwater from multiple wells for dissolved oxygen, dissolved inorganic carbon, and dissolved organic contaminant levels. Analyses of groundwater chemistry allowed us to measure the concentrations of creosote components and to identify oxygenated intermediates produced by the HPO treatment. Dissolved organic carbon levels increased in response to steam injections because of the enhanced dissolution and mobilization of the creosote into the heated groundwater. Elevated concentrations of phenols and benzoic acid were measured in wells affected by the steam injections. Concentrations of other oxygenated compounds (i.e., fluorenone, anthrone, and 9,10-anthracenedione) increased in response to the steam injections. The production of these partially oxidized compounds is consistent with …
Date: February 5, 1998
Creator: Chiarappa, M.; Knauss, K. G.; Kumamoto, G.; Leif, R. N. & Newmark, R. L.
Object Type: Report
System: The UNT Digital Library
Tungsten Z-Pinch Long Implosions on the Saturn Generator (open access)

Tungsten Z-Pinch Long Implosions on the Saturn Generator

Recent success on the Saturn and Z accelerators at Sandia National Laboratories have demonstrated the ability to scale z-pinch parameters to increasingly larger current pulsed power facilities. Next generation machines will require even larger currents (>20 MA), placing further demands on pulsed power technology. To this end, experiments have been carried out on Saturn operating in a long pulse mode, investigating the potential of lower voltages and longer implosion times while still maintaining pinch fidelity. High wire number, 25 mm diameter tungsten arrays were imploded with implosion times ranging from 130 to 240 ns. The results were comparable to those observed in the Saturn short pulse mode, with risetimes on the order of 4.5 to 6.5 ns. Experimental data will be presented, along with two dimensional radiation magnetohydrodynamic simulations used to explain and reproduce the experiment.
Date: November 5, 1999
Creator: Douglas, Melissa R.; Deeney, Christopher; Spielman, Rick B.; Coverdale, Christine A.; Roderick, N. F. & Haines, M. G.
Object Type: Article
System: The UNT Digital Library
Large-eddy simulation formulation and implementation in HYDRA (open access)

Large-eddy simulation formulation and implementation in HYDRA

This report provides the equation formulation for a large-eddy simulation (LES) approach and Smagorinsky subgrid-scale (SGS) model for incompressible flow using the finite element method (FEM). This report also outlines the model implementation in the computer code HYDRA and the results of a coding check. The check was accomplished by running simple two- and three-element problems for a specified velocity field. The values of the eddy viscosity (the coefficient of proportionality in the SGS eddy diffusion model), the SGS diffusion term, and overall diffusion term (molecular plus SGS plus balancing tensor diffusivity) were compared to known hand-calculated values. Coding checks are best done by comparing the code-calculated solution to known analytical solutions. However, with LES turbulence modeling, these analytical solutions do not exist. It is also impossible to determine that the eddy viscosity is free of coding errors when performing code validation by comparing the LES to direct numerical simulations (DNS) (i.e., fine discretization with no turbulence model) or experimental results. Therefore, the coding checks presented here for a specified velocity field are necessary.
Date: December 5, 1995
Creator: McCallen, R.
Object Type: Report
System: The UNT Digital Library
The restructured fusion program and the role of alternative fusion concepts (open access)

The restructured fusion program and the role of alternative fusion concepts

This testimony to the subcommittee on Energy and the Environment of the U.S. House of Representatives`s Committee on Science pushes for about 25% of the fusion budget to go to alternative fusion concepts. These concepts are: low density magnetic confinement, inertial confinement fusion, high density magnetic confinement, and non- thermonuclear and miscellaneous programs. Various aspects of each of these concepts are outlined.
Date: March 5, 1996
Creator: Perkins, L.J.
Object Type: Report
System: The UNT Digital Library
Field and laboratory testing of seal materials proposed for the Waste Isolation Pilot Plant (open access)

Field and laboratory testing of seal materials proposed for the Waste Isolation Pilot Plant

The Small Scale Seal Performance Tests (SSSPT) were a series of in situ tests designed to evaluate the feasibility of various materials for sealing purposes. Testing was initiated in 1985 and concluded in 1995. Materials selected for the SSSPT included salt-saturated concrete, a 50%/50% mixture of crushed salt and bentonite, bentonite, and crushed salt. This paper presents a summary of the SSSPT field program, results of the in situ testing, and a discussion of post-testing laboratory studies of salt-saturated concrete. Results of the SSSPT support the use of salt-saturated concrete, compacted bentonite clay, and compacted crushed salt as sealing materials for the WIPP.
Date: February 5, 1996
Creator: Knowles, M.K. & Howard, C.L.
Object Type: Article
System: The UNT Digital Library
Laser systems for the generation of sodium layer guide stars (open access)

Laser systems for the generation of sodium layer guide stars

Laser generated guide stars in the mesosphere at 90 km provide an effective beacon for adaptive optics schemes which compensate the effects of atmospheric turbulence. This report discusses the attributes of the laser systems which are desirable from a point of view of overall adaptive optics system performance and operation ease.
Date: March 5, 1996
Creator: Friedman, H.; Erbert, G.; Kuklo, T.; Salmon, T.; Thompson, G.; Wong, N. et al.
Object Type: Article
System: The UNT Digital Library
Demonstration, testing, and evaluation of in situ heating of soil. Final report, Volume 2, Appendices A to E (open access)

Demonstration, testing, and evaluation of in situ heating of soil. Final report, Volume 2, Appendices A to E

This is a final report presented in two volumes. Volume I contains the technical report and Volume II contains appendices with background information and data. In this project approximately 300 cubic yards of clayey soil containing a low concentration plume of volatile organic chemicals was heated in situ by the application of electrical energy. It was shown that as a result of heating the effective permeability of soil to air flow was increased such that in situ soil vapor extraction could be performed. The initial permeability of soil was so low that the soil gas flow rate was immeasurably small even at high vacuum levels. It was demonstrated that the mass flow rate of the volatile organic chemicals was enhanced in the recovered soil gas as a result of heating. When scaled up, this process can be used for the environmental clean up and restoration of DOE sites contaminated with VOC`s and other organic chemicals. Although it may be applied to many types of soil formations, it is particularly attractive for low permeability clayey soil where conventional in situ venting techniques are limited by air flow.
Date: April 5, 1996
Creator: Dev, H.; Enk, J.; Jones, D. & Sabato, W.
Object Type: Report
System: The UNT Digital Library
Paleohydrologic investigations in the vicinity of Yucca Mountain: Late Quaternary paleobotanical and polynological records (open access)

Paleohydrologic investigations in the vicinity of Yucca Mountain: Late Quaternary paleobotanical and polynological records

The primary objective of this research in the vicinity of the proposed Yucca Mountain Nuclear Waste Repository is the detection of episodes of increased runoff and groundwater discharge in this presently arid area. Ancient, inactive spring deposits in nearby valley bottoms (Haynes, 1967; Quade, 1986; Quade and Pratt, 1989), evidence for perennial water in presently dry canyons (Spaulding, 1992), and recent claims for extraordinary increases in precipitation during the last glacial age (Forester, 1994), provide good reason to further investigate both lowland spring-discharge habitats, and upland drainages. The ultimate purpose is to assess the long-term variability of the hydrologic system in the vicinity of Yucca Mountain in response to naturally occurring climatic changes. The data generated in the course of this study are derived from radiocarbon dated packrat (Neotoma) middens. This report presents the results of an initial assessment of the hydrologic stability of the candidate area based on a limited suite of middens from localities that, on geomorphic and hydrologic grounds, could have been close to ancient stream-side or spring environments. Paleoclimatic reconstructions are another means of studying the long-term climatic hydrologic stability of the Candidate Area include, and are also generated from packrat midden data. A different flora …
Date: October 5, 1994
Creator: Spaulding, W. G.
Object Type: Report
System: The UNT Digital Library
Report of scouting study on precipitation of strontium, plutonium, and americium from Hanford complexant concentrate waste (open access)

Report of scouting study on precipitation of strontium, plutonium, and americium from Hanford complexant concentrate waste

A laboratory scouting test was conducted of precipitation methods for reducing the solubility of radionuclides in complexant concentrate (CC) waste solution. The results show that addition of strontium nitrate solution is effective in reducing the liquid phase activity of 90Sr (Strontium) in CC waste from tank 107-AN by 94% when the total strontium concentration is adjusted to 0.1 M. Addition of ferric nitrate solution effective in reducing the 241Am (Americium) activity in CC waste by 96% under the conditions described in the report. Ferric nitrate was also marginally effective in reducing the solubility of 239/240Pu (Plutonium) in CC waste
Date: September 5, 1995
Creator: Herting, D. L.
Object Type: Report
System: The UNT Digital Library
Technical progress report, January-December 1996 (open access)

Technical progress report, January-December 1996

Most of the last quarter was spent in the designing and planning mode on farm machinery to cultivate cotton stalks.
Date: March 5, 1996
Creator: Thacker, G.W.
Object Type: Report
System: The UNT Digital Library
CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, Fourth quarter 1995 (open access)

CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, Fourth quarter 1995

The principle objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Texaco Exploration and Production Inc`s. (TEPI) mid-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. TEPI has concluded all of the Tasks associated with the First Budget Period. The DOE approved the TEPI continuation application. Budget Period No. 2 is now in progress. Initial injection of CO{sub 2} began in November, and after a short shut-in period for the soak, the well was returned to production in late December, 1995.
Date: February 5, 1996
Creator: Wehner, S. & Prieditis, J.
Object Type: Report
System: The UNT Digital Library
A quantum mechanical equivalent photon spectrum for heavy ion reactions (open access)

A quantum mechanical equivalent photon spectrum for heavy ion reactions

Radioactive nuclear beams are rapidly coming to the fore as an important alternative to traditional measurements in nuclear astrophysics. Radioactive nuclei are scattered off the strong electromagnetic fields of a heavy ion, such as lead, providing an independent measurement of electromagnetic cross sections that are difficult to measure otherwise. In this paper, we examine the corrections to the semi-classical ``equivalent photon spectrum`` used to analyze these experiments, and derive an improved spectrum, valid in the long wavelength limit, that includes the effects of the size of the heavy ion, the non-zero longitudinal momentum transfer required by kinematics, and the response of the target nucleus to be off-shell photon.
Date: December 5, 1995
Creator: Benesh, C.J.; Hayes, A.C. & Friar, J.L.
Object Type: Article
System: The UNT Digital Library
Longitudinal dynamics and stability in beams for heavy-ion fusion (open access)

Longitudinal dynamics and stability in beams for heavy-ion fusion

Successful transport of induction-driven beams for heavy-ion fusion requires careful control of the longitudinal space charge. The usual control technique is the periodic application of time-varying longitudinal electric fields, called `ears`, that on the average, balance the space-charge field. this technique is illustrated using a fluid/envelope code CIRCE, and the sensitivity of the method to errors in these ear fields is illustrated. The possibility that periodic ear fields also excite the longitudinal instability is examined.
Date: January 5, 1996
Creator: Sharp, W. M.; Callahan, D. A. & Grote, D. P.
Object Type: Article
System: The UNT Digital Library
Applications of high average power nonlinear optics (open access)

Applications of high average power nonlinear optics

Nonlinear optical frequency convertors (harmonic generators and optical parametric oscillators are reviewed with an emphasis on high average power performance and limitations. NLO materials issues and NLO device designs are discussed in reference to several emerging scientific, military and industrial commercial applications requiring {approx} 100 watt average power level in the visible and infrared spectral regions. Research efforts required to enable practical {approx} 100 watt class NLO based laser systems are identified.
Date: February 5, 1996
Creator: Velsko, S. P. & Krupke, W. F.
Object Type: Article
System: The UNT Digital Library
Analysis of high resolution scatter images from laser damage experiments performed on KDP (open access)

Analysis of high resolution scatter images from laser damage experiments performed on KDP

Interest in producing high damage threshold KH{sub 2}PO{sub 4} (KDP) and (D{sub x}H{sub 1-x}){sub 2}PO{sub 4} (KD*P, DKDP) for optical switching and frequency conversion applications is being driven by the system requirements for the National Ignition Facility (NIF) at Lawrence Livermore National Lab (LLNL). Historically, the path to achieving higher damage thresholds has been to improve the purity of crystal growth solutions. Application of advanced filtration technology has increased the damage threshold, but gives little insight into the actual mechanisms of laser damage. We have developed a laser scatter diagnostic to better study bulk defects and laser damage mechanisms in KDP and KD*P crystals. This diagnostic consists of a cavity doubled, kilohertz class, Nd:YLF laser (527 nm) and high dynamic range CCD camera which allows imaging of bulk scatter signals. With it, we have performed damage tests at 355 nm on four different {open_quotes}vintages{close_quotes} of KDP crystals, concentrating on crystals produced via fast growth methods. We compare the diagnostic`s resolution to LLNL`s standard damage detection method of 100X darkfield microscopy and discuss its impact on damage threshold determination. We have observed the disappearance of scatter sites upon exposure to subthreshold irradiation. In contrast, we have seen scatterers appear where none …
Date: January 5, 1996
Creator: Runkel, M.; Woods, B. & Yan, M.
Object Type: Article
System: The UNT Digital Library
Clean iron production and machining technology. Year 1 summary report, January 1--December 31, 1995 (open access)

Clean iron production and machining technology. Year 1 summary report, January 1--December 31, 1995

The first phase of this project was conducted to develop a technique for evaluating the machinability of gray and ductile iron. That technique was then used to measure the machinability of a variety of irons and determine the processing factors that influenced and controlled machinability. The procedure developed to evaluate machinability involved drilling holes with a feed rate of 0.009 in/rev at various surface speeds. High speed steel drills were used so wear was observed more quickly. Microcarbides present in the irons were found to dominate the machinability. Pearlitic irons considered to have ``acceptable`` machinability (indicated either by tool life measured in the laboratory using high speed steel (HSS) drills or reports from commercial machine shops using other cutters) were found to contain from 8.9 to 10.5% by weight microscopic carbides. The tool wear rate increased when machining at higher surface speeds or machining irons containing higher weight percentage of microcarbides. All irons containing above 11.5% microcarbides consistently exhibited poor machinability. Tool wear results obtained using cubic boron nitride (CBN) cutters paralleled those obtained with HSS. Higher iron microcarbide concentrations produced faster tool wear. Experiments are now being formulated to explore methods of improving iron machinability. Future work will extend …
Date: March 5, 1996
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Improving reservoir conformance using gelled polymer systems. Fourteenth quarterly report, January 1, 1996--March 31, 1996 (open access)

Improving reservoir conformance using gelled polymer systems. Fourteenth quarterly report, January 1, 1996--March 31, 1996

The general objectives are to (1) to identify and develop gelled polymer systems which have potential to improve reservoir conformance of fluid displacement processes, (2) to determine the performance of these systems in bulk and in porous media, and (3) to develop methods to predict the capability of these systems to recover oil from petroleum reservoirs. This work focuses on three types of gel systems - an aqueous polysaccharide (KUSP1) system that gels as a function of pH, the chromium(III)-polyacrylamide system and the aluminum citrate-polyacrylamide system. Laboratory research is directed at the fundamental understanding of the physics and chemistry of the gelation process in bulk form and in porous media. This knowledge will be used to develop conceptual and mathematical models of the gelation process. Mathematical models will then be extended to predict the performance of gelled polymer treatments in oil reservoirs. Technical progress of Task III, mechanisms of in situ gelation is presented in this progress report.
Date: May 5, 1996
Creator: Green, D.W. & Willhite, G.P.
Object Type: Report
System: The UNT Digital Library
Influence of microstructure on laser damage threshold of IBS coatings (open access)

Influence of microstructure on laser damage threshold of IBS coatings

Ion-beam sputtering (IBS) coatings were developed for the laser gyro industry to meet significantly different requirements than those of fusion lasers. Laser gyro mirrors are small (< 25 mm) and require low losses (< 30 ppm typical) and high stability with long exposures to low power laser energy. In contrast, fusion laser optics are large (< 1 meter), have significantly reduced loss requirements (< 5,000 ppm) and high damage thresholds (> 26 J/cm{sup 2} at 1,064 nm with 3-ns pulses). As part of the National Ignition Facility (NIF) coating development effort, IBS coatings are being studied to explore the possible benefits of this technology to NIF optics. As an initial step to achieving the NIF size and damage threshold requirements, the coating process is being scaled to uniformly coat a 20 x 40 cm{sup 2} area with reduced spectral, reflected wavefront, and laser damage threshold requirements. Here, multilayer coatings deposited by ion-beam sputtering with amorphous layers were found to have lower damage thresholds at 1,064 nm than similar coatings with crystalline layers. Interestingly, at higher fluences the damage was less severe for the amorphous coatings. The magnitude of the difference in damage thresholds between the two different microstructures was strongly …
Date: January 5, 1996
Creator: Stolz, C. J.; Genin, F. Y.; Kozlowski, M. R.; Long, D.; Lalazari, R.; Wu, Z. L. et al.
Object Type: Article
System: The UNT Digital Library
Scientific and engineering services for the LANCE/ER accelerator production of tritium (APT) project (open access)

Scientific and engineering services for the LANCE/ER accelerator production of tritium (APT) project

The APT project office is conducting a preconceptual design study for an accelerator driven concept to produce tritium. The facility will require new technology in many areas, since the scale of this accelerator is significantly larger then any in operation to date. The facility is composed of four subsystems: accelerator, target & blanket, balance of plant, and tritium purification system (TPS). New physics realms will be entered in order for the concept to be feasible; for example, extremely high energy levels of the entering protons that induce (multiplicative) spallation of the neutrons from the high Z target will occur. These are complex and require advance codes (MCNP) to predict the physics interactions and as well as deleterious material effects in the surrounding structures. Other issues include component cooling and complex thermal-hydraulics effects within the blanket and the beam {open_quotes}window.{close_quotes} In order to support a DOE mandated fast ROD schedule, Los Alamos APT staff will be provided with senior, engineering technical support staff with direct APT technology experience and whom are {open_quotes}on site{close_quotes}. This report contains resumes of the staff.
Date: December 5, 1994
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Laboratory astrophysics: Measurements of n = n{prime} to n = 2 line emission in Fe{sup 16+} to Fe{sup 23+} (open access)

Laboratory astrophysics: Measurements of n = n{prime} to n = 2 line emission in Fe{sup 16+} to Fe{sup 23+}

One of the dominant forms of astronomical line emission in the 6 {angstrom} to 18 {angstrom} spectral region is line emission produced by n = n{prime} to n = 2 transitions in Fe{sup 16+} to Fe{sup 23+} (i.e., Fe L-shell n-2 line emission). Using the Lawrence Livermore National Laboratory electron beam ion trap (EBIT) facility, the authors have carried out a number of measurements designed to address astrophysical issues concerning Fe L-shell line emission. Desired ions are produced and trapped using the nearly monoenergetic electron beam of EBIT. Trapped ions are collisionally excited and the resulting X-ray line emission detected using Bragg crystal spectrometers. They have recently completed a line survey of Fe L-shell 3-2 line emission. The line survey will allow a more reliable accounting of line blending in astronomical spectra. They have now begun a series of broadband, high resolution line ratio measurements. These measurements are designed to benchmark atomic calculations used in astronomical plasma emission codes and also for comparison with X-ray spectral observations of astronomical objects. Initial measurements have been carried out in Fe{sup 23+}. Preliminary results agree with distorted wave calculations to within 20% and better.
Date: March 5, 1996
Creator: Savin, D.W.; Beiersdorfer, P.; Lopez-Urrutia, J.C.; Decaux, V.; Liedahl, D.A.; Reed, K.J. et al.
Object Type: Report
System: The UNT Digital Library
Design of an infrared camera based aircraft detection system for laser guide star installations (open access)

Design of an infrared camera based aircraft detection system for laser guide star installations

There have been incidents in which the irradiance resulting from laser guide stars have temporarily blinded pilots or passengers of aircraft. An aircraft detection system based on passive near infrared cameras (instead of active radar) is described in this report.
Date: March 5, 1996
Creator: Friedman, H. & Macintosh, B.
Object Type: Article
System: The UNT Digital Library
Volume increase analysis of production test 040 (open access)

Volume increase analysis of production test 040

This statistical analysis examines volume increase data from PTA-040. The purpose of this analysis is to compare four 1.25 enriched uranium core alloys (Standard, British, High Silicon, and Modified British), two heat treatments (Induction and Salt Bath), and the alloy-treatment interaction. The four core alloys were each processed using the two treatments and then canned as 5.540-in. AlSi fuel elements. Test pieces were charged in 16 tubes with 40 pieces per tube. The eight fuel types (4 alloys {times} 2 treatments) were arranged in a series of Latin squares in the test tubes to eliminate the effect of position and tube. A comparison of volume increase was deemed worthwhile after analyzing PTA-040 with regard to fuel element distortion. Volume increases in the present analysis were calculated by H.D. Huber using OD and ID measurements taken at C-Basin with consideration for can wall corrosion and geometric distortion. these volume increase calculations were not completely substantiated, since a thorough check with water displacement measurements at the Radiometallurgical Laboratory was not possible. Despite this fact, the present analysis was continued since a good correlation between the volume increase calculations and element exposure was observed.
Date: September 5, 1967
Creator: Stein, R.C.
Object Type: Report
System: The UNT Digital Library
Evaluation of the discrete complex-image method for a NEC-like moment-method solution (open access)

Evaluation of the discrete complex-image method for a NEC-like moment-method solution

The discrete image approximation for the field of a half-space is tested in the NEC antenna modeling program as an alternative to the interpolation method presently used. The accuracy and speed of the discrete image approximation are examined for varying number of images and approximation contour, and the solution for current is obtained on a horizontal wire approaching the interface.
Date: January 5, 1996
Creator: Burke, G. J.
Object Type: Report
System: The UNT Digital Library
Femtosecond laser materials processing (open access)

Femtosecond laser materials processing

Femtosecond lasers enable materials processing of most any material with extremely high precision and negligible shock or thermal loading to the surrounding area. Applications ranging from drilling teeth to cutting explosives to precision cuts in composites are possible by using this technology. For material removal at reasonable rates, we have developed a fully computer-controlled 15-Watt average power, 100-fs laser machining system.
Date: August 5, 1998
Creator: Stuart, B
Object Type: Article
System: The UNT Digital Library