Application of non-radiometric methods to the determination of plutonium. Literature review conducted for the Buried Waste Integrated Program (open access)

Application of non-radiometric methods to the determination of plutonium. Literature review conducted for the Buried Waste Integrated Program

This literature review was motivated by discussions that took place during a review of contamination control technologies proposed for INEL (buried waste). It should be a useful tool in identifying non-radiation measurement techniques for Pu and Am such as ICP-MS, which should fulfill the following criteria: apparatus must be field deployable; up to 100 samples per day; and lower levels of detection and required time must be listed. The sensitivity of ICP and RIMS is compared against that needed for contamination monitoring at INEL. Only Pu-241, with a required detection limit of 400 ppt, would challenge the sensitivity of ICP-MS; Pu-238 would be easily determined. The need to determine Pu-238 and Am-241 in the presence of U-238 and Pu-241 seems to preclude the possibility of using laser ablation ICP-MS for Pu monitoring. ICP-AES and -LEAFS methods may not have enough sensitivity to determine Pu-238 at 2 ppb level with confidence, but RIMS (resonance ionization mass spectroscopy) should be adequate. 47 refs, figs.
Date: March 5, 1992
Creator: Edelson, M. C.
Object Type: Report
System: The UNT Digital Library
ARM tropical pacific experiment (ATPEX): Role of cloud, water vapor and convection feedbacks in the coupled ocean/atmosphere system (open access)

ARM tropical pacific experiment (ATPEX): Role of cloud, water vapor and convection feedbacks in the coupled ocean/atmosphere system

We have initiated studies that include radiation model validation, improved treatment of the three-dimensional structure of cloud-radiation interactions, and sensitivity runs that will unravel the role of cloud-convection-radiation interactions in the Pacific Sear Surface Temperatures and the overlying Walker and Hadley circulation. The research program is divided into three phases: (1) radiation, (2) cloud parameterization issues; (3) feedback and ocean-atmosphere interactions.
Date: March 5, 1992
Creator: Ramanathan, V. & Barnett, T.P.
Object Type: Report
System: The UNT Digital Library
ARM tropical pacific experiment (ATPEX): Role of cloud, water vapor and convection feedbacks in the coupled ocean/atmosphere system. Progress report, September 1, 1991--August 31, 1992 (open access)

ARM tropical pacific experiment (ATPEX): Role of cloud, water vapor and convection feedbacks in the coupled ocean/atmosphere system. Progress report, September 1, 1991--August 31, 1992

We have initiated studies that include radiation model validation, improved treatment of the three-dimensional structure of cloud-radiation interactions, and sensitivity runs that will unravel the role of cloud-convection-radiation interactions in the Pacific Sear Surface Temperatures and the overlying Walker and Hadley circulation. The research program is divided into three phases: (1) radiation, (2) cloud parameterization issues; (3) feedback and ocean-atmosphere interactions.
Date: March 5, 1992
Creator: Ramanathan, V. & Barnett, T. P.
Object Type: Report
System: The UNT Digital Library
Asymptotics of a free boundary problem (open access)

Asymptotics of a free boundary problem

This article is concerned with free boundary problems for the differential equations u{double_prime} + (2{nu} + 1)/r u{prime} + u - u{sup q} = 0, r > 0, where 0 {le} q < 1 and {nu} {ge} 0. As was shown by Kaper and Kwong, there exists a unique R > 0, such that the equation admits a classical solution u that is positive and monotone on (0,R) and that satisfies the boundary conditions u{prime}(0) = 0, u(R) = u{prime}(R) = 0. This article is concerned with the behavior of R and u(0) as q {yields} 1.
Date: October 5, 1992
Creator: Atkinson, F. V.; Kaper, H. G. & Kwong, Man Kam
Object Type: Report
System: The UNT Digital Library
Completing fault models for abductive diagnosis (open access)

Completing fault models for abductive diagnosis

In logic-based diagnosis, the consistency-based method is used to determine the possible sets of faulty devices. If the fault models of the devices are incomplete or nondeterministic, then this method does not necessarily yield abductive explanations of system behavior. Such explanations give additional information about faulty behavior and can be used for prediction. Unfortunately, system descriptions for the consistency-based method are often not suitable for abductive diagnosis. Methods for completing the fault models for abductive diagnosis have been suggested informally by Poole and by Cox et al. Here we formalize these methods by introducing a standard form for system descriptions. The properties of these methods are determined in relation to consistency-based diagnosis and compared to other ideas for integrating consistency-based and abductive diagnosis.
Date: November 5, 1992
Creator: Knill, E. (Los Alamos National Lab., NM (United States)); Cox, P.T. & Pietrzykowski, T. (Technical Univ., NS (Canada))
Object Type: Article
System: The UNT Digital Library
Completing fault models for abductive diagnosis (open access)

Completing fault models for abductive diagnosis

In logic-based diagnosis, the consistency-based method is used to determine the possible sets of faulty devices. If the fault models of the devices are incomplete or nondeterministic, then this method does not necessarily yield abductive explanations of system behavior. Such explanations give additional information about faulty behavior and can be used for prediction. Unfortunately, system descriptions for the consistency-based method are often not suitable for abductive diagnosis. Methods for completing the fault models for abductive diagnosis have been suggested informally by Poole and by Cox et al. Here we formalize these methods by introducing a standard form for system descriptions. The properties of these methods are determined in relation to consistency-based diagnosis and compared to other ideas for integrating consistency-based and abductive diagnosis.
Date: November 5, 1992
Creator: Knill, E.; Cox, P. T. & Pietrzykowski, T.
Object Type: Article
System: The UNT Digital Library
A computer system for access to distributed genome mapping data (open access)

A computer system for access to distributed genome mapping data

Development of a computer system for access to distributed genome mapping data is continuing. This effort is to develop software which accesses multiple databases and retrieves data which contain information useful for accelerating mapping human chromosomes. For example, the molecular sequence databases (GenBank, EMBL Data Library, PIR, SwissProt) which contain data required for the development of oligonucleotides for probing DNA as well as for extracting data for primer pair development for PCR-based methods. It is also to develop software which qualitatively integrates the following mapping data: (1) markers regionally localized using cytogenetic methods, (2) polymorphic markers ordered by genetic linkage analysis, (3) clones ordered by various finger-printing'' methods, (4) fragments ordered by long-range restriction mapping, (5) single genomic fragments or clones that have STSs assigned to them, (6) nucleotide sequences, (7) the associated metadata such as the submitting investigator's name, location, etc; the source organism; the chromosome the element is from; the chromosomal location is whatever detail is available.
Date: February 5, 1992
Creator: Marr, T.G.
Object Type: Report
System: The UNT Digital Library
A computer system for access to distributed genome mapping data. Progress report (open access)

A computer system for access to distributed genome mapping data. Progress report

Development of a computer system for access to distributed genome mapping data is continuing. This effort is to develop software which accesses multiple databases and retrieves data which contain information useful for accelerating mapping human chromosomes. For example, the molecular sequence databases (GenBank, EMBL Data Library, PIR, SwissProt) which contain data required for the development of oligonucleotides for probing DNA as well as for extracting data for primer pair development for PCR-based methods. It is also to develop software which qualitatively integrates the following mapping data: (1) markers regionally localized using cytogenetic methods, (2) polymorphic markers ordered by genetic linkage analysis, (3) clones ordered by various ``finger-printing`` methods, (4) fragments ordered by long-range restriction mapping, (5) single genomic fragments or clones that have STSs assigned to them, (6) nucleotide sequences, (7) the associated metadata such as the submitting investigator`s name, location, etc; the source organism; the chromosome the element is from; the chromosomal location is whatever detail is available.
Date: February 5, 1992
Creator: Marr, T. G.
Object Type: Report
System: The UNT Digital Library
The development and testing of a fieldworthy system of improved fluid pumping device and liquid sensor for oil wells (open access)

The development and testing of a fieldworthy system of improved fluid pumping device and liquid sensor for oil wells

An economical gas lift system has been designed that uses the airlift principles of the APOP system to enable one to pump deep wells which have been initially pumped using jack pumps. It can be constructed and installed in oil and/or gas wells where jack pumps have been operating. The 2 in. tubing in the bore hole is left in place and the rods are pulled from the normally 2 in. tubing. A 1 in. or greater diameter tubing containing a one way valve near its bottom and several small holes near the bottom of the 1 in. tube and just above the one way valve is installed into the 2 in. tubing. The one inch tube extends the total length of the 2 in. tubing and is seated on the seating nipple at the bottom of the 2 in. tubing. The space between the concentric tubes can serve as the gas(air) line and the center 1 in. tube serves as the liquid discharge line. This enables this pump to be used in many marginal wells which ordinarily would be uneconomical to pump. This is especially true for deep wells because the cost of jack pumps and the tubing as …
Date: October 5, 1992
Creator: Buckman, W. G.
Object Type: Report
System: The UNT Digital Library
The development and testing of a fieldworthy system of improved fluid pumping device and liquid sensor for oil wells. Technical progress report, third quarter 1992 (open access)

The development and testing of a fieldworthy system of improved fluid pumping device and liquid sensor for oil wells. Technical progress report, third quarter 1992

An economical gas lift system has been designed that uses the airlift principles of the APOP system to enable one to pump deep wells which have been initially pumped using jack pumps. It can be constructed and installed in oil and/or gas wells where jack pumps have been operating. The 2 in. tubing in the bore hole is left in place and the rods are pulled from the normally 2 in. tubing. A 1 in. or greater diameter tubing containing a one way valve near its bottom and several small holes near the bottom of the 1 in. tube and just above the one way valve is installed into the 2 in. tubing. The one inch tube extends the total length of the 2 in. tubing and is seated on the seating nipple at the bottom of the 2 in. tubing. The space between the concentric tubes can serve as the gas(air) line and the center 1 in. tube serves as the liquid discharge line. This enables this pump to be used in many marginal wells which ordinarily would be uneconomical to pump. This is especially true for deep wells because the cost of jack pumps and the tubing as …
Date: October 5, 1992
Creator: Buckman, W. G.
Object Type: Report
System: The UNT Digital Library
Draft Implementation Plan for the Hawaii Geothermal Project Environmental Impact Statement (open access)

Draft Implementation Plan for the Hawaii Geothermal Project Environmental Impact Statement

None
Date: November 5, 1992
Creator: unknown
Object Type: Report
System: The UNT Digital Library
DWPF ammonium ion analysis (open access)

DWPF ammonium ion analysis

Ammonium nitrate production during the operation of the Defense Waste Processing Facility (DWPF) has been identified as a major problem. The accumulation of ammonium nitrate deposits in the vent system of the chemical processing cell has substantial safety implications and will require analysis of ammonium ions within DWPF process samples. As a part of the research and development of the DWPF at TNX, an ammonium analysis method developed by Dionex Corporation has been identified and confirmed to provide the required information. This memorandum describes the technical basis of the method, the accuracy and precision of the method, known interferences, and maintenance details.
Date: June 5, 1992
Creator: Eibling, R. E.
Object Type: Report
System: The UNT Digital Library
DWPF ammonium ion analysis (open access)

DWPF ammonium ion analysis

Ammonium nitrate production during the operation of the Defense Waste Processing Facility (DWPF) has been identified as a major problem. The accumulation of ammonium nitrate deposits in the vent system of the chemical processing cell has substantial safety implications and will require analysis of ammonium ions within DWPF process samples. As a part of the research and development of the DWPF at TNX, an ammonium analysis method developed by Dionex Corporation has been identified and confirmed to provide the required information. This memorandum describes the technical basis of the method, the accuracy and precision of the method, known interferences, and maintenance details.
Date: June 5, 1992
Creator: Eibling, R. E.
Object Type: Report
System: The UNT Digital Library
Experimental study of interactions of highly charged ions with atoms at keV energies (open access)

Experimental study of interactions of highly charged ions with atoms at keV energies

This Progress Report describes the experimental work carried out, and the work in progress, at the Cornell EBIS Laboratory during the period 7/1/1991 to 6/30/1992. During this period, a number of experiments were carried out. The absolute values of the total, one, two and three electron transfer cross sections for highly charged argon ions (8{le}q{le}16) colliding with argon at 2.3 qkev laboratory energy were measured. The distribution of recoil ions and molecular fragments formed in highly charged ion atom and molecule collisions was measured in order to help the interpretation of electron spectra in the 40--320 eV energy range emitted in Ar{sup q+}+Ar(8{le}q{le}16) collisions at 2.3 qkeV that were measured in our laboratory. The interpretation of the electron spectra is still under way. A new collision chamber was built which contains an ion decelerating lens system and a high resolution monochromator-analyzer combination. Ions extracted from the Cornell Electron Beam Ion Source were successfully decelerated from 2.3 qkeV down to 30 qeV Preliminary 0{degree} translational energy spectra for Ar{sup l2+} on Ar at a collision energy of 38.6 qeV show a 0.56 qeV resolution. Work is in progress to extend measurements of cross sections and recoil ion charge state distributions down …
Date: July 5, 1992
Creator: Kostroun, V. O.
Object Type: Report
System: The UNT Digital Library
Experimental study of interactions of highly charged ions with atoms at keV energies. Progress report, July 1, 1991--June 30, 1992 (open access)

Experimental study of interactions of highly charged ions with atoms at keV energies. Progress report, July 1, 1991--June 30, 1992

This Progress Report describes the experimental work carried out, and the work in progress, at the Cornell EBIS Laboratory during the period 7/1/1991 to 6/30/1992. During this period, a number of experiments were carried out. The absolute values of the total, one, two and three electron transfer cross sections for highly charged argon ions (8{le}q{le}16) colliding with argon at 2.3 qkev laboratory energy were measured. The distribution of recoil ions and molecular fragments formed in highly charged ion atom and molecule collisions was measured in order to help the interpretation of electron spectra in the 40--320 eV energy range emitted in Ar{sup q+}+Ar(8{le}q{le}16) collisions at 2.3 qkeV that were measured in our laboratory. The interpretation of the electron spectra is still under way. A new collision chamber was built which contains an ion decelerating lens system and a high resolution monochromator-analyzer combination. Ions extracted from the Cornell Electron Beam Ion Source were successfully decelerated from 2.3 qkeV down to 30 qeV Preliminary 0{degree} translational energy spectra for Ar{sup l2+} on Ar at a collision energy of 38.6 qeV show a 0.56 qeV resolution. Work is in progress to extend measurements of cross sections and recoil ion charge state distributions down …
Date: July 5, 1992
Creator: Kostroun, V. O.
Object Type: Report
System: The UNT Digital Library
Final report for the flow excursion follow-on testing (open access)

Final report for the flow excursion follow-on testing

The purpose of the Mark 22 Flow Excursion Follow-On testing was to investigate the theory that approximately 15% of the flow bypassed the primary flow channels in previous testing, whereas the design called for only a 3% bypass. The results of the follow-on tests clearly confirmed this theory. The testing was performed in two phases. During the first phase, characterization tests performed during the earlier test program were repeated.
Date: August 5, 1992
Creator: Nash, C. A. & Walters, T. W.
Object Type: Report
System: The UNT Digital Library
Final report for the flow excursion follow-on testing (open access)

Final report for the flow excursion follow-on testing

The purpose of the Mark 22 Flow Excursion Follow-On testing was to investigate the theory that approximately 15% of the flow bypassed the primary flow channels in previous testing, whereas the design called for only a 3% bypass. The results of the follow-on tests clearly confirmed this theory. The testing was performed in two phases. During the first phase, characterization tests performed during the earlier test program were repeated.
Date: August 5, 1992
Creator: Nash, C. A. & Walters, T. W.
Object Type: Report
System: The UNT Digital Library
First measurement of the left-right cross section asymmetry in Z boson production at E{sub cm} = 91.5 GeV (open access)

First measurement of the left-right cross section asymmetry in Z boson production at E{sub cm} = 91.5 GeV

The left-right cross section asymmetry for Z boson production in e{sup +} e{sup {minus}} annihilation (A{sub LR}) is being measured at E{sub cm} 91.5 GeV with the SLD detector at the SLAC Linear Collider (SLC) using a longitudinally polarized electron beam. The electron polarization is continually monitored with a Compton scattering polarimeter, and is typically 22%. At the current time, we have accumulated a sample of 4779 Z events. We find that A{sub LR} = 0.02 {double_bond} 0.07 {doteq} 0.001 where the first error is statistical and the second is systematic. Using this very preliminary measurement, we determine the weak mixing angle defined at the Z boson pole to be sin{sup 2}{sub W}{sup olept} = 0.247 {plus_minus} 0.009.
Date: August 5, 1992
Creator: Collaboration, SLD
Object Type: Article
System: The UNT Digital Library
First measurement of the left-right cross section asymmetry in Z boson production at E[sub cm] = 91. 5 GeV (open access)

First measurement of the left-right cross section asymmetry in Z boson production at E[sub cm] = 91. 5 GeV

The left-right cross section asymmetry for Z boson production in e[sup +] e[sup [minus]] annihilation (A[sub LR]) is being measured at E[sub cm] 91.5 GeV with the SLD detector at the SLAC Linear Collider (SLC) using a longitudinally polarized electron beam. The electron polarization is continually monitored with a Compton scattering polarimeter, and is typically 22%. At the current time, we have accumulated a sample of 4779 Z events. We find that A[sub LR] = 0.02 [double bond] 0.07 [doteq] 0.001 where the first error is statistical and the second is systematic. Using this very preliminary measurement, we determine the weak mixing angle defined at the Z boson pole to be sin[sup 2][sub W][sup olept] = 0.247 [plus minus] 0.009.
Date: August 5, 1992
Creator: unknown
Object Type: Article
System: The UNT Digital Library
Highly dispersed catalysts for coal liquefaction (open access)

Highly dispersed catalysts for coal liquefaction

The objectives of this project are to study the effect of pretreatment methods on the two-stage liquefaction process. In particular, the effects of dispersed catalysts and carbon monoxide atmospheres on a coal liquefaction process. The project is divided into three technical tasks. Task 1 and 2 deal with the analyses and liquefaction experiments, respectively, whereas Task 3 deals with the economic impact of utilizing the pretreatment methods. This quarter we concentrated on Tasks 1 and 2, which are summarized below. Samples of Black Thunder Subbituminous coal and the corresponding recycle solvent were received from Wilsonville. These particular samples were obtained from run [number sign]263. The samples were analyzed for a proximate and ultimate analysis, as well as heat content. We have also received samples of the iron oxide used in the Wilsonville coal liquefaction runs as well as Shell 324 and molyVanL for use in future runs. Base-line screening experiments were conducted in 300 mL autoclaves using 2.5 parts by weight of recycle solvent to 1 part Black Thunder coal at 425[degree]C for one hour. In preliminary results for the comparison of iron oxide and iron carbonyl, the iron carbonyl appears to give higher yields to soluble products.
Date: November 5, 1992
Creator: Hirschon, A. S. & Wilson, R. B.
Object Type: Report
System: The UNT Digital Library
Highly Dispersed Catalysts for Coal Liquefaction. Quarterly Report No. 4, May 23, 1992--August 22, 1992 (open access)

Highly Dispersed Catalysts for Coal Liquefaction. Quarterly Report No. 4, May 23, 1992--August 22, 1992

The objectives of this project are to study the effect of pretreatment methods on the two-stage liquefaction process. In particular, the effects of dispersed catalysts and carbon monoxide atmospheres on a coal liquefaction process. The project is divided into three technical tasks. Task 1 and 2 deal with the analyses and liquefaction experiments, respectively, whereas Task 3 deals with the economic impact of utilizing the pretreatment methods. This quarter we concentrated on Tasks 1 and 2, which are summarized below. Samples of Black Thunder Subbituminous coal and the corresponding recycle solvent were received from Wilsonville. These particular samples were obtained from run {number_sign}263. The samples were analyzed for a proximate and ultimate analysis, as well as heat content. We have also received samples of the iron oxide used in the Wilsonville coal liquefaction runs as well as Shell 324 and molyVanL for use in future runs. Base-line screening experiments were conducted in 300 mL autoclaves using 2.5 parts by weight of recycle solvent to 1 part Black Thunder coal at 425{degree}C for one hour. In preliminary results for the comparison of iron oxide and iron carbonyl, the iron carbonyl appears to give higher yields to soluble products.
Date: November 5, 1992
Creator: Hirschon, Albert S. & Wilson, Robert B.
Object Type: Report
System: The UNT Digital Library
Interpretation of rapidly rotating pulsars (open access)

Interpretation of rapidly rotating pulsars

The minimum possible rotational period of pulsars, which are interpreted as rotating neutron stars, is determined by applying a representative collection of realistic nuclear equations of state. It is found that none of the selected equations of state allows for neutron star rotation at periods below 0.8--0.9 ms. Thus, this work strongly supports the suggestion that if pulsars with shorter rotational periods were found, these are likely to be strange-quark-matter stars. The conclusion that the confined hadronic phase of nucleons and nuclei is only metastable would then be almost inescapable, and the plausible ground-state in that event is the deconfined phase of (3-flavor) strange-quark-matter.
Date: August 5, 1992
Creator: Weber, F. (Technische Univ. Muenchen, Garching (Germany). Inst. fuer Theoretische Physik) & Glendenning, N. K. (Lawrence Berkeley Lab., CA (United States))
Object Type: Article
System: The UNT Digital Library
Interpretation of rapidly rotating pulsars (open access)

Interpretation of rapidly rotating pulsars

The minimum possible rotational period of pulsars, which are interpreted as rotating neutron stars, is determined by applying a representative collection of realistic nuclear equations of state. It is found that none of the selected equations of state allows for neutron star rotation at periods below 0.8--0.9 ms. Thus, this work strongly supports the suggestion that if pulsars with shorter rotational periods were found, these are likely to be strange-quark-matter stars. The conclusion that the confined hadronic phase of nucleons and nuclei is only metastable would then be almost inescapable, and the plausible ground-state in that event is the deconfined phase of (3-flavor) strange-quark-matter.
Date: August 5, 1992
Creator: Weber, F. & Glendenning, N. K.
Object Type: Article
System: The UNT Digital Library
Investigation of rare particle production in high energy nuclear collisions (open access)

Investigation of rare particle production in high energy nuclear collisions

None
Date: October 5, 1992
Creator: unknown
Object Type: Report
System: The UNT Digital Library