Lawrence Livermore Laboratory is conducting a safeguards program for the Nuclear Regulatory Commission. The goal of the Material Control Project of this program is to evaluate material control and accounting (MCA) methods in plants that handle special nuclear material (SNM). To this end we designed and implemented the dynamic chemical plant simulation program DYNSYL. This program can be used to generate process data or to provide estimates of process performance; it simulates both steady-state and dynamic behavior. The MCA methods that may have to be evaluated range from sophisticated on-line material trackers such as Kalman filter estimators, to relatively simple material balance procedures. This report describes the overall structure of DYNSYL and includes some example problems. The code is still in the experimental stage and revision is continuing.

A filter fluorescer experiment has been installed and operated on the Argus laser system of the Lawrence Livermore Laboratory. X-ray spectra have been measured between 20 and 116 keV from laser produced plasmas. Three spectral cuts were made in this region (20 to 29, 47 to 61 and 80 to 116 keV) with an additional channel providing a measure of the high energy response (> 116 keV) of the third channel. We have measured x-ray spectra from laser shots of 600 to 900 J in 1 ns with intensities of 3 x 10/sup 14/ to 3 x 10/sup 15/ W/cm/sup 2/ incident on Au disks.

The purpose of this manual is to present procedures to execute the Spent Nuclear Fuel Storage Model (SNFSM) program. This manual includes an overview of the model, operating environment, input and output specifications and user procedures. An example of the execution of the program is included to assist potential users.

A subscale, direct contact heat exchanger (1-ft dia packed column) was built and operated under conditions applicable to the Biphase diesel bottoming cycle. Special probes for measuring gas and liquid temperatures and for measuring gas-phase compositions were designed and installed in the exchanger. The data obtained are unique in that they indicate both the extent of evaporation and condensation zones within the exchanger and the effect that those mass transport mechanisms have upon heat exchanger performance. For gas temperatures greater than 500/sup 0/F it was found that the maximum temperature to which Therminol 66 could be heated was strongly dependent upon vaporization effects. Data obtained are sufficient to provide for the preliminary design of a direct contact heat exchanger using Therminol 66 as the thermal fluid. Recommendations are made for further testing using other heat transfer fluids to derive a more general engineering approach to the design of direct heat exchangers.

During the past quarter, 5 runs were made on a number of hydrotreated samples including a mildly hydrotreated simulated in-situ (1.35% N) and two moderately hydrotreated Tosco II (0.82% N and 1.55% N) distillates. The results are, in general, consistent with previous results which indicated an increase in olefins yield as the severity of hydrogenation increased. The olefins yields for the simulated in-situ oil were greater than those for the Tosco II oil for oil hydrogenated to comparable severities. The moderately hydrogenated Tosco II oil exhibited gasification tendencies at severe pyrolysis conditions, similar to the severely hydrogenated Tosco II oil. Correlational efforts were continued in using the propylene yield versus severity factor, and the yields of all major gas components versus propylene to ethylene ratio as a means of correlating pyrolysis yields. The efforts were extended to the hydrogenated simulated in-situ and Tosco II distillates.