Evaluation of High-Efficiency Gas-Liquid Contactors for Natural Gas Processing (open access)

Evaluation of High-Efficiency Gas-Liquid Contactors for Natural Gas Processing

None
Date: June 5, 1996
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Evaluation of the discrete complex-image method for a NEC-like moment-method solution (open access)

Evaluation of the discrete complex-image method for a NEC-like moment-method solution

The discrete image approximation for the field of a half-space is tested in the NEC antenna modeling program as an alternative to the interpolation method presently used. The accuracy and speed of the discrete image approximation are examined for varying number of images and approximation contour, and the solution for current is obtained on a horizontal wire approaching the interface.
Date: January 5, 1996
Creator: Burke, G. J.
Object Type: Report
System: The UNT Digital Library
Exhaust gas sensors. CRADA final report for CRADA Number 94MULT-912ES (open access)

Exhaust gas sensors. CRADA final report for CRADA Number 94MULT-912ES

This project was canceled shortly after final approval. Thus, there are no accomplishments. The major problem encountered was the extreme effort required to obtain approval (about two years) to start work. No lessons were learned. No close-outs items require addressing. No contracts were let. Only two commitments were scheduled to be completed before the Y-12 cancellation: both involved the industrial partners: (1) the industrial partners were to define the preferred sensor power requirements, this was completed and the details are treated as proprietary or CRADA-Protected Information; (2) the industrial partners were to perform a physical integration assessment of sensor technologies and the details are treated as proprietary or CRADA-Protected Information.
Date: June 5, 1996
Creator: Hiller, J.M. & Miree, T.J.
Object Type: Report
System: The UNT Digital Library
Experiments on hot and dense laser-produced plasmas (open access)

Experiments on hot and dense laser-produced plasmas

Plasmas generated by irradiating targets with {approx}20 kJ of laser energy are routinely created in inertial confinement fusion research. X-ray spectroscopy provides one of the few methods for diagnosing the electron temperature and electron density. For example, electron densities approaching 10{sup 24} cm{sup -3} have been diagnosed by spectral linewidths. However, the accuracy of the spectroscopic diagnostics depends on the population kinetics, the radiative transfer, and the line shape calculations. Analysis for the complex line transitions has recently been improved and accelerated by the use of a database where detailed calculations can be accessed rapidly and interactively. Examples of data from Xe and Ar doped targets demonstrate the current analytic methods. First we will illustrate complications that arise from the presence of a multitude of underlying spectral lines. Then, we will consider the Ar He-like 1s{sup 2}({sup 1}S{sub 0}) - 1s3p({sup 1}P{sub 0}) transition where ion dynamic effects may affect the profile. Here, the plasma conditions are such that the static ion microfield approximation is no longer valid; therefore in addition to the width, the details of the line shape can be used to provide additional information. We will compare the data to simulations and discuss the possible pitfalls involved …
Date: August 5, 1996
Creator: Back, C. A.; Woolsey, N. C.; Asfaw, A.; Glenzer, S. H.; Hammel, B. A.; Keane, C. J. et al.
Object Type: Article
System: The UNT Digital Library
Field and laboratory testing of seal materials proposed for the Waste Isolation Pilot Plant (open access)

Field and laboratory testing of seal materials proposed for the Waste Isolation Pilot Plant

The Small Scale Seal Performance Tests (SSSPT) were a series of in situ tests designed to evaluate the feasibility of various materials for sealing purposes. Testing was initiated in 1985 and concluded in 1995. Materials selected for the SSSPT included salt-saturated concrete, a 50%/50% mixture of crushed salt and bentonite, bentonite, and crushed salt. This paper presents a summary of the SSSPT field program, results of the in situ testing, and a discussion of post-testing laboratory studies of salt-saturated concrete. Results of the SSSPT support the use of salt-saturated concrete, compacted bentonite clay, and compacted crushed salt as sealing materials for the WIPP.
Date: February 5, 1996
Creator: Knowles, M.K. & Howard, C.L.
Object Type: Article
System: The UNT Digital Library
GENII dose calculations for radioactive liquid waste tank criticality (open access)

GENII dose calculations for radioactive liquid waste tank criticality

This document provides the values of dose calculations for radioactive liquid waste tank criticality.
Date: September 5, 1996
Creator: Huang, C. H.
Object Type: Report
System: The UNT Digital Library
Improving on hidden Markov models: An articulatorily constrained, maximum likelihood approach to speech recognition and speech coding (open access)

Improving on hidden Markov models: An articulatorily constrained, maximum likelihood approach to speech recognition and speech coding

The goal of the proposed research is to test a statistical model of speech recognition that incorporates the knowledge that speech is produced by relatively slow motions of the tongue, lips, and other speech articulators. This model is called Maximum Likelihood Continuity Mapping (Malcom). Many speech researchers believe that by using constraints imposed by articulator motions, we can improve or replace the current hidden Markov model based speech recognition algorithms. Unfortunately, previous efforts to incorporate information about articulation into speech recognition algorithms have suffered because (1) slight inaccuracies in our knowledge or the formulation of our knowledge about articulation may decrease recognition performance, (2) small changes in the assumptions underlying models of speech production can lead to large changes in the speech derived from the models, and (3) collecting measurements of human articulator positions in sufficient quantity for training a speech recognition algorithm is still impractical. The most interesting (and in fact, unique) quality of Malcom is that, even though Malcom makes use of a mapping between acoustics and articulation, Malcom can be trained to recognize speech using only acoustic data. By learning the mapping between acoustics and articulation using only acoustic data, Malcom avoids the difficulties involved in collecting …
Date: November 5, 1996
Creator: Hogden, J.
Object Type: Report
System: The UNT Digital Library
Improving reservoir conformance using gelled polymer systems. Fourteenth quarterly report, January 1, 1996--March 31, 1996 (open access)

Improving reservoir conformance using gelled polymer systems. Fourteenth quarterly report, January 1, 1996--March 31, 1996

The general objectives are to (1) to identify and develop gelled polymer systems which have potential to improve reservoir conformance of fluid displacement processes, (2) to determine the performance of these systems in bulk and in porous media, and (3) to develop methods to predict the capability of these systems to recover oil from petroleum reservoirs. This work focuses on three types of gel systems - an aqueous polysaccharide (KUSP1) system that gels as a function of pH, the chromium(III)-polyacrylamide system and the aluminum citrate-polyacrylamide system. Laboratory research is directed at the fundamental understanding of the physics and chemistry of the gelation process in bulk form and in porous media. This knowledge will be used to develop conceptual and mathematical models of the gelation process. Mathematical models will then be extended to predict the performance of gelled polymer treatments in oil reservoirs. Technical progress of Task III, mechanisms of in situ gelation is presented in this progress report.
Date: May 5, 1996
Creator: Green, D.W. & Willhite, G.P.
Object Type: Report
System: The UNT Digital Library
Increasing heavy oil reserves in the Wilmington Oil field through advanced reservoir characterization and thermal production technologies. Quarterly report, April 1, 1996--June 30, 1996 (open access)

Increasing heavy oil reserves in the Wilmington Oil field through advanced reservoir characterization and thermal production technologies. Quarterly report, April 1, 1996--June 30, 1996

The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., California using advanced reservoir characterization and thermal production technologies. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The technologies include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal …
Date: August 5, 1996
Creator: Hara, S.
Object Type: Report
System: The UNT Digital Library
Influence of microstructure on laser damage threshold of IBS coatings (open access)

Influence of microstructure on laser damage threshold of IBS coatings

Ion-beam sputtering (IBS) coatings were developed for the laser gyro industry to meet significantly different requirements than those of fusion lasers. Laser gyro mirrors are small (< 25 mm) and require low losses (< 30 ppm typical) and high stability with long exposures to low power laser energy. In contrast, fusion laser optics are large (< 1 meter), have significantly reduced loss requirements (< 5,000 ppm) and high damage thresholds (> 26 J/cm{sup 2} at 1,064 nm with 3-ns pulses). As part of the National Ignition Facility (NIF) coating development effort, IBS coatings are being studied to explore the possible benefits of this technology to NIF optics. As an initial step to achieving the NIF size and damage threshold requirements, the coating process is being scaled to uniformly coat a 20 x 40 cm{sup 2} area with reduced spectral, reflected wavefront, and laser damage threshold requirements. Here, multilayer coatings deposited by ion-beam sputtering with amorphous layers were found to have lower damage thresholds at 1,064 nm than similar coatings with crystalline layers. Interestingly, at higher fluences the damage was less severe for the amorphous coatings. The magnitude of the difference in damage thresholds between the two different microstructures was strongly …
Date: January 5, 1996
Creator: Stolz, C. J.; Genin, F. Y.; Kozlowski, M. R.; Long, D.; Lalazari, R.; Wu, Z. L. et al.
Object Type: Article
System: The UNT Digital Library
INTEG: A program to calculate groundwater contamination and human dose (open access)

INTEG: A program to calculate groundwater contamination and human dose

INTEG is a computer program to calculate groundwater contamination concentration levels and human dose from inventories, vadose zone transport, and aquifer transport.
Date: September 5, 1996
Creator: Mann, F. M.
Object Type: Report
System: The UNT Digital Library
Investigation and demonstration of dry carbon-based sorbent injection for mercury control. Quarterly report, November 1, 1995--December 31, 1995 (open access)

Investigation and demonstration of dry carbon-based sorbent injection for mercury control. Quarterly report, November 1, 1995--December 31, 1995

The overall objective to this two phase program is to investigate dry carbon-based sorbents for mercury control. During Phase I, a bench-scale field test device that can simulate an electrostatic precipitator, a pulse-jet baghouse, or a reverse-gas baghouse will be designed and integrated with an existing pilot-scale facility at Public Service Company of Colorado`s (PSCo`s) Comanche station. Various sorbents will then be injected to determine the mercury removal efficiency for each. During Phase II effort, component integration of the most promising technologies shall be tested at the 5000 acfm pilot-scale. The primary task currently underway is the facility design. The design is expected to be finished in January, 1996. The facility, regardless of the particulate control module configuration, will be fitted with supply line injection port, through which mercury sorbents and SO{sub 2} control sorbents can be added to the flue gas stream.
Date: February 5, 1996
Creator: Hunt, T. & Sjostrom, S.
Object Type: Report
System: The UNT Digital Library
Laboratory astrophysics: Measurements of n = n{prime} to n = 2 line emission in Fe{sup 16+} to Fe{sup 23+} (open access)

Laboratory astrophysics: Measurements of n = n{prime} to n = 2 line emission in Fe{sup 16+} to Fe{sup 23+}

One of the dominant forms of astronomical line emission in the 6 {angstrom} to 18 {angstrom} spectral region is line emission produced by n = n{prime} to n = 2 transitions in Fe{sup 16+} to Fe{sup 23+} (i.e., Fe L-shell n-2 line emission). Using the Lawrence Livermore National Laboratory electron beam ion trap (EBIT) facility, the authors have carried out a number of measurements designed to address astrophysical issues concerning Fe L-shell line emission. Desired ions are produced and trapped using the nearly monoenergetic electron beam of EBIT. Trapped ions are collisionally excited and the resulting X-ray line emission detected using Bragg crystal spectrometers. They have recently completed a line survey of Fe L-shell 3-2 line emission. The line survey will allow a more reliable accounting of line blending in astronomical spectra. They have now begun a series of broadband, high resolution line ratio measurements. These measurements are designed to benchmark atomic calculations used in astronomical plasma emission codes and also for comparison with X-ray spectral observations of astronomical objects. Initial measurements have been carried out in Fe{sup 23+}. Preliminary results agree with distorted wave calculations to within 20% and better.
Date: March 5, 1996
Creator: Savin, D.W.; Beiersdorfer, P.; Lopez-Urrutia, J.C.; Decaux, V.; Liedahl, D.A.; Reed, K.J. et al.
Object Type: Report
System: The UNT Digital Library
Laser systems for the generation of sodium layer guide stars (open access)

Laser systems for the generation of sodium layer guide stars

Laser generated guide stars in the mesosphere at 90 km provide an effective beacon for adaptive optics schemes which compensate the effects of atmospheric turbulence. This report discusses the attributes of the laser systems which are desirable from a point of view of overall adaptive optics system performance and operation ease.
Date: March 5, 1996
Creator: Friedman, H.; Erbert, G.; Kuklo, T.; Salmon, T.; Thompson, G.; Wong, N. et al.
Object Type: Article
System: The UNT Digital Library
Longitudinal dynamics and stability in beams for heavy-ion fusion (open access)

Longitudinal dynamics and stability in beams for heavy-ion fusion

Successful transport of induction-driven beams for heavy-ion fusion requires careful control of the longitudinal space charge. The usual control technique is the periodic application of time-varying longitudinal electric fields, called `ears`, that on the average, balance the space-charge field. this technique is illustrated using a fluid/envelope code CIRCE, and the sensitivity of the method to errors in these ear fields is illustrated. The possibility that periodic ear fields also excite the longitudinal instability is examined.
Date: January 5, 1996
Creator: Sharp, W. M.; Callahan, D. A. & Grote, D. P.
Object Type: Article
System: The UNT Digital Library
Microstructural dependence of cavitation damage in polycrystalline materials. Final report, 1 November 1992--31 October 1994 (open access)

Microstructural dependence of cavitation damage in polycrystalline materials. Final report, 1 November 1992--31 October 1994

Microstructure of a sample of Inconel X-750 damaged by ISCC (intergranular stress corrosion cracking) was examined after fatigue precracking in a high-temperature environment of deaerated water. Orientation imaging microscopy was used to reveal the microstructure adjacent to the crack path. General high-angle boundaries were found to be most susceptible to cracking. An ordering of the susceptibilities to ISCC damage was proposed; all boundaries have been classified into one of 12 categories. A model is proposed to predict the crack path for ISCC based on ex situ record of damage probabilities. The cracking is modeled as a Markov chain on a regular hexagonal array of grain boundaries representing the connectivity of the network.
Date: February 5, 1996
Creator: Adams, B.L.
Object Type: Report
System: The UNT Digital Library
Minimum TI4085D interlock setpoint at 1.0 GPM sludge-only feed rate and 14,000 ppm TOC (open access)

Minimum TI4085D interlock setpoint at 1.0 GPM sludge-only feed rate and 14,000 ppm TOC

DWPF-Engineering requested that SRTC determine the minimum indicated melter vapor space temperature that must be maintained in order to minimize the potential for off-gas flammability during a steady sludge-only feeding operation at 1.0 GPM containing 14,000 ppm total organic carbon. The detailed scope of this request is described in the technical task request, HLW-DWPF-TTR-960092 (DWPT Activity No. DWPT-96-0065). In response to this request, a dynamic simulation study was conducted in which the concentration of flammable gases was tracked throughout the course of a simulated 3X off-gas surge using the melter off-gas (MOG) dynamics model. The results of simulation showed that as long as the melter vapor space temperature as indicated on TI4085D is kept at 570 degrees C or higher, the peak concentration of combustible gases in the melter off-gas system is not likely to exceed 60 percent of the lower flammability limit (LFL). The minimum TI4085D of 570 degrees C is valid only when the air purges to FIC3221A and FIC3221B are maintained at or above 850 and 250 lb/hr, respectively. All the key bases and assumptions along with the input data used in the simulation are described in the attached E-7 calculation note.
Date: November 5, 1996
Creator: Choi, A.S.
Object Type: Report
System: The UNT Digital Library
National Ignition Facility sub-system design requirements computer system SSDR 1.5.1 (open access)

National Ignition Facility sub-system design requirements computer system SSDR 1.5.1

This System Design Requirement document establishes the performance, design, development and test requirements for the Computer System, WBS 1.5.1 which is part of the NIF Integrated Computer Control System (ICCS). This document responds directly to the requirements detailed in ICCS (WBS 1.5) which is the document directly above.
Date: September 5, 1996
Creator: Spann, J.; VanArsdall, P. & Bliss, E.
Object Type: Report
System: The UNT Digital Library
Neutron-induced noise in NIF-class diagnostic instruments (open access)

Neutron-induced noise in NIF-class diagnostic instruments

Neutron yields form DT-filled ICF targets have reached 10{sup 14}. Above 10{sup 13}, a significant neutron-induced background appears in images recorded with nearby streak cameras. Since cameras components (streak tube, image-intensifier tube, and CCD array) are similar to components that will be used in many NIF instruments, streak camera images provide information about neutron-induced backgrounds that will be encountered in the NIF environment. At a fluence of 10{sup 7} neutrons/cm{sup 2}, the background consists of two distinct components: a uniform component equal to nearly 20% of the camera`s linear range and sharp, intense peaks each localized to just a couple of image pixels. About 80% of the uniform background is caused by interactions with the streak tube and image-intensifier tube. Nearly all of the sharp spikes are caused by interactions with pixels of the CCD array. The spikes make the most significant contribution to image noise.
Date: June 5, 1996
Creator: Lerche, R.A.
Object Type: Article
System: The UNT Digital Library
Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 17, October 1, 1994-- December 31, 1994 (open access)

Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 17, October 1, 1994-- December 31, 1994

A series of experiments in which the stirrer speed was varied during a methanol synthesis run with BASF S3-86 catalyst showed that mass transfer limitations were present at 750 psig reactor pressure and at space velocities of 5000 and 10000 sl/kg(cat.)-hr.. There was no effect of stirrer speed on reaction rate at 2500 psig reactor pressure and 16500 sl/kg(cat.)-hr. space velocity. However, this was probably due to a close approach to equilibrium rather than to the lack of a mass transfer effect. The most plausible explanation for the presence of a mass transfer influence is the position of the gas feed dip tube relative to the agitator impeller. A second set of stirrer speed experiments using the same catalyst showed that feeding into the reactor headspace produced much lower reaction rates, compared with gas feed through a dip tube. The headspace feed also showed a strong dependence on stirrer speed, consistent with the dip tube feed results. In a ``blank` run at 375{degree}C with decahydronaphthalene, about 110 mL of the initial charge of 150 mL remained in the reactor after 73 hours of operation at 375{degree}C and 850 psig of hydrogen. The rate of hydrocarbon evolution was low throughout the …
Date: July 5, 1996
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 18, January 1, 1995-- March 31, 1995 (open access)

Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 18, January 1, 1995-- March 31, 1995

A set of stirrer speed experiments using the Cu/ZnO methanol synthesis catalyst showed that introducing the gas feed into the reactor through an extended dip tube eliminated the dependency of catalyst performance on stirrer speed. The methanol productivity data from the reactor gas feed configuration tests conducted in December, 1994 and January, 1995, were correlated with stirrer speed. The influence on mass transfer on catalyst performance was clearly illustrated for each gas feed location. The ``high pressure, high temperature` zinc chromite methanol synthesis catalyst showed surprising activity at temperatures as low as 300{degree}C during the first successful stirred autoclave run with this catalyst. No C{sub 2{sup {plus}}} alcohols were detected, but significant levels of C{sub 2}-C{sub 4} olefins and dimethyl ether (DME) were produced. The presence of olefins suggests that higher alcohols might have formed and subsequently dehydrated. The slurry liquid, decahydronaphthalene, showed no evidence of decomposition during 15 days of continuous operation. 2 figs., 1 tab.
Date: July 5, 1996
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 20, July 1, 1995--September 30, 1995 (open access)

Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 20, July 1, 1995--September 30, 1995

Standard thermal stability tests were carried out on four liquids: decahydroquinoline (DHQ); 1, 3-Di-4 piperidylpropane (134PPDP), Naphthenic Base 37 and tetrahydronaphthalene (tetralin). Tetralin was more stable than decahydronaphthalene (Decalin{reg_sign}), and THQ was slightly less stable. Both tetralin and THQ should be evaluated further as slurry liquids in the presence of catalyst and syngas. Naphthenic Base 37 and 134PPDP do not have satisfactory thermal stability. Vapor pressure osmometry (VPO) was shown to be an unreliable technique for measuring the average molecular weight of slurry liquids. Gas chromatography/mass spectroscopy (GUMS) is a more accurate technique for pure compounds.
Date: September 5, 1996
Creator: Roberts, G. W.
Object Type: Report
System: The UNT Digital Library
Nuclear diagnostics in support of ICF experiments (open access)

Nuclear diagnostics in support of ICF experiments

As the yields of Inertial Confinement Fusion (ICF) experiments increase to NIF levels new diagnostic techniques for studying details of fusion burn behavior will become feasible. The new techniques will provide improved measurements of fusion burn temperature and history. Improved temperature measurements might be achieved with magnetic spectroscopy of fusion neutrons. High-bandwidth fusion reaction history will be measured with fusion-specific {gamma}-ray diagnostics. Additional energy-resolved {gamma}-ray might be able to study a selection of specific behaviors during fusion burn. Present ICF yields greater than 10{sup 13} neutrons are sufficient to demonstrate the basic methods that underlie the new techniques. As ICF yields increase, the diagnostics designs adjusted accordingly in order to provide clear and specific data on fusion burn performance.
Date: June 5, 1996
Creator: Moran, M. J. & Hall, J.
Object Type: Article
System: The UNT Digital Library
Operability Test Procedure (OTP) for the Annulus Thermocouple Tree (open access)

Operability Test Procedure (OTP) for the Annulus Thermocouple Tree

This document outlines the steps required to properly document the operability testing of this prototypical system. The tree is deployed in the annulus of the underground nuclear waste storage tank 241-AN-107; it is to monitor the temperature gradient of the primary containment wall using 3 arrays of contact thermocouples.
Date: February 5, 1996
Creator: Steele, R.J.
Object Type: Report
System: The UNT Digital Library